Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine

KÜÇÜKİSLAMOĞLU, MUSTAFA; Imamoglu, Mustafa; TOPLAN, HÜSEYİN ÖZKAN; Zengin, Mustafa; Arslan, Mustafa; GENÇ, HAYRİYE

Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine

Hayriye GENÇ, (Sakarya Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Sakarya, Türkiye)

Mustafa ZENGİN, (Sakarya Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Sakarya, Türkiye)

Mustafa KÜÇÜKİSLAMOĞLU, (Sakarya Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Sakarya, Türkiye)

Mustafa İMAMOĞLU, (Sakarya Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Sakarya, Türkiye)

Hüseyin Özkan TOPLAN, (Sakarya Üniversitesi, Mühendislik Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümü, Sakarya, Türkiye)

Mustafa ARSLAN (Sakarya Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Sakarya, Türkiye)

Turkish Journal of Chemistry

2 0

Yıl: 2017 Cilt: 41 Sayı: 5 Sayfa Aralığı: 784 - 792 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine

Öz:

The catalytic activity of 1,3,5-triazine-pentaethylenehexamine (TAPEHA) polymer-supported Pd nanoparticles was investigated in the reduction of nitro arenes to the corresponding amines by NaBH4 or N2 H4 .H2 O. Optimized reaction conditions for both systems were successfully tested on 20 nitroarenes with different characteristics. Considerably high yields (80% 98% in NaBH4 and 85% 98% in N2 H4) were obtained in a short time and at ambient temperature. In addition to these methods being selective against other reducible functionalities such as CN, Br, Cl, and I, the catalyst can be recovered easily and reused more than ten times.

Anahtar Kelime:

Konular: Mühendislik, Kimya

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	GENÇ H, Zengin M, KÜÇÜKİSLAMOĞLU M, Imamoglu M, TOPLAN H, Arslan M (2017). Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine. , 784 - 792.
Chicago	GENÇ HAYRİYE,Zengin Mustafa,KÜÇÜKİSLAMOĞLU MUSTAFA,Imamoglu Mustafa,TOPLAN HÜSEYİN ÖZKAN,Arslan Mustafa Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine. (2017): 784 - 792.
MLA	GENÇ HAYRİYE,Zengin Mustafa,KÜÇÜKİSLAMOĞLU MUSTAFA,Imamoglu Mustafa,TOPLAN HÜSEYİN ÖZKAN,Arslan Mustafa Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine. , 2017, ss.784 - 792.
AMA	GENÇ H,Zengin M,KÜÇÜKİSLAMOĞLU M,Imamoglu M,TOPLAN H,Arslan M Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine. . 2017; 784 - 792.
Vancouver	GENÇ H,Zengin M,KÜÇÜKİSLAMOĞLU M,Imamoglu M,TOPLAN H,Arslan M Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine. . 2017; 784 - 792.
IEEE	GENÇ H,Zengin M,KÜÇÜKİSLAMOĞLU M,Imamoglu M,TOPLAN H,Arslan M "Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine." , ss.784 - 792, 2017.
ISNAD	GENÇ, HAYRİYE vd. "Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine". (2017), 784-792.

APA	GENÇ H, Zengin M, KÜÇÜKİSLAMOĞLU M, Imamoglu M, TOPLAN H, Arslan M (2017). Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine. Turkish Journal of Chemistry, 41(5), 784 - 792.
Chicago	GENÇ HAYRİYE,Zengin Mustafa,KÜÇÜKİSLAMOĞLU MUSTAFA,Imamoglu Mustafa,TOPLAN HÜSEYİN ÖZKAN,Arslan Mustafa Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine. Turkish Journal of Chemistry 41, no.5 (2017): 784 - 792.
MLA	GENÇ HAYRİYE,Zengin Mustafa,KÜÇÜKİSLAMOĞLU MUSTAFA,Imamoglu Mustafa,TOPLAN HÜSEYİN ÖZKAN,Arslan Mustafa Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine. Turkish Journal of Chemistry, vol.41, no.5, 2017, ss.784 - 792.
AMA	GENÇ H,Zengin M,KÜÇÜKİSLAMOĞLU M,Imamoglu M,TOPLAN H,Arslan M Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine. Turkish Journal of Chemistry. 2017; 41(5): 784 - 792.
Vancouver	GENÇ H,Zengin M,KÜÇÜKİSLAMOĞLU M,Imamoglu M,TOPLAN H,Arslan M Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine. Turkish Journal of Chemistry. 2017; 41(5): 784 - 792.
IEEE	GENÇ H,Zengin M,KÜÇÜKİSLAMOĞLU M,Imamoglu M,TOPLAN H,Arslan M "Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine." Turkish Journal of Chemistry, 41, ss.784 - 792, 2017.
ISNAD	GENÇ, HAYRİYE vd. "Catalytic application of 1,3,5-triazine-pentaethylenehexamine polymer-supported palladium nanoparticles in the convenient reduction of nitroarenes with sodium borohydride or hydrazine". Turkish Journal of Chemistry 41/5 (2017), 784-792.