High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism

GÖKIRMAK SÖĞÜT, Eda; ÇELEBI, METIN

doi:10.55730/1300-0527.3462

High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism

METIN ÇELEBI, (Van Yüzüncü Yıl Üniversitesi, Van Güvenlik Meslek Yüksekokulu, Van, Türkiye)

Eda GÖKIRMAK SÖĞÜT (Van Yüzüncü Yıl Üniversitesi, Van Güvenlik Meslek Yüksekokulu, Van, Türkiye)

Turkish Journal of Chemistry

4 0

Yıl: 2022 Cilt: 46 Sayı: 5 Sayfa Aralığı: 1577 - 1593 Metin Dili: İngilizce DOI: 10.55730/1300-0527.3462 İndeks Tarihi: 07-12-2022

High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism

Öz:

GO-NH2 (amino functionalized graphene oxide) was synthesized by grafting (3-aminopropyl) triethoxysilane onto the surface GO (graphene oxide). The $GO-NH_2$ with a higher surface area and many active sites was characterized and its effectiveness in removing Rhod B dye and Ni(II) ions from wastewater by adsorption was observed. The effects of pH, time, and strange ions on the adsorption efficiency were investigated. The equilibrium isotherm data confirmed that it fits the Langmuir and Freundlich isotherm models. GO and $GO-NH_2$ exhibited high adsorption capacity (QM); 2500 (mg L^{–1}) and 3333 (mg L^{–1}) for Rhod B dye, and 312.5 $(mg L^{–1})$, and 714.28 (mg L^{–1}) for Ni(II) ions, respectively. The kinetics of adsorption was studied using pseudo-first-order, pseudo-second-order, intraparticle diffusion, and the Boyd model. It was found that the adsorption followed pseudo-second-order and film diffusion model are effective in this adsorption process. Adsorption mechanisms have been attributed to possible electrostatic attractions, hydrogen bonding, and interactions. In summary, the experimental results showed the synthesized GO and $GO-NH_2$ would be promising adsorbents to remove aqueous solutions contaminated with Rhod B dye and Ni(II) ions.

Anahtar Kelime: Adsorption amino functionalized graphene oxide grapheneoxide mechanism Ni (II) ions and rhodamine B dye.

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	ÇELEBI M, GÖKIRMAK SÖĞÜT E (2022). High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism. , 1577 - 1593. 10.55730/1300-0527.3462
Chicago	ÇELEBI METIN,GÖKIRMAK SÖĞÜT Eda High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism. (2022): 1577 - 1593. 10.55730/1300-0527.3462
MLA	ÇELEBI METIN,GÖKIRMAK SÖĞÜT Eda High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism. , 2022, ss.1577 - 1593. 10.55730/1300-0527.3462
AMA	ÇELEBI M,GÖKIRMAK SÖĞÜT E High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism. . 2022; 1577 - 1593. 10.55730/1300-0527.3462
Vancouver	ÇELEBI M,GÖKIRMAK SÖĞÜT E High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism. . 2022; 1577 - 1593. 10.55730/1300-0527.3462
IEEE	ÇELEBI M,GÖKIRMAK SÖĞÜT E "High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism." , ss.1577 - 1593, 2022. 10.55730/1300-0527.3462
ISNAD	ÇELEBI, METIN - GÖKIRMAK SÖĞÜT, Eda. "High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism". (2022), 1577-1593. https://doi.org/10.55730/1300-0527.3462

APA	ÇELEBI M, GÖKIRMAK SÖĞÜT E (2022). High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism. Turkish Journal of Chemistry, 46(5), 1577 - 1593. 10.55730/1300-0527.3462
Chicago	ÇELEBI METIN,GÖKIRMAK SÖĞÜT Eda High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism. Turkish Journal of Chemistry 46, no.5 (2022): 1577 - 1593. 10.55730/1300-0527.3462
MLA	ÇELEBI METIN,GÖKIRMAK SÖĞÜT Eda High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism. Turkish Journal of Chemistry, vol.46, no.5, 2022, ss.1577 - 1593. 10.55730/1300-0527.3462
AMA	ÇELEBI M,GÖKIRMAK SÖĞÜT E High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism. Turkish Journal of Chemistry. 2022; 46(5): 1577 - 1593. 10.55730/1300-0527.3462
Vancouver	ÇELEBI M,GÖKIRMAK SÖĞÜT E High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism. Turkish Journal of Chemistry. 2022; 46(5): 1577 - 1593. 10.55730/1300-0527.3462
IEEE	ÇELEBI M,GÖKIRMAK SÖĞÜT E "High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism." Turkish Journal of Chemistry, 46, ss.1577 - 1593, 2022. 10.55730/1300-0527.3462
ISNAD	ÇELEBI, METIN - GÖKIRMAK SÖĞÜT, Eda. "High-efficiency removal of cationic dye and heavy metal ions from aqueous solution using amino-functionalized graphene oxide, adsorption isotherms, kinetics studies, and mechanism". Turkish Journal of Chemistry 46/5 (2022), 1577-1593. https://doi.org/10.55730/1300-0527.3462