Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles

KARAKIŞLA, Meral; Saçak, Mehmet; OKAY, Zeynep; KALKAN ERDOĞAN, MERYEM; Karaca, Başar

doi:10.55730/1300-0527.3422

Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles

Zeynep OKAY, (Ankara Üniversitesi, Fen Fakültesi, Kimya Bölümü, Ankara, Türkiye)

Meryem ERDOĞAN, (Ankara Üniversitesi, Fen Fakültesi, Kimya Bölümü, Ankara, Türkiye)

Başar KARACA, (Ankara Üniversitesi, Fen Fakültesi, Biyoloji Bölümü, Ankara, Türkiye)

Meral KARAKIŞLA, (Ankara Üniversitesi, Fen Fakültesi, Kimya Bölümü, Ankara, Türkiye)

Mehmet SAÇAK (Ankara Üniversitesi, Fen Fakültesi, Kimya Bölümü, Ankara, Türkiye)

Turkish Journal of Chemistry

3 0

Yıl: 2022 Cilt: 46 Sayı: 4 Sayfa Aralığı: 1137 - 1151 Metin Dili: İngilizce DOI: 10.55730/1300-0527.3422 İndeks Tarihi: 06-12-2022

Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles

Öz:

This work reports the surface modification of polyacrylonitrile (PAN) fibers by graft copolymerization to ensure the decoration of homogenous and dense Ag nanoparticles. Two facile and subsequent modification processes resulted in a PAN fiber composite with an intact fibrous structure, sufficiently conductive for antistatic application and antibacterial activity. In the first step, some chemically attractive monomers and monomer mixtures, such as acrylic acid (AA), AA-itaconic acid (AA-IA), AA-acrylamide (AA-AAm), were introduced to the fiber surface by grafting. The grafting process was evidenced by FTIR, $^1H-NMR$, and SEM techniques. The second step aimed to form a chelate structure by $Ag^+$ ions with the coordination centers imparted to the PAN structure, and then, Ag nanoparticles (AgNPs) were decorated on the copolymer fiber surfaces by reducing with the NaBH4. The presence, distribution, and changes that occurred after the AgNPs decoration were also monitored by the SEM technique. It was obtained that the AgNPs could not be easily removed from the composites, which presented an appearance as if they were dyed with Ag. It was determined that the composite fibers gained a certain degree of conductivity with the surface resistivity value of $10^9$–$10^2$ Ω/$cm^2$. The antibacterial activity of the composites against E. coli and S. aureus was examined by the zone of inhibition test compared to their detergent-washed samples.

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APA	OKAY Z, KALKAN ERDOĞAN M, Karaca B, KARAKIŞLA M, Saçak M (2022). Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles. , 1137 - 1151. 10.55730/1300-0527.3422
Chicago	OKAY Zeynep,KALKAN ERDOĞAN MERYEM,Karaca Başar,KARAKIŞLA Meral,Saçak Mehmet Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles. (2022): 1137 - 1151. 10.55730/1300-0527.3422
MLA	OKAY Zeynep,KALKAN ERDOĞAN MERYEM,Karaca Başar,KARAKIŞLA Meral,Saçak Mehmet Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles. , 2022, ss.1137 - 1151. 10.55730/1300-0527.3422
AMA	OKAY Z,KALKAN ERDOĞAN M,Karaca B,KARAKIŞLA M,Saçak M Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles. . 2022; 1137 - 1151. 10.55730/1300-0527.3422
Vancouver	OKAY Z,KALKAN ERDOĞAN M,Karaca B,KARAKIŞLA M,Saçak M Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles. . 2022; 1137 - 1151. 10.55730/1300-0527.3422
IEEE	OKAY Z,KALKAN ERDOĞAN M,Karaca B,KARAKIŞLA M,Saçak M "Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles." , ss.1137 - 1151, 2022. 10.55730/1300-0527.3422
ISNAD	OKAY, Zeynep vd. "Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles". (2022), 1137-1151. https://doi.org/10.55730/1300-0527.3422

APA	OKAY Z, KALKAN ERDOĞAN M, Karaca B, KARAKIŞLA M, Saçak M (2022). Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles. Turkish Journal of Chemistry, 46(4), 1137 - 1151. 10.55730/1300-0527.3422
Chicago	OKAY Zeynep,KALKAN ERDOĞAN MERYEM,Karaca Başar,KARAKIŞLA Meral,Saçak Mehmet Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles. Turkish Journal of Chemistry 46, no.4 (2022): 1137 - 1151. 10.55730/1300-0527.3422
MLA	OKAY Zeynep,KALKAN ERDOĞAN MERYEM,Karaca Başar,KARAKIŞLA Meral,Saçak Mehmet Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles. Turkish Journal of Chemistry, vol.46, no.4, 2022, ss.1137 - 1151. 10.55730/1300-0527.3422
AMA	OKAY Z,KALKAN ERDOĞAN M,Karaca B,KARAKIŞLA M,Saçak M Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles. Turkish Journal of Chemistry. 2022; 46(4): 1137 - 1151. 10.55730/1300-0527.3422
Vancouver	OKAY Z,KALKAN ERDOĞAN M,Karaca B,KARAKIŞLA M,Saçak M Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles. Turkish Journal of Chemistry. 2022; 46(4): 1137 - 1151. 10.55730/1300-0527.3422
IEEE	OKAY Z,KALKAN ERDOĞAN M,Karaca B,KARAKIŞLA M,Saçak M "Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles." Turkish Journal of Chemistry, 46, ss.1137 - 1151, 2022. 10.55730/1300-0527.3422
ISNAD	OKAY, Zeynep vd. "Investigation of antibacterial properties of polyacrylonitrile fibers modified by new functional groups and silver nanoparticles". Turkish Journal of Chemistry 46/4 (2022), 1137-1151. https://doi.org/10.55730/1300-0527.3422