Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation

Menzek, Abdullah; ARTUNÇ, TEKİN

doi:10.55730/1300-0527.3446

Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation

Tekin ARTUNÇ, (Atatürk Üniversitesi, Fen Fakültesi, Kimya Bölümü, Erzurum, Türkiye)

Abdullah MENZEK (Atatürk Üniversitesi, Fen Fakültesi, Kimya Bölümü, Erzurum, Türkiye)

Turkish Journal of Chemistry

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Yıl: 2022 Cilt: 46 Sayı: 5 Sayfa Aralığı: 1397 - 1404 Metin Dili: İngilizce DOI: 10.55730/1300-0527.3446 İndeks Tarihi: 06-12-2022

Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation

Öz:

Known 1,6-di(thiophen-2-yl)hexane-1,6-dione (2) and novel 1,7-di(thiophen-2-yl)heptane-1,7-dione (4) were obtained from the reactions of thiophene with the corresponding diacyl chlorides. Furthermore, compounds with furan and pyrrole units in place of thiophene units in compound 2 were obtained in the same way. Bromination of 2 and 4 gave bromides regioselectively. The reaction of each of the compounds 2 and 4 in HOAc medium yielded cyclocondensation products. In total, four known and eleven novel compounds were synthesized.

Anahtar Kelime: Acylation bromination cyclocondensation diketone thiophene

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	ARTUNÇ T, Menzek A (2022). Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation. , 1397 - 1404. 10.55730/1300-0527.3446
Chicago	ARTUNÇ TEKİN,Menzek Abdullah Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation. (2022): 1397 - 1404. 10.55730/1300-0527.3446
MLA	ARTUNÇ TEKİN,Menzek Abdullah Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation. , 2022, ss.1397 - 1404. 10.55730/1300-0527.3446
AMA	ARTUNÇ T,Menzek A Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation. . 2022; 1397 - 1404. 10.55730/1300-0527.3446
Vancouver	ARTUNÇ T,Menzek A Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation. . 2022; 1397 - 1404. 10.55730/1300-0527.3446
IEEE	ARTUNÇ T,Menzek A "Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation." , ss.1397 - 1404, 2022. 10.55730/1300-0527.3446
ISNAD	ARTUNÇ, TEKİN - Menzek, Abdullah. "Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation". (2022), 1397-1404. https://doi.org/10.55730/1300-0527.3446

APA	ARTUNÇ T, Menzek A (2022). Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation. Turkish Journal of Chemistry, 46(5), 1397 - 1404. 10.55730/1300-0527.3446
Chicago	ARTUNÇ TEKİN,Menzek Abdullah Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation. Turkish Journal of Chemistry 46, no.5 (2022): 1397 - 1404. 10.55730/1300-0527.3446
MLA	ARTUNÇ TEKİN,Menzek Abdullah Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation. Turkish Journal of Chemistry, vol.46, no.5, 2022, ss.1397 - 1404. 10.55730/1300-0527.3446
AMA	ARTUNÇ T,Menzek A Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation. Turkish Journal of Chemistry. 2022; 46(5): 1397 - 1404. 10.55730/1300-0527.3446
Vancouver	ARTUNÇ T,Menzek A Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation. Turkish Journal of Chemistry. 2022; 46(5): 1397 - 1404. 10.55730/1300-0527.3446
IEEE	ARTUNÇ T,Menzek A "Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation." Turkish Journal of Chemistry, 46, ss.1397 - 1404, 2022. 10.55730/1300-0527.3446
ISNAD	ARTUNÇ, TEKİN - Menzek, Abdullah. "Synthesis and reactions of di(thiophen-2-yl)alkane diones: Cyclocondensation". Turkish Journal of Chemistry 46/5 (2022), 1397-1404. https://doi.org/10.55730/1300-0527.3446