Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC

UĞUZ, Gediz; ayanoglu, abdulkadir

Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC

Gediz UĞUZ, (Ondokuz Mayıs Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü, Samsun, Türkiye)

Abdülkadir AYANOĞLU (Mardin Artuklu Üniversitesi, Meslek Yüksekokulu, Makine ve Metal Teknolojileri Bölümü, Mardin, Türkiye)

Bitlis Eren Üniversitesi Fen Bilimleri Dergisi

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Yıl: 2021 Cilt: 10 Sayı: 3 Sayfa Aralığı: 930 - 942 Metin Dili: İngilizce İndeks Tarihi: 16-08-2022

Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC

Öz:

The huge amount of waste tires (WTs) have been disposed to surroundings which cause dangerous effect on nature. Owing to recycled WTs, the pyrolysis is a good technique to dismiss harmful effect of the WTs, by converting into gas, liquid and solid. The present study has two steps of liquefaction at a batch reactor. Firstly, conversion of the WTs into gas, waste tire oil (WTO) and char. Then the WTO were blended with calcium oxide (CaO) or natural zeolite (NZ) at different ratio and pyrolyzed to obtain high quality oil, similar to gasoline fuel (GF) or diesel fuel (DF). The distillation curve is a good key to define fuel quaility. Thus, 10% CaO-WTO blend curve near to the DF. Unfortunately, the mixture was distillated at 54 oC, lower than the DF. Therefore, the blend was separated into two fractions due to intial-final boiling points as 150 oC to 360 oC, named as Diesel like fuel (DLF); between 54 oC to 150 oC, called as gasoline like fuel (GLF). Finally, samples were analyzed to characterizate by GC, ICP-MS, TGA and DSC for similarities of conventional fuels. The heavy metals and other elements of samples were analyzed by ICP-MS techniques. TGA is a good test to determine the oxidative and thermal stabilities of fuel while DSC was used to determine crystallization onset temperature on fuel samples. GC analysis is done for detemening of gas heating value and beside gas contents which has a comprehensive with standard burnable gas. Based on GLF and DLF with unliquified gas results, all of components of products can be burned in engine without any problem.

Anahtar Kelime: Waste Tire Pyrolysis Gasoline Like Fuel Diesel Like Fuel Characterization

Atık Lastik Piroliz Ürünlerinin GC, ICP-MS, TGA ve DSC tarafından karakterizasyon

Öz:

Büyük miktarda atık lastik (AL) çevreye atılmakta ve doğa üzerinde tehlikeli etkilere sebep olmaktadır. AL’in geri donuşumu için, piroliz kullanılarak atık lastiklerin gaz, sıvı ve katı ürünlere dönüştürülerek AL’nin zararlı etkilerini bertaraf etmek amacıyla kullanılan etkili bir tekniktir. Bu çalışmada, bir kesikli reaktör kullanılarak iki adımda sıvılaştırma yapılmıştır. İlk olarak, atık lastik gaza, atık lastik yağına (ALY) ve karbon siyahına dönüştürülmüştür. İkinci adımda ise ALY, farklı oranda Kalsiyum Oksit (CaO) veya Doğal Zeolit (NZ) ile karıştırılarak; benzine veya dizel benzeyen yakıt yüksek kaliteli yakıt elde etmek için piroliz edilmiştir. Distilasyon eğrisi, yakıt kalitesini tanımlamak için iyi bir referanstır. % 10CaO-ALY karışımının distilasyon eğrisi dizel yakıta benzerlik gösterdiği tespit edilmiştir. Fakat karışımın dizel yakıttan daha düşük olan 54 oC'de distile edilmiştir. Bu nedenle karışım, ilk-son kaynama noktalarına göre ayrıştırılarak iki fraksiyon elde edilmiştir. 54 oC ile 150 oC arasında, benzin benzeri yakıt (BBY); 150 oC ile 360 oC arasında dizel benzeri yakıt (DBY)) elde edilmiştir. Elde edilen bu iki fraksiyon, geleneksel yakıtlara benzerliklerini değerlendirmek amacıyla GC, ICP-MS, TGA ve DSC teknikleri kullanılarak analiz edilmiştir. Örneklerdeki ağır metaller ve diğer elementler ICP-MS tekniği ile analiz edilmiştir. TGA yakıtlardaki termal ve oksidasyon kararlılığını belirlemek için kullanılan iyi bir tekniktir. DSC ise yakıt örneklerindeki kristallenmeye başladığı noktanın belirlenmesi amacıyla kullanılmıştır. GC analizi ile gazin ısıl değeri tespit edilip, bununla beraber gaz içeriği de tespit edilerek standard yanabilen gazlarla karşılastıtılmıştır. Elde edilen sonuçlar BBY ve DBY ile sıvılaşmayan gaz numune sonuçlarının motorlarda problemsiz kullanılabileceğini göstermiştir.

Anahtar Kelime: Atık Lastik Piroliz Benzin Benzeri Yakıt Dizel Benzeri Yakıt Karakterizasyon

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	UĞUZ G, ayanoglu a (2021). Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC. , 930 - 942.
Chicago	UĞUZ Gediz,ayanoglu abdulkadir Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC. (2021): 930 - 942.
MLA	UĞUZ Gediz,ayanoglu abdulkadir Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC. , 2021, ss.930 - 942.
AMA	UĞUZ G,ayanoglu a Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC. . 2021; 930 - 942.
Vancouver	UĞUZ G,ayanoglu a Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC. . 2021; 930 - 942.
IEEE	UĞUZ G,ayanoglu a "Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC." , ss.930 - 942, 2021.
ISNAD	UĞUZ, Gediz - ayanoglu, abdulkadir. "Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC". (2021), 930-942.

APA	UĞUZ G, ayanoglu a (2021). Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, 10(3), 930 - 942.
Chicago	UĞUZ Gediz,ayanoglu abdulkadir Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 10, no.3 (2021): 930 - 942.
MLA	UĞUZ Gediz,ayanoglu abdulkadir Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol.10, no.3, 2021, ss.930 - 942.
AMA	UĞUZ G,ayanoglu a Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2021; 10(3): 930 - 942.
Vancouver	UĞUZ G,ayanoglu a Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2021; 10(3): 930 - 942.
IEEE	UĞUZ G,ayanoglu a "Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC." Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, 10, ss.930 - 942, 2021.
ISNAD	UĞUZ, Gediz - ayanoglu, abdulkadir. "Characterization of Waste Tire Pyrolysis Products by GC, ICP-MS, TGA and DSC". Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 10/3 (2021), 930-942.