Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method

GÜMÜŞKAYA, Esat; ATİK, Celil; NI, Yonghao; ATEŞ, Saim

Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method

Saim ATEŞ, (Kastamonu Üniversitesi, Orman Fakültesi, Kastamonu, Türkiye)

Celil ATİK, (İstanbul Üniversitesi, Ormancılık Meslek Yüksek Okulu, İstanbul Türkiye)

Yonghao NI, (Limerick Pulp and Paper Cent. UNB, Fredericton, NB, E3B6C2, CANADA)

Esat GÜMÜŞKAYA (Karadeniz Teknik Üniversitesi, Orman Fakültesi, Trabzon, Türkiye)

Turkish Journal of Agriculture and Forestry

3 1

Yıl: 2008 Cilt: 32 Sayı: 6 Sayfa Aralığı: 561 - 570 Metin Dili: Türkçe İndeks Tarihi: 29-07-2022

Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method

Öz:

Buğday sapları pişirilmesi aşamasında kraft-anthraquinone (AQ), bio-kraft, soda-AQ, ALCELL, ve FORMACELL gibi farklı pişirme yöntemleri uygulanmıştır. Biokraft yöntemi kapsamında buğday sapları Ceriporiopsis subvermispora, beyaz çürüklük mantarı, ile kraft-AQ pişirme öncesinde ön işleme uğratılmıştır. Elde edilen farklı hamurlara ait lif özellikleri, karbonhidrat bileşimleri, FT-IR analizleri, direnç özellikleri, ve ağartma karakteristikleri belirlenmiştir. Bunlara ilave olarak, ksilanaz ön işleminin Elementer Klorsuz Ağartma (ECF) işlemi üzerine etkisi araştırılmıştır. Sonuç olarak, düşük kappa numarası, yüksek karbonhidrat bileşimi, en yüksek kâğıt direnç özellikleri ve en iyi ağartılabilirlik özelliği ile buğday sapları için kraft-AQ yöntemlerinin en iyi sonuçları verdiği görülmüştür. Organosolv hamur örneklerinin yüksek kappa numarası, viskozite ve lif kabalık değerlerinin yanında daha düşük karbonhidrat bileşimi ve direnç özellikleri ve daha zayıf ağartılabilirlik özelliklerine sahip oldukları gözlemlenmiştir. C. subvermispora ile ön işleme uğratılmış buğday saplarından üretilen kâğıt hamurlarının direnç özellikleri ve ağartma karakteristiklerinin olumlu yönde etkilendiği görülmüştür. FT-IR sonuçlarından da açıkça görüleceği üzere elde edilen hamurların kristalinite indekslerinde önemli bir değişim görülmemiştir.

Anahtar Kelime: direnme gücü ağartma antrakuinon karbonhidratlar saman çürükçül mantar buğday samanı kağıt hamuru üretimi buğday

Konular: Orman Mühendisliği

Buğday sapının farklı pişirme yöntemleri ile elde edilen kimyasal hamurlarının karşılaştırılması ve enzim ön işlemli ECF yöntemi ile ağartılması

Öz:

Different pulping processes, kraft-anthraquinone (AQ), bio-kraft, soda-AQ, ALCELL, and FORMACELL were studied for wheat straw. Fungal pre-treatment with Ceriporiopsis subvermispora, white rot fungi, was applied to wheat straw before kraft-AQ pulping, the so-called bio-kraft process. Fiber properties, carbohydrate contents, FT-IR analyses, strength properties of resultant paper, and bleachability characteristics were included to determine the properties of these pulp samples. In addition, the effects of the xylanase pre-treatment on the subsequent Elemental Chlorine Free (ECF) bleaching process were investigated. The results indicated that kraft-AQ pulps from wheat straw exhibited better characteristics than the other pulp samples with lower kappa number, higher carbohydrate content, higher paper strength properties, and better bleachability. The highest kappa number, viscosity, and fiber coarseness were found for organosolv pulp samples; however, these pulps had the lowest carbohydrate contents and strength values and poor bleaching properties. It was concluded that the fungal pre-treatment of wheat straw with C. subvermispora had a positive effect on the bleachability and gave stronger pulp. There was no clear alteration in the crystallinity index of pulp samples based on the FT-IR results.

Anahtar Kelime: straw decay fungi wheat straw pulping wheat strength bleaching anthraquinones carbohydrates

Konular: Orman Mühendisliği

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	ATEŞ S, ATİK C, NI Y, GÜMÜŞKAYA E (2008). Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method. , 561 - 570.
Chicago	ATEŞ Saim,ATİK Celil,NI Yonghao,GÜMÜŞKAYA Esat Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method. (2008): 561 - 570.
MLA	ATEŞ Saim,ATİK Celil,NI Yonghao,GÜMÜŞKAYA Esat Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method. , 2008, ss.561 - 570.
AMA	ATEŞ S,ATİK C,NI Y,GÜMÜŞKAYA E Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method. . 2008; 561 - 570.
Vancouver	ATEŞ S,ATİK C,NI Y,GÜMÜŞKAYA E Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method. . 2008; 561 - 570.
IEEE	ATEŞ S,ATİK C,NI Y,GÜMÜŞKAYA E "Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method." , ss.561 - 570, 2008.
ISNAD	ATEŞ, Saim vd. "Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method". (2008), 561-570.

APA	ATEŞ S, ATİK C, NI Y, GÜMÜŞKAYA E (2008). Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method. Turkish Journal of Agriculture and Forestry, 32(6), 561 - 570.
Chicago	ATEŞ Saim,ATİK Celil,NI Yonghao,GÜMÜŞKAYA Esat Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method. Turkish Journal of Agriculture and Forestry 32, no.6 (2008): 561 - 570.
MLA	ATEŞ Saim,ATİK Celil,NI Yonghao,GÜMÜŞKAYA Esat Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method. Turkish Journal of Agriculture and Forestry, vol.32, no.6, 2008, ss.561 - 570.
AMA	ATEŞ S,ATİK C,NI Y,GÜMÜŞKAYA E Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method. Turkish Journal of Agriculture and Forestry. 2008; 32(6): 561 - 570.
Vancouver	ATEŞ S,ATİK C,NI Y,GÜMÜŞKAYA E Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method. Turkish Journal of Agriculture and Forestry. 2008; 32(6): 561 - 570.
IEEE	ATEŞ S,ATİK C,NI Y,GÜMÜŞKAYA E "Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method." Turkish Journal of Agriculture and Forestry, 32, ss.561 - 570, 2008.
ISNAD	ATEŞ, Saim vd. "Comparison of different chemical pulps from wheat straw and bleaching with xylanase pre-treated ECF method". Turkish Journal of Agriculture and Forestry 32/6 (2008), 561-570.