POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ

Ulas, Abdullah; BAYANER, Volkan; Ozen, Ilhan; OKYAY, Assistant Professor Gamze

doi:10.7216/1300759920222912606

POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ

Gamze OKYAY, (Malatya Turgut Özal Üniversitesi, Tasarım Bölümü, Malatya, Türkiye)

Volkan BAYANER, (Yünsa Yünlü Sanayii ve Ticaret A.Ş., Çerkezköy Organize Sanayi Bölgesi, Tekirdağ, Türkiye)

Abdullah ULAŞ, (Erciyes Üniversitesi, Toprak Bilimi ve Bitki Besleme Bölümü, Kayseri, Türkiye)

İlhan ÖZEN (Erciyes Üniversitesi, Tekstil Mühendisliği Bölümü, Kayseri, Türkiye)

Tekstil ve Mühendis

2 0

Yıl: 2022 Cilt: 29 Sayı: 126 Sayfa Aralığı: 88 - 95 Metin Dili: Türkçe DOI: 10.7216/1300759920222912606 İndeks Tarihi: 15-09-2022

POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ

Öz:

Tarımsal uygulamalar için su emici/tutucu ve kontrollü gübre salım özelliğine sahip agrotekstil yapısı oluşturmak amacıyla, 75/25 poli(etilen terefitalat)/viskon (PET/CV) dokusuz yüzeyler (DY), öncelikle poli(vinil alkol) (PVOH) ve ardından sodyum karboksimetil selüloz (Na-CMC), potasyum nitrat (PN) ve sitrik asit (CA) içeren çözeltilerle kaplanmıştır. PVOH ve Na-CMC kaplama miktarları sırasıyla 120 g/m2 ve 30, 60 ve 90 g/m2 olarak belirlenmiş ve çapraz bağlayıcı olarak %5 CA kullanılmıştır. Kaplamadan sonra dokusuz yüzeylerin morfolojik ve yapısal, jelleşme, su emicilik, su tutma ve gübre salım davranışı incelenmiştir. Çalışma sonuçları değerlendirildiğinde, sitrik asit kullanımının çapraz bağ oluşumunu desteklediği ve tüm kaplama formülasyonlarında %1000’in üzerinde su emicilik kapasitesine ulaşıldığı görülmüştür. Ayrıca, hazırlanan agrotekstil yapıları lineer bir gübre salım şekli göstererek, kontrollü salım gübre olarak adlandırılabilmesi için gerekli olan besin salım şeklini sağlamıştır. Ancak, hiçbir numune besin salım hızı açısından gerekli olan kriterleri karşılayamamaktadır. Sonuç olarak, üretilen agrotekstil yapıları performans açısından değerlendirildiğinde, 60 g/m2 Na-CMC ile yapılan formülasyonun en optimum özelliklere sahip olduğu söylenebilir.

Anahtar Kelime:

EFFECT OF COATING AMOUNT ON WATER AND FERTILIZER RELEASE PROPERTIES OF POTASSIUM NITRATE CONTAINING SODIUM-CARBOXYMETHYL CELLULOSE COATED NONWOVENS

Öz:

To create an agrotextile structure with water-absorbing/retaining and controlled fertilizer release properties for agricultural applications,75/25 poly(ethylene terephthalate)/viscose (PET/CV) nonwoven fabrics (DY) were firstly coated with poly(vinyl alcohol) (PVOH) and then with sodium carboxymethyl cellulose (Na-CMC), potassium nitrate (PN) and citric acid (CA) solutions. PVOH and Na-CMC coating amounts were adjusted to 120 g/m2 and 30, 60, and 90 g/m2, respectively, and 5% CA was utilized as a cross-linker. Morphological and structural, water absorbency, water retention, and fertilizer release behaviors of the nonwoven fabrics were investigated after coating. When the results of the study were evaluated, it could be said that the use of citric acid supported the formation of crosslinking and all coating formulations had a water absorbency capacity of over 1000%. Furthermore, the created agrotextile structures displayed a linear fertilizer release pattern, indicating that they provided the criteria for being classified as a controlled-release fertilizer. However, no sample achieved the nutrient release rate criteria. When the prepared formulations were evaluated in terms of performance, it could be said that the formulation made with 60 g/m2 Na-CMC had the most optimum properties.

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

1. Kiiski, H., Scherer, H. W., Mengel, K., Kluge, G., Severin, K., (2000), Fertilizers, 1. general, in: Ullmann’s Encyclopedia of Industrial Chemistry, 1-30.
2. Glibert, P. M., Harrison, J., Heil, C., Seitzinger, S., (2006), Escalating Worldwide Use of Urea A Global Change Contributing to Coastal Eutrophication, Biogeochemistry, 77 (3), 441-463.
3. Howarth, R. W., (2008), Coastal Nitrogen Pollution: A Review of Sources and Trends Globally and Regionally, Harmful Algae, 8 (1), 14-20.
4. Yang, X., Fang, S., (2015), Practices, Perceptions, and Implications of Fertilizer Use in East-Central China, Ambio, 44 (7), 647-652.
5. Lewu, F. B., Volova, T., Thomas, S., Rakhimol, K. R., (2020), Controlled Release Fertilizers for Sustainable Agriculture, Elsevier, London, United Kingdom.
6. Savci, S., (2012), Investigation of Effect of Chemical Fertilizers on Environment, APCBEE Procedia, 287-292, 5-7 January 2012, Hong Kong.
7. Deniz Temiz Derneği., (2021), Deniz Salyası için Acil Eylem Planı Çağrısı, Deniz Kültürü ve Çevre Dergisi, 62, 1-100.
8. Ayoub, A. T., (1999), Fertilizers and the Environment, Nutrient Cycl. Agroecosyst, 55(2), 117-121.
9. Chandini., Kumar, R., Kumar, R., Prakash, O., (2019), The Impact of Chemical Fertilizers on our Environment and Ecosystem, in: Book: Research Trends in Environmental Sciences, 69-86.
10. Sharma, N., Singhvi, R., (2017), Effects of Chemical Fertilizers and Pesticides on Human Health and Environment: A Review, International Journal of Agriculture Environment and Biotechnology, 10(6), 675-679.
11. Hite, D., Hudson, D., Intarapapong, W., (2002), Willingness to Pay for Water Quality Improvements: The Case of Precision Application Technology, Journal of Agricultural and Resource Economics, 27(2), 433-449.
12. Ladha, J. K., Pathak, H., Krupnik, T., Six, J., Kessel, J. V., (2005), Efficiency of Fertilizer Nitrogen in Cereal Production: Retrospects and Prospects, Advances in Agronomy, 87, 85-156.
13. Han, H. Y., Zhao, L. G., (2009), Farmers’ Character and Behavior of Fertilizer Application Evidence from A Survey of Xinxiang County, Henan Province, China, Agricultural Sciences in China, 8(10), 1238-1245.
14. Wang, C., Song, S. H., Yang, Z. M., Liu, Y. H., He, Z. Y., Zhou, C., Du, L. Q., Sun, D. Q., Li, P. W., (2022), Hydrophobic Modification of Castor Oil-Based Polyurethane Coated Fertilizer to Improve The Controlled Release of Nutrient with Polysiloxane and Halloysite, Progress in Organic Coatings, 165, 1-10.
15. Bi, S., Barinbelli, V., Eriksen, B., Ruiz, S., Sobkowicz, M. J., (2021), Biodegradable Polyester Coated Mulch Paper for Controlled Release of Fertilizer, Journal of Cleaner Production, 294, 1-9.
16. Pimenta, I. F., Figueiredo, L. R. F., Santos, A. M. C., Oliveira, J. E., Medeiros, E. S., (2021), Development of Controlled Release Fertilizer Systems for KCl Using Glycerol-Based Polymers, Journal of Applied Polymer Science, 139(10), 1-9.
17. Cen, Z., Wei, L., Muthukumarappan, K., Sobhan, A., McDaniel, R., (2021), Assessment of a Biochar-Based Controlled Release Nitrogen Fertilizer Coated with Polylactic Acid, Journal of Soil Science and Plant Nutrition, 21, 2007-2019.
18. Ersundu, M. Ç., Kuzu, B., Ersundu, A. E., (2022), Structural Properties and Dissolution Behavior of New Generation Controlled Release Phosphate Glass Fertilizers, Journal of Non-Crystalline Solids, 576, 1-15.
19. Liao, Y., Liu, L., Wang, M., Li, Li-Xia., Cao, B., Wang, H., Huang, W. Q., (2020), Preparation and Properties of Starch-Based Polyurethane/Montmorillonite Composite Coatings for Controlled- Release Fertilizer, 42, 2293-2304.
20. Havlin, J. L., Tisdale, S. L., Nelson, W. L., Beaton, J. D., (2014), Soil Fertility and Fertilizers: An Introduction to Nutrient Management, Pearson, New Jersey.
21. Ni, B., Liu, M., Lü, S., (2009), Multifunctional Slow-Release Urea Fertilizer from Ethylcellulose and Superabsorbent Coated Formulations, Chemical Engineering Journal, 155, 892-898.
22. Irfan, S. A., Razali, R., KuShaari, K., Mansor, N., Azeem, B., Versypt, A. Ford., (2018), A Review of Mathematical Modeling and Simulation of Controlled-Release Fertilizers, Journal of Controlled Release 271, 45-54.
23. Purnomo, C. W., Respito, A., Sitanggang, E. P., Mulyono, P., Slow- Release Fertilizer Preparation from Sugar Cane Industrial Waste, Environmental Technology Innovation 10, 275-280.
24. Dave, A. M., Mehta, M. H., T Aminabhavi, M., Kulkarni, A. R., Soppimath, K. S., (1999), A Review on Controlled Release of Nitrogen Fertilizers through Polymeric Membrane Devices, Polymer-Plastics Technology and Engineering, 38(4), (675-711.
25. Versino, F., Urriza, M., García, M. A., (2019), Eco-Compatible Cassava Starch Films for Fertilizer Controlled-Release, International Journal of Biological Macromolecules, 1(134), 302- 307.
26. Han, X. Z., Chen, S., Hu, X. G., (2009), Controlled-Release Fertilizer Encapsulated by Starch/Polyvinyl Alcohol Coating, Desalination 240(1), 21-26.
27. Jamnongkan, T., Kaewpirom, S., (2010), Potassium Release Kinetics and Water Retention of Controlled-Release Fertilizers Based on Chitosan Hydrogels, Journal of Polymers and the Environment 18(3), 413-421.
28. Wang, Y., Liu, M., Ni, B., Xie, L., (2012), K-Carrageenan- Sodium Alginate Beads and Superabsorbent Coated Nitrogen Fertilizer with Slow-Release, Water-Retention, and Anticompaction Properties, Industrial & Engineering Chemistry Research, 51(3), 1413–1422.
29. Ni, B., Liu, M., Lü, S., (2009), Multifunctional Slow-Release Urea Fertilizer from Ethylcellulose and Superabsorbent Coated Formulations, Chemical Engineering Journal, 155, 892–898.
30. Wu, L., Liu, M., Liang, R., (2008), Preparation and Properties of a Double-Coated Slow-Release NPK Compound Fertilizer with Superabsorbent and Water-Retention, Bioresource Technology, 99(3), 547–554.
31. Mukerabigwi, J. F., Wang, Ma, Q. X., Liu, M., Lei, S., Wei, H., Huang, X., Cao, Y., (2015), Urea Fertilizer Coated with Biodegradable Polymers and Diatomite for Slow Release and Water Retention, Journal of Coatings Technology Reserarch, 12(6), 1085– 109.
32. Bajpai, A. K., Giri, A., (2002), Swelling Dynamics of a Macromolecular Hydrophilic Network and Evaluation of Its Potential for Controlled Release of Agrochemicals, Reactive & Functional Polymers, 53(2-3), 125–141.
33. Hemvichian, K., Chanthawong, A., Suwanmalan, P., (2014), Synthesis and Characterization of Superabsorbent Polymer Prepared by Radiation-Induced Graft Copolymerization of Acrylamide onto Carboxymethyl Cellulose for Controlled Release of Agrochemicals, Radiation Physics and Chemistry, 103, 167-171.
34. Davidson, D. W., Verma, M. S., Gu., F. X., (2013), Controlled Root Targeted Delivery of Fertilizer Using an Ionically Crosslinked Carboxymethyl Cellulose Hydrogel Matrix, SpringerPlus, 2(318), 1- 9.
35. Morita, A., Takano, H., Oota, M., Yoneyama, T., (2002), Nitrification and Denitrification in an Acidic Soil of Tea (Camellia sinensis L.) Field Estimated by Delta N-15 Values of Leached Nitrogen from the Soil Columns Treated with Ammonium Nitrate in the Presence or Absence of a Nitrification Inhibitor and with Slow- Release Fertilizers, Soil Science & Plant Nutrition, 48, 585-593.
36. Drost, D., Koenig, R., Tindall, T., (2002), Nitrogen Use Efficiency and Onion Yield Increased with a Polymer-Coated Nitrogen Source, Hortscience, 37(2), 338-342.
37. Tian, X. H., Saigusa, M., (2005), Response of Tomato Plants to a New Application Method of Polyolefin-Coated Fertilizer, Pedosphere ,15, 491-498.
38. Charpentier, D., Mocanu, G., Carpov, A., Chapelle, S., Merle, L., & Muller, G., (1997). New Hydrophobically Modified Carboxymethylcellulose Derivatives, Carbohydrate Polymers, 33, 177-186.
39. Mitsumata, T., Suemitsu, Y., Fujii, K., Fujii, T., Taniguchi, T., & Koyama, K., (2003), pH-Response of Chitosan, K-Carrageenan, Carboxymethylcellulose Sodium Salt Complex Hydrogels, Polymer, 44(23), 7103-7111.
40. Goswami, B. C., Anandjiwala, R. D., Hall, D. M., (2004), Textile Sizing, Marcel, New York.
41. Borůvková, K., Wiener, J., (2011), Water Absorption in Carboxymethyl Cellulose, AUTEX Research Journal, 11(4), 110- 113.
42. Borůvková, K., Wiener, J., Jakubıčková, M., (2012), Preparation and Properties of Microporous Structures Based on CMC, Nanocon, 23-25(10), 1-6.
43. Krizova, H., Wiener, J., (2013), Development of Carboxymethyl Cellulose/Polyphenols Gels for Textile Applications, AUTEX Research Journal, 13(2), 33-36.
44. Özen, I., Okyay, G., Ulaş, A., 2018, Coating of Nonwovens with Potassium Nitrate Containing Carboxymethyl Cellulose for Efficient Water and Fertilizer Management, Cellulose, 25, 1527-1538.
45. Özen, I., Okyay, G., Ulaş, A., (2019), Controlled Fertilizer Release via Tunable Poly(vinyl alcohol)/Ammonium Sulfate-Coated Nonwoven Materials, Journal of Coatings Technology Research, 16(1), 93-102.
46. Foomany, K. S., Foomany, Ka. S., Biglouei, M. H., Assimi, M. H., Daneshian, J., Barzegarkho, M. H., (2012), Investigation the Effect of Irrigation and Different Amounts of Nitrogen Fertilizer on Tobacco Cocker 347, Technical Journal of Engineering & Applied Science, 2(2), 51-55.
47. Gholizadeh, R., Roshan, N. M., Sadeghi, S., Dorodian, M. H., (2012), Study Effects of Different Nitrogen and Potassium Fertilizers Application Amounts on Quantitative and Qualitative Characteristics of Tobacco (male sterile variety, PVH19) in Talesh Region, Annals of Biological Research, 3(11), 5323-5349.
48. Raucci, M. G., Alvarez-Perez, M. A., Demitri, C., Giugliano, D., De Benedictis, V., Sannino, A., Ambrosio, L., (2015), Effect of Citric Acid Crosslinking Cellulose-Based Hydrogels on Osteogenic Differentiation, Journal of Biomedical Materials Research Part A, 103(6), 2045-2056.
49. Sultana, S., Islam, M. R., Dafader, N. C., Haque, M. E., Nagasawa, N., Tamada, M., (2012), Effect of Mono-and Divalent Salts on the Properties of Carboxymethyl Cellulose Hydrogel Under Irradiation Technique, International Journal of Chemical Sciences, 10, 627-634.
50. Noppakundilograt, S., Pheatcharat, N., Kiatkamjornwong, S. (2015), Multilayer-Coated NPK Compound Fertilizer Hydrogel with Controlled Nutrient Release and Water Absorbency, Journal of Applied Polymer Science, 132, 1-11.
51. Mukerabigwi, J. F., Wang, Q., Ma, X. Y., Liu, M., Lei, S. J., Wei, H. T., Huang, X. Y., Cao, Y., (2015), Urea Fertilizer Coated with Biodegradable Polymers and Diatomite for Slow Release and Water Retention, Journal of Coatings Technology and Research, 12, 1085- 1094.
52. Wu, L., Liu, M. Z., (2008), Preparation and Properties of Chitosan- Coated NPK Compound Fertilizer with Controlled-Release and Water-Retention, Carbohydrate Polymers, 72, 240-247.

APA	OKYAY A, BAYANER V, Ulas A, Ozen I (2022). POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ. , 88 - 95. 10.7216/1300759920222912606
Chicago	OKYAY Assistant Professor Gamze,BAYANER Volkan,Ulas Abdullah,Ozen Ilhan POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ. (2022): 88 - 95. 10.7216/1300759920222912606
MLA	OKYAY Assistant Professor Gamze,BAYANER Volkan,Ulas Abdullah,Ozen Ilhan POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ. , 2022, ss.88 - 95. 10.7216/1300759920222912606
AMA	OKYAY A,BAYANER V,Ulas A,Ozen I POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ. . 2022; 88 - 95. 10.7216/1300759920222912606
Vancouver	OKYAY A,BAYANER V,Ulas A,Ozen I POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ. . 2022; 88 - 95. 10.7216/1300759920222912606
IEEE	OKYAY A,BAYANER V,Ulas A,Ozen I "POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ." , ss.88 - 95, 2022. 10.7216/1300759920222912606
ISNAD	OKYAY, Assistant Professor Gamze vd. "POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ". (2022), 88-95. https://doi.org/10.7216/1300759920222912606

APA	OKYAY A, BAYANER V, Ulas A, Ozen I (2022). POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ. Tekstil ve Mühendis, 29(126), 88 - 95. 10.7216/1300759920222912606
Chicago	OKYAY Assistant Professor Gamze,BAYANER Volkan,Ulas Abdullah,Ozen Ilhan POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ. Tekstil ve Mühendis 29, no.126 (2022): 88 - 95. 10.7216/1300759920222912606
MLA	OKYAY Assistant Professor Gamze,BAYANER Volkan,Ulas Abdullah,Ozen Ilhan POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ. Tekstil ve Mühendis, vol.29, no.126, 2022, ss.88 - 95. 10.7216/1300759920222912606
AMA	OKYAY A,BAYANER V,Ulas A,Ozen I POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ. Tekstil ve Mühendis. 2022; 29(126): 88 - 95. 10.7216/1300759920222912606
Vancouver	OKYAY A,BAYANER V,Ulas A,Ozen I POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ. Tekstil ve Mühendis. 2022; 29(126): 88 - 95. 10.7216/1300759920222912606
IEEE	OKYAY A,BAYANER V,Ulas A,Ozen I "POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ." Tekstil ve Mühendis, 29, ss.88 - 95, 2022. 10.7216/1300759920222912606
ISNAD	OKYAY, Assistant Professor Gamze vd. "POTASYUM NİTRAT İÇEREN SODYUM KARBOKSİMETİL SELÜLOZ İLE KAPLANMIŞ DOKUSUZ YÜZEYLERDE KAPLAMA MİKTARININ SU VE GÜBRE SALIM ÖZELLİKLERİ ÜZERİNE ETKİSİ". Tekstil ve Mühendis 29/126 (2022), 88-95. https://doi.org/10.7216/1300759920222912606