Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders

Erunal, Ebru

doi:10.55730/1300-0527.3425

Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders

Ebru Erunal (Çukurova Üniversitesi, Fen Edebiyat Fakültesi, Kimya Mühendisliği Bölümü, Adana, Türkiye)

Turkish Journal of Chemistry

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Yıl: 2022 Cilt: 46 Sayı: 4 Sayfa Aralığı: 1176 - 1184 Metin Dili: İngilizce DOI: 10.55730/1300-0527.3425 İndeks Tarihi: 06-12-2022

Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders

Öz:

The identification of the defects and secondary phases which significantly affect the material properties are of crucial importance. In this study, a systematic structure examination of $PbTiO_3$ and cobalt doped $PbTiO_3$ powder ceramics was carried out. X-ray diffraction (XRD), Fourier-transform infrared (FT-IR), Raman, and electron paramagnetic resonance (EPR) spectroscopies were applied along with nonsimultaneous thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The doped and undoped $PbTiO_3$ materials were synthesized via a practical sol-gel route that takes place at 50 °C. The perovskite formation for both materials was verified. The dislocation density of cobalt doped $PbTiO_3$ was found to be 0.0121 $nm^{–2}$ while it was 0.00239 $nm^{–2}$ for the undoped material. Besides, a strong strain effect was observed for cobalt doped PbTiO3 via XRD. This was attributed to the $Co_3O_4$ phase which was detected through EPR and FT-IR analyses. The formation of the $Co_3O_4$ phase during synthesis revealed the previously unexpected nonimproved ferroelectric behavior for cobalt doped PbTiO3. The dielectric constant and the dielectric loss (tan δ) of cobalt doped $PbTiO_3$ were estimated as 1066 and 0.8370, respectively.

Anahtar Kelime: $Co_3O_4$ Doping sol-gel synthesis perovskite $PbTiO_3$

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	Erunal E (2022). Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders. , 1176 - 1184. 10.55730/1300-0527.3425
Chicago	Erunal Ebru Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders. (2022): 1176 - 1184. 10.55730/1300-0527.3425
MLA	Erunal Ebru Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders. , 2022, ss.1176 - 1184. 10.55730/1300-0527.3425
AMA	Erunal E Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders. . 2022; 1176 - 1184. 10.55730/1300-0527.3425
Vancouver	Erunal E Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders. . 2022; 1176 - 1184. 10.55730/1300-0527.3425
IEEE	Erunal E "Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders." , ss.1176 - 1184, 2022. 10.55730/1300-0527.3425
ISNAD	Erunal, Ebru. "Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders". (2022), 1176-1184. https://doi.org/10.55730/1300-0527.3425

APA	Erunal E (2022). Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders. Turkish Journal of Chemistry, 46(4), 1176 - 1184. 10.55730/1300-0527.3425
Chicago	Erunal Ebru Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders. Turkish Journal of Chemistry 46, no.4 (2022): 1176 - 1184. 10.55730/1300-0527.3425
MLA	Erunal Ebru Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders. Turkish Journal of Chemistry, vol.46, no.4, 2022, ss.1176 - 1184. 10.55730/1300-0527.3425
AMA	Erunal E Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders. Turkish Journal of Chemistry. 2022; 46(4): 1176 - 1184. 10.55730/1300-0527.3425
Vancouver	Erunal E Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders. Turkish Journal of Chemistry. 2022; 46(4): 1176 - 1184. 10.55730/1300-0527.3425
IEEE	Erunal E "Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders." Turkish Journal of Chemistry, 46, ss.1176 - 1184, 2022. 10.55730/1300-0527.3425
ISNAD	Erunal, Ebru. "Detailed structure analyses on Cobalt doped Pb$TiO_3$ powders". Turkish Journal of Chemistry 46/4 (2022), 1176-1184. https://doi.org/10.55730/1300-0527.3425