Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles

Mustafa Ersin PEKDEMİR, (Kimya Bölümü, Fen Fakültesi, Fırat Üniversitesi, Elazığ, Türkiye)
Mediha KÖK, (Department of Physics, College of Science, University of Raparin, Sulaymaneyah, Iraq)
Yildirim AYDOGDU, (Gazi Üniversitesi, Fen Fakültesi, Fizik Bölümü, Ankara, Türkiye)
meltem coşkun (Fırat Üniversitesi, Fen Fakültesi, Fizik Bölümü, Elazığ, Türkiye)
El-Cezerî Journal of Science and Engineering
3 0
Yıl: 2021 Cilt: 8 Sayı: 3 Sayfa Aralığı: 1395 - 1404 Metin Dili: İngilizce DOI: 10.31202/ecjse.932313 İndeks Tarihi: 17-10-2022

Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles

Öz:
Polyvinyl chloride (PVC) is one of the popular materials that extensively used in different areas, so scientists are trying to investigate its characteristics in different formats, such as blends and composites, to improve its properties. Due to the distinctive nano particles’ properties, polymer-based nanocomposites can offer new characteristics to pure polymers and can widen their applications in different areas. In this study, we added different compositions of silicon carbide (SiC) to PVC to investigate its molecular, thermal, and microstructural properties. Attenuated total reflection- infrared (ATR-IR), thermogravimetry (TG), differential scanning calorimetry (DSC), and optical microscopy (OM) were utilized to study molecular bond structure, thermal degradation, caloric properties, and surface morphology of the pure PVC and its composites. The first derivative of TG results showed that the temperature of the maximum thermal degradation of the PVC increased with increasing SiC nanoparticle ratio. Also, it is found that the PVC/12 mol% SiC started thermal degradation at comparably low temperature, however, the amount of residue of the composites is more than the pure PVC. Additionally, SiC nanoparticles caused the melting temperature of the composites to slightly shifts to a lower temperature compared to the PVC. It was observed that silicon carbide diminished the smoothness of the surface by increasing its fraction in the composite.
Anahtar Kelime: PVC silicon carbide composite thermal optic microscope

Farklı Miktarlarda SiC Nanopartiküllerini İçeren Polivinilklorür / Silisyum Karbür Nanokompozitlerinin Keşfi

Öz:
Polivinil klorür (PVC), farklı alanlarda yaygın olarak kullanılan popüler malzemelerden biridir, bu nedenle bilim adamları, özelliklerini iyileştirmek için karışımlar ve kompozitler gibi farklı formatlarda özelliklerini araştırmaya çalışıyorlar. Ayırt edici nano parçacıkların özellikleri nedeniyle, polimer bazlı nanokompozitler, saf polimerlere yeni özellikler sunabilir ve farklı alanlardaki uygulamalarını genişletebilir. Bu çalışmada, moleküler, termal ve mikroyapısal özelliklerini araştırmak için PVC'ye farklı oranlarda silisyum karbür (SiC) nanoparçacıklarını ekledik. Saf PVC ve kompozitlerinin moleküler bağ yapısını, termal bozunmasını, kalorik özelliklerini ve yüzey morfolojisini incelemek için zayıflatılmış toplam yansıma-kızılötesi (ATR-IR), termogravimetri (TG), diferansiyel taramalı kalorimetri (DSC) ve optik mikroskop (OM) kullanıldı. TG sonuçlarının ilk türevi, PVC' nin maksimum termal bozunması sıcaklığının artan SiC nanopartikül oranı ile arttığını gösterdi. Aynı zamanda, PVC / % 12 mol SiC'nin nispeten düşük sıcaklıkta termal bozunmaya başladığı, ancak kompozit atık miktarının saf PVC' den daha fazla olduğu bulundu. Ek olarak, SiC nanpartikülleri, kompozitlerin erime sıcaklığının PVC' ye kıyasla biraz daha düşük bir sıcaklığa kaymasına neden oldu. Silisyum karbürün kompozit içindeki payını artmasıyla yüzeyin düzgünlüğünün azaldığı görüldü.
Anahtar Kelime: PVC silisyum karbür kompozit termal optik mikroskop

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA PEKDEMİR M, Qader I, AYDOGDU Y, coşkun m (2021). Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles. , 1395 - 1404. 10.31202/ecjse.932313
Chicago PEKDEMİR Mustafa Ersin,Qader Ibrahim Nazem,AYDOGDU YILDIRIM,coşkun meltem Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles. (2021): 1395 - 1404. 10.31202/ecjse.932313
MLA PEKDEMİR Mustafa Ersin,Qader Ibrahim Nazem,AYDOGDU YILDIRIM,coşkun meltem Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles. , 2021, ss.1395 - 1404. 10.31202/ecjse.932313
AMA PEKDEMİR M,Qader I,AYDOGDU Y,coşkun m Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles. . 2021; 1395 - 1404. 10.31202/ecjse.932313
Vancouver PEKDEMİR M,Qader I,AYDOGDU Y,coşkun m Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles. . 2021; 1395 - 1404. 10.31202/ecjse.932313
IEEE PEKDEMİR M,Qader I,AYDOGDU Y,coşkun m "Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles." , ss.1395 - 1404, 2021. 10.31202/ecjse.932313
ISNAD PEKDEMİR, Mustafa Ersin vd. "Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles". (2021), 1395-1404. https://doi.org/10.31202/ecjse.932313
APA PEKDEMİR M, Qader I, AYDOGDU Y, coşkun m (2021). Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles. El-Cezerî Journal of Science and Engineering, 8(3), 1395 - 1404. 10.31202/ecjse.932313
Chicago PEKDEMİR Mustafa Ersin,Qader Ibrahim Nazem,AYDOGDU YILDIRIM,coşkun meltem Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles. El-Cezerî Journal of Science and Engineering 8, no.3 (2021): 1395 - 1404. 10.31202/ecjse.932313
MLA PEKDEMİR Mustafa Ersin,Qader Ibrahim Nazem,AYDOGDU YILDIRIM,coşkun meltem Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles. El-Cezerî Journal of Science and Engineering, vol.8, no.3, 2021, ss.1395 - 1404. 10.31202/ecjse.932313
AMA PEKDEMİR M,Qader I,AYDOGDU Y,coşkun m Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles. El-Cezerî Journal of Science and Engineering. 2021; 8(3): 1395 - 1404. 10.31202/ecjse.932313
Vancouver PEKDEMİR M,Qader I,AYDOGDU Y,coşkun m Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles. El-Cezerî Journal of Science and Engineering. 2021; 8(3): 1395 - 1404. 10.31202/ecjse.932313
IEEE PEKDEMİR M,Qader I,AYDOGDU Y,coşkun m "Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles." El-Cezerî Journal of Science and Engineering, 8, ss.1395 - 1404, 2021. 10.31202/ecjse.932313
ISNAD PEKDEMİR, Mustafa Ersin vd. "Exploring of Polyvinylchloride / Silicon Carbide Nanocomposites Containing Different Amounts of SiC Nanoparticles". El-Cezerî Journal of Science and Engineering 8/3 (2021), 1395-1404. https://doi.org/10.31202/ecjse.932313
Sayfa Oluşturulma Tarihi
24-04-2024 4:3

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