Yıl: 2022 Cilt: 46 Sayı: 6 Sayfa Aralığı: 1755 - 1775 Metin Dili: İngilizce DOI: 10.55730/1300-0527.3479 İndeks Tarihi: 30-12-2022

Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction

Öz:
Sample preparation is the crucial and most challenging part of analytical chemistry for the speciation of environmental pollutants’ traces. Along with the development of the sample preparation methods, the ionic liquid-based microextraction technique plays an important role. Due to the unequivocally unique “green” characteristic of ionic liquids (ILs), they owe their tunable properties, such as highly selective and high reaction efficiency, reusability, and good thermal stability, to present advancements in the sample preparation process. The ionic liquid-based microextraction techniques miniaturize the sample preparation process. Liquid phase microextraction intermediate solvents, desorption solvent extractants, and mediators have been used. They are quoting the benefits and limitations of each method. A few essential sample preparation methods covered the microextraction technique. In this context, miniaturized microextraction methods have been developed. They are generally used for their unlimited positive features, including easy, simple, and environmentally friendly; they also extract inorganic and organic species with low-cost instrumentation. This review advances the sample preparation process using ILs-based liquid phase microextraction as an intermediate solvent, extractant desorption, and mediator solvents.
Anahtar Kelime: Sample preparation methods ionic liquids liquid-phase microextraction toxic pollutants

Belge Türü: Makale Makale Türü: Derleme Erişim Türü: Erişime Açık
  • 1. Namiesnik J. Pro-ecological education: Chemical faculty of the Technical University of Gdańsk, Poland. Environmental Science and Pollution Research 1999; 6: 243-244.
  • 2. Spietelun A, Marcinkowski Ł, de la Guardia M, Namieśnik J. Recent developments and future trends in solid phase microextraction techniques towards green analytical chemistry. Journal of Chromatography A 2013; 1321: 1-13.
  • 3. Spietelun A, Marcinkowsk, Ł, de la Guardia M, Namieśnik J. Green aspects, developments and perspectives of liquid phase microextraction techniques. Talanta 2014; 119: 34-45.
  • 4. Ozdemir S, Yalcin MS, Kilinc E, Soylak M. Magnetic solid-phase extraction based on Coriolus versicolor-immobilized gamma-Fe2O3 nanoparticles for preconcentration and determination of Al (III) in water and food samples. Turkish Journal of Chemistry 2019; 43: 1217-1228.
  • 5. Wierucka M, Biziuk M. Application of magnetic nanoparticles for magnetic solid-phase extraction in preparing biological, environmental and food samples. TrAC Trends in Analytical Chemistry 2019; 59: 50-58.
  • 6. Ozkantar N, Yilmaz E, Soylak M, Tuzen M. Pyrocatechol violet impregnated magnetic graphene oxide for magnetic solid phase microextraction of copper in water, black tea and diet supplements. Food Chemistry 2020; 321, 126737.
  • 7. Saydan Kanberoglu G, Yilmaz E, Soylak M. Fabrication and characterization of SiO2@ Fe3O4@ nanodiamonds for vortex-assisted magnetic solid-phase extraction of lead in cigarette samples prior to FAAS detection. Journal of the Iranian Chemical Society 2020; 17-1627-1634.
  • 8. Soylak M, Elci L, Dogan M. A sorbent extraction procedure for the preconcentration of gold, silver and palladium on an activated carbon column. Analytical Letters 2000; 33:513-525.
  • 9. Tuzen M, Soylak M, Citak D, Ferreira HS, Korn MG et al. A preconcentration system for determination of copper and nickel in water and food samples employing flame atomic absorption spectrometry. Journal of Hazardous Materials 2009; 162: 1041-1045.
  • 10. Ulusoy H İ, Yılmaz E, Soylak M. Magnetic solid phase extraction of trace paracetamol and caffeine in synthetic urine and wastewater samples by a using core shell hybrid material consisting of graphene oxide/multiwalled carbon nanotube/Fe3O4/SiO2. Microchemical Journal 2019; 145: 843-851.
  • 11. Yilmaz E, Soylak M. Ultrasound assisted-deep eutectic solvent based on emulsification liquid phase microextraction combined with microsample injection flame atomic absorption spectrometry for valence speciation of chromium (III/VI) in environmental samples. Talanta 2016; 160: 680-685.
  • 12. de La Guardia M, Ruzicka J. Guest editorial. Towards environmentally conscientious analytical chemistry through miniaturization, containment and reagent replacement. Analyst 1995; 120: 17N-17N.
  • 13. Yuvali D, Narin I, Soylak M, Yilmaz E. Green synthesis of magnetic carbon nanodot/graphene oxide hybrid material (Fe3O4@ C-nanodot@ GO) for magnetic solid phase extraction of ibuprofen in human blood samples prior to HPLC-DAD determination. Journal of Pharmaceutical and Biomedical Analysis 2020; 179: 113001.
  • 14. Jagirani M S, Soylak M. A review: Recent advances in solid phase microextraction of toxic pollutants using nanotechnology scenario. Microchemical Journal 2020; 159: 105436.
  • 15. Soylak M, Ozalp O, Uzcan F. Magnetic Nanomaterials for the Removal, Separation and Preconcentration of Organic and Inorganic Pollutants at Trace Levels and their Practical Applications: A Review. Trends in Environmental Analytical Chemistry 2021; 29: e00109.
  • 16. Soylak M, Jagirani MS. Extraction techniques used for the removal of pharmaceuticals from environmental samples. Pharmaceutical Sciences 2021; 27: 450-452.
  • 17. Hallett JP, Welton T. Room-temperature ionic liquids: solvents for synthesis and catalysis. Chemical Reviews 2011; 111: 3508-3576.
  • 18. Yavir K, Marcinkowski Ł, Marcinkowska R, Namieśnik J, Kloskowski A. Analytical applications and physicochemical properties of ionic liquid-based hybrid materials: a review. Analytica Chimica Acta 2019; 1054: 1-16.
  • 19. Martinis EM, Berton P, Monasterio RP, Wuilloud RG. Emerging ionic liquid-based techniques for total-metal and metal-speciation analysis. TRAC Trends in Analytical Chemistry 2010; 29: 1184-1201.
  • 20. Inman D, Lovering DG. Ionic liquids: Springer Science & Business Media; 2013.
  • 21. Copeland JL. Transport properties of ionic liquids: Gordon & Breach Publishing Group; 1974.
  • 22. Petkovic M, Seddon KR, Rebelo LPN, Pereira CS. Ionic liquids: a pathway to environmental acceptability. Chemical Society Reviews 2011; 40: 1383-1403.
  • 23. Khodadadi S, Konoz E, Ezabadi A, Niazi A. Magnetic Solid-Phase Extraction using Ionic Liquid-Modified Magnetic Nanoparticles for The Simultaneous Extraction of Cadmium and Lead in Milk Samples Evaluation of Measurement Uncertainty. Journal of the Mexican Chemical Society 2021; 65: 457-468.
  • 24. Alham A, Ibraimov A, Alimzhanova M, Mamedova M. Natural Material Shungite as Solid-Phase Extraction Sorbent for the Extraction of Red Synthetic Dye Ponceau 4R from Tap Water, Wine, and Juice. Food Analytical Methods 2022; 15: 707-716.
  • 25. Castillo J, Coll MT, Fortuny A, Donoso PN, Sepúlveda R et al. Cu (II) extraction using quaternary ammonium and quaternary phosphonium based ionic liquid. Hydrometallurgy 2014; 141: 89-96.
  • 26. Sun X, Luo H, Dai S. Solvent extraction of rare-earth ions based on functionalized ionic liquids. Talanta 2012; 90: 132-137.
  • 27. Coll M, Fortuny A, Kedari C, Sastre A. Studies on the extraction of Co (II) and Ni (II) from aqueous chloride solutions using Primene JMT-Cyanex272 ionic liquid extractant. Hydrometallurgy 2012; 125: 24-28.
  • 28. Tong Y, Wang C, Li J, Yang Y. Extraction mechanism, behavior and stripping of Pd (II) by pyridinium-based ionic liquid from hydrochloric acid medium. Hydrometallurgy 2014; 147: 164-169.
  • 29. Stojanovic A, Keppler BK. Ionic liquids as extracting agents for heavy metals. Separation Science and Technology 2012; 47: 189-203.
  • 30. Wellens S, Vander Hoogerstraete T, Möller C, Thijs B, Luyten J et al. Dissolution of metal oxides in an acid-saturated ionic liquid solution and investigation of the back-extraction behaviour to the aqueous phase. Hydrometallurgy 2014; 144: 27-33.
  • 31. Zhou Y, Boudesocque S, Mohamadou A, Dupont L. Extraction of metal ions with task specific ionic liquids: influence of a coordinating anion. Separation Science and Technology 2015; 50: 38-44.
  • 32. Papaiconomou N, Svecova L, Bonnaud C, Cathelin L, Billard I, Chainet E. Possibilities and limitations in separating Pt (IV) from Pd (II) combining imidazolium and phosphonium ionic liquids. Dalton Transactions 2015; 44: 20131-20138.
  • 33. Ozdemir S, Yalcin MS, Kilinc E, Soylak M. Boletus edulis loaded with γ-Fe2O3 nanoparticles as a magnetic sorbent for preconcentration of Co (II) and Sn (II) prior to their determination by ICP-OES. Microchimica Acta 2018; 185: 73.
  • 34. Saracoglu S, Soylak M, Elçi L. Enrichment and separation of traces of cadmium, chromium, lead and manganese ions in urine by using magnesium hydroxide coprecipitation method. Trace Elements and Electrolytes 2001; 18: 129-133. UZCAN et al. / Turk J Chem1767
  • 35. Ranke J, Müller A, Bottin-Weber U, Stock F, Stolte S et al. Lipophilicity parameters for ionic liquid cations and their correlation to in vitro cytotoxicity. Ecotoxicology and Environmental Safety 2007; 67: 430-438.
  • 36. Kavitha T, Attri P, Venkatesu P, Devi RR, Hofman T. Influence of alkyl chain length and temperature on thermophysical properties of ammonium-based ionic liquids with molecular solvent. The Journal of Physical Chemistry B 2012; 116: 4561-4574.
  • 37. Soylak M. Solid phase extraction of trace metal ions in drinking water samples from Kayseri-Turkey. Journal of Trace and Microprobe Techniques 2000; 18: 397-403.
  • 38. Soylak M, Şahin U, Elçi L. Spectrophotometric determination of molybdenum in steel samples utilizing selective sorbent extraction on Amberlite XAD-8 resin. Analytica Chimica Acta 1996; 322: 111-115.
  • 39. Zheng Y, Huang X, Ling Y, Huang W, Wang J et al. Ultrasonic-enhanced preconcentration of trace Pb (II) using hydrophobic, lighter-than- water ionic liquid microextraction combined with solidification of the aqueous solution prior to detection by graphite furnace atomic absorption spectrometry in human fluids. Spectrochimica Acta Part B: Atomic Spectroscopy 2019; 157: 27-36.
  • 40. Singh SK, Savoy AW. Ionic liquids synthesis and applications: An overview. Journal of Molecular Liquids 2020; 297: 112038.
  • 41. He, J Yang J, Tariq SM, Duan C, Zhao Y. Comparative investigation on copper leaching efficiency from waste mobile phones using various types of ionic liquids. Journal of Cleaner Production 2020; 256: 120368.
  • 42. Wier JTP, Hurley FH. Electrodeposition of aluminum. US patenrs patent no: 2, 446, 349; (1948).
  • 43. Toral A, De Los Rios A, Hernández F, Janssen M. Cross-linked Candida antarctica lipase B is active in denaturing ionic liquids. Enzyme and Microbial Technology 2007; 40: 1095-1099.
  • 44. Marsousi S, Karimi-Sabet J, Moosavian MA, Amini Y. Liquid-liquid extraction of calcium using ionic liquids in spiral microfluidics. Chemical Engineering Journal 2019; 356: 492-505.
  • 45. Germani R, Mancini MV, Savelli G, Spreti N. Mercury extraction by ionic liquids: temperature and alkyl chain length effect. Tetrahedron Letters 2007; 48: 1767-1769.
  • 46. Pham TPT, Cho C-W, Yun YS. Environmental fate and toxicity of ionic liquids: a review. Water Research 2010; 44: 352-372.
  • 47. Isosaari P, Srivastava V, Sillanpää M. Ionic liquid-based water treatment technologies for organic pollutants: Current status and future prospects of ionic liquid mediated technologies. Science of the Total Environment 2019; 690: 604-619.
  • 48. Barakat M. New trends in removing heavy metals from industrial wastewater. Arabian Journal of Chemistry 2011; 4: 361-377.
  • 49. Bhatluri KK, Chakraborty S, Manna MS, Ghoshal AK, Saha P. Separation of toxic heavy metals from its aqueous solution using environmentally benign vegetable oil as liquid membrane. RSC Advances 2015; 5: 88331-88338.
  • 50. Ozcan S, Tor A, Aydin ME. Determination of polycyclic aromatic hydrocarbons in waters by ultrasound-assisted emulsification- microextraction and gas chromatography–mass spectrometry. Analytica Chimica Acta 2010; 665: 193-199.
  • 51. Lambropoulou DA, Albanis TA. Liquid-phase micro-extraction techniques in pesticide residue analysis. Journal of Biochemical and Biophysical Methods 2007; 70: 195-228.
  • 52. Liu J F, Chi Y G, Jiang GB. Screening the extractability of some typical environmental pollutants by ionic liquids in liquid phase microextraction. Journal of Separation Science 2005; 28: 87-91.
  • 53. Wang Q, Qiu H, Li J, Liu X, Jiang S. On-line coupling of ionic liquid-based single-drop microextraction with capillary electrophoresis for sensitive detection of phenols. Journal of Chromatography A 2010; 1217: 5434-5439.
  • 54. Xia L, Li X, Wu Y, Hu B, Chen R. Ionic liquids based single drop microextraction combined with electrothermal vaporization inductively coupled plasma mass spectrometry for determination of Co, Hg and Pb in biological and environmental samples. Spectrochimica Acta Part B: Atomic Spectroscopy 2008; 63: 1290-1296.
  • 55. Pena-Pereira F, Lavilla I, Bendicho C, Vidal L, Canals A. Speciation of mercury by ionic liquid-based single-drop microextraction combined with high-performance liquid chromatography-photodiode array detection, Talanta 2009; 78: 537-541.
  • 56. Manzoori JL, Amjadi M, Abulhassani J. Ultra-trace determination of lead in water and food samples by using ionic liquid-based single drop microextraction-electrothermal atomic absorption spectrometry. Analytica Chimica Acta 2009; 644: 48-52.
  • 57. Peng J-F, Liu JF, Hu XL, Jiang GB. Direct determination of chlorophenols in environmental water samples by hollow fiber supported ionic liquid membrane extraction coupled with high-performance liquid chromatography. Journal of Chromatography A 2007; 1139: 165-170.
  • 58. Tao Y, Liu JF, Hu XL, Li HC, Wang T et al. Hollow fiber supported ionic liquid membrane microextraction for determination of sulfonamides in environmental water samples by high-performance liquid chromatography. Journal of Chromatography A 2009; 1216: 6259-6266.
  • 59. Abulhassani J, Manzoori J L, Amjadi M. Hollow fiber based-liquid phase microextraction using ionic liquid solvent for preconcentration of lead and nickel from environmental and biological samples prior to determination by electrothermal atomic absorption spectrometry. Journal of Hazardous Materials 2010; 176: 481-486.
  • 60. Ma X, Huang M, Li Z, Wu J. Hollow fiber supported liquid-phase microextraction using ionic liquid as extractant for preconcentration of benzene, toluene, ethylbenzene and xylenes from water sample with gas chromatography-hydrogen flame ionization detection. Journal of Hazardous Materials 2011; 194: 24-29.
  • 61. Ge D, Lee HK. Ionic liquid based hollow fiber supported liquid phase microextraction of ultraviolet filters. Journal of Chromatography A 2012; 1229: 1-5.
  • 62. Basheer C, Alnedhary AA, Rao BM, Balasubramanian R, Lee HK. Ionic liquid supported three-phase liquid–liquid–liquid microextraction as a sample preparation technique for aliphatic and aromatic hydrocarbons prior to gas chromatography-mass spectrometry. Journal of Chromatography A 2008; 1210: 19-24.
  • 63. Zeng C, Hu Y, Luo J. Ionic liquid-based hollow fiber supported liquid membrane extraction combined with thermospray flame furnace AAS for the determination of cadmium. Microchimica Acta 2012; 177: 53-58.
  • 64. Liu W, Wei Z, Zhang Q, Wu F, Lin Z et al. Novel multifunctional acceptor phase additive of water-miscible ionic liquid in hollow-fiber protected liquid phase microextraction. Talanta 2012; 88: 43-49.
  • 65. Fortunato R, Afonso CA, Benavente J, Rodriguez-Castellón E, Crespo JG. Stability of supported ionic liquid membranes as studied by X-ray photoelectron spectroscopy. Journal of Membrane Science 2005; 256: 216-223.
  • 66. Fortunato R, Afonso CA, Reis M, Crespo JG. Supported liquid membranes using ionic liquids: study of stability and transport mechanisms. Journal of Membrane Science 2004; 242: 197-209.
  • 67. Armstrong DW, He L, Liu YS. Examination of ionic liquids and their interaction with molecules, when used as stationary phases in gas chromatography. Analytical Chemistry 1999; 71: 3873-3876.
  • 68. Abejón R, Pérez-Acebo H, Garea A. A bibliometric analysis of research on supported ionic liquid membranes during the 1995–2015 period: Study of the main applications and trending topics. Membranes 2017; 7: 63.
  • 69. Branco LC, Crespo JG, Afonso CA. Highly selective transport of organic compounds by using supported liquid membranes based on ionic liquids. Angewandte Chemie International Edition 2002; 41: 2771-2773.
  • 70. Matsumoto M, Inomoto Y, Kondo K. Selective separation of aromatic hydrocarbons through supported liquid membranes based on ionic liquids. Journal of Membrane Science 2005; 246: 77-81.
  • 71. Fu XM, Dai SG. Synthesis of ionic liquids containing the hydroxyl functionality for extracting nonylphenol and octylphenol in water. Synthetic Communications 2011; 41: 2455-2460.
  • 72. Shah F, Kazi TG, Afridi H I, Soylak M. Temperature controlled ionic liquid-dispersive liquid phase microextraction for determination of trace lead level in blood samples prior to analysis by flame atomic absorption spectrometry with multivariate optimization. Microchemical Journal 2012; 101: 5-10.
  • 73. Santos LM, Canongia Lopes JN, Coutinho JA, Esperança JM, Gomes LR et al. Ionic liquids: first direct determination of their cohesive energy. Journal of the American Chemical Society 2007; 129: 284-285.
  • 74. Shamsuri AA, Abdullah DK. Ionic liquids: Preparations and limitations. Makara Journal of Science 2011; 14:101-106.
  • 75. Aguilera-Herrador E, Lucena R, Cárdenas S, Valcárcel M. Sample treatments based on ionic liquids A. Kokorin. Ionic Liquids: Applications and Perspectives 2011; 181-206.
  • 76. Aydin F, Yilmaz E, Ölmez E, Soylak M. Cu2O-CuO ball like/multiwalled carbon nanotube hybrid for fast and effective ultrasound-assisted solid phase extraction of uranium at ultra-trace level prior to ICP-MS detection. Talanta 2020; 207: 120295.
  • 77. Aydin F, Yilmaz E, Soylak M. A simple and novel deep eutectic solvent based ultrasound-assisted emulsification liquid phase microextraction method for malachite green in farmed and ornamental aquarium fish water samples. Microchemical Journal 2017; 132: 280-285.
  • 78. Elci L, Soylak M, Uzun A, Büyükpatır E, Doğan M. Determination of trace impurities in some nickel compounds by flame atomic absorption spectrometry after solid phase extraction using Amberlite XAD-16 resin. Fresenius’ Journal of Analytical Chemistry 2000; 368: 358-361.
  • 79. Erbas Z, Soylak M, Ozdemir S, Kilinc E. Fe3O4@ SiO2@ Bacillus pumilis: magnetised solid phase bio-extractor for preconcentration of Pb (II) and Cu (II) from water samples. International Journal of Environmental Analytical Chemistry 2019; 99: 1112-1122.
  • 80. Habila MA, ALOthman ZA, El-Toni AM, Labis JP, Soylak M. Synthesis and application of Fe3O4@SiO2@TiO2 for photocatalytic decomposition of organic matrix simultaneously with magnetic solid phase extraction of heavy metals prior to ICP-MS analysis. Talanta 2016; 154: 539-547.
  • 81. Ozdemir S, Mohamedsaid SA, Kilinc E, Yıldırım A, Soylak M. Application of magnetized fungal solid phase extractor with Fe2O3 nanoparticle for determination and preconcentration of Co (II) and Hg (II) from natural water samples. Microchemical Journal 2018; 143: 198-204.
  • 82. Soylak M, Elci L, Narin I, Dogan M. Separation and Preconcentration of Gold, Silver and Palladium from Some Aluminum and Manganese Salts on an Activated Carbon Column. Asian Journal of Chemistry 2001; 13: 699-703.
  • 83. Zaijun L, Xiulan S, Junkang L. (Ed: Alexander Kokorin) Ionic liquid as novel solvent for extraction and separation in analytical chemistry Ionic liquids: Applications and perspectives, pp. 153-180, IntechOpen, 2011
  • 84. Narin I, Soylak M, Elci L, Dogan M. Separation and Enrichment of Chromium, Copper, Nickel and Lead in Surface Seawater Samples on a Column Filled with Amberlite XAD-2000. Analytical Letters 2001; 34: 1935-1947.
  • 85. Koçoglu ES, Yılmaz Ö, Bakırdere EG, Bakırdere S. Quantification of palladium in wastewater samples by matrix-matching calibration strategy assisted deep eutectic solvent based microextraction. Environmental Monitoring and Assessment 2021; 193: 344.
  • 86. Kartoglu B, Tezgit E, Yiğit A, Zaman BT, Bakırdere EG et al. Determination of trace nickel after complexation with a schiff base by switchable solvent–liquid phase microextraction (SS-LPME) and flame atomic absorption spectrometry (FAAS). Analytical Letters 2022; 55: 1017-1026.
  • 87. Dalmaz A, Özak SS. DES-Based Vortex-Assisted Liquid-Liquid Microextraction Procedure Developed for the Determination of Paraben Preservatives in Mouthwashes. Microchemical Journal 2022: 179, 107445.
  • 88. Erarpat S, Bodur S, Öner M, Günkara ÖT, Bakırdere S. A simple and efficient derivatization strategy combined with switchable solvent liquid–liquid microextraction hydroxychloroquine methyl acetate d 3 based quadruple isotope dilution gas chromatography mass spectrometry for the determination of hydroxychloroquine sulfate in biological fluids. Rapid Communications in Mass Spectrometry 2022; 36: e9282.
  • 89. Rezaee M, Tajer-Mohammad-Ghazvini P. Rapid and efficient determination of zinc in water samples by graphite furnace atomic absorption spectrometry after homogeneous liquid-liquid microextraction via flotation assistance. Bulletin of the Chemical Society of Ethiopia 2022; 36: 1-11.
  • 90. Song X, Ye M, Tang X, Wang C. Ionic liquids dispersive liquid–liquid microextraction and HPLC atomic fluorescence spectrometric determination of mercury species in environmental waters. Journal of Separation Science 2013; 36: 414-420.
  • 91. Rabieh S, Bagheri M, Planer-Friedrich B. Speciation of arsenite and arsenate by electrothermal AAS following ionic liquid dispersive liquid-liquid microextraction. Microchimica Acta 2013; 180: 415-421.
  • 92. Chamsaz M, Atarodi A, Eftekhari M, Asadpour S, Adibi M. Vortex-assisted ionic liquid microextraction coupled to flame atomic absorption spectrometry for determination of trace levels of cadmium in real samples. Journal of Advanced Research 2013; 4: 35-41.
  • 93. Hu B, He M, Chen B, Xia L. Liquid phase microextraction for the analysis of trace elements and their speciation. Spectrochimica Acta Part B: Atomic Spectroscopy 2013; 86: 14-30.
  • 94. El-Shahawi M, Al-Saidi H. Dispersive liquid-liquid microextraction for chemical speciation and determination of ultra-trace concentrations of metal ions. TRAC Trends in Analytical Chemistry 2013; 44: 12-24.
  • 95. Asensio-Ramos M, Ravelo-Pérez LM, González-Curbelo MÁ, Hernández-Borges J. Liquid phase microextraction applications in food analysis. Journal of Chromatography A 2011; 1218: 7415-7437.
  • 96. Elik A, Bingöl D, Altunay N. Ionic hydrophobic deep eutectic solvents in developing air-assisted liquid-phase microextraction based on experimental design: Application to flame atomic absorption spectrometry determination of cobalt in liquid and solid samples. Food Chemistry 2021; 350: 129237.
  • 97. Al Othman Z, Unsal YE, Habila M, Shabaka A, Tuzen M, Soylak M. Determination of copper in food and water by dispersive liquid-liquid microextraction and flame atomic absorption spectrometry. Analytical Letters 2015; 48: 1738-1750.
  • 98. Yilmaz E, Soylak M. Latest trends, green aspects, and innovations in liquid-phase--based microextraction techniques: a review. Turkish Journal of Chemistry 2016; 40: 868-893.
  • 99. Kandhro GA, Soylak M, Kazi TG, Yilmaz E. Enrichment of copper as 1-(2-pyridylazo)-2-naphthol complex by the combination of dispersive liquid–liquid microextraction/flame atomic absorption spectrometry. Journal of AOAC International 2014; 97: 205-210.
  • 100. Soylak M, Topalak Z. Enrichment-separation and determinations of cadmium(II) and lead(II)-1-phenyl-1H-tetrazole-5-thiol chelates on Diaion SP-207 by solid phase extraction-flame atomic absorption spectrometry. Arabian Journal of Chemistry 2015; 8: 720-725.
  • 101. Borahan T, Zaman BT, Arıca Polat BS, Bakırdere EG, Bakırdere S. An accurate and sensitive effervescence-assisted liquid phase microextraction method for the determination of cobalt after a Schiff base complexation by slotted quartz tube-flame atomic absorption spectrophotometry in urine samples. Analytical Methods 2021; 13: 703-711.
  • 102. Mohanna E, Moinfar S, Mohammadi S, Khayatian G. A Continuous Sample Drop Flow-Based Microextraction Method for Spectrophotometric Determination of Cobalt with 1-(2-Pyridylazo)-2-Naphthol in Water Samples, Journal of Analytical Chemistry 2021; 76: 172-179.
  • 103. Yahya M, Kesekler S, Durukan İ, Arpa Ç. Determination of prohibited lead and cadmium traces in hair dyes and henna samples using ultrasound assisted-deep eutectic solvent-based liquid phase microextraction followed by microsampling-flame atomic absorption spectrometry. Analytical Methods 2021; 13: 1058-1068.
  • 104. Stanisz E, Zgoła-Grześkowiak A. In situ metathesis ionic liquid formation dispersive liquid–liquid microextraction for copper determination in water samples by electrothermal atomic absorption spectrometry. Talanta 2013; 115: 178-183.
  • 105. 105.Khan S, Kazi TG, Soylak M. Ionic liquid-based ultrasound-assisted emulsification microextraction of cadmium in biological samples: Optimization by a multivariate approach. Analytical Letters 2015; 48: 1751-1766.
  • 106. Jalbani N, Soylak M. Ligandless ultrasonic-assisted and ionic liquid-based dispersive liquid–liquid microextraction of copper, nickel and lead in different food samples. Food Chemistry 2015; 167: 433-437.
  • 107. Bagda E, Altundag H, Tüzen M, Soylak M. A novel selective deep eutectic solvent extraction method for versatile determination of copper in sediment samples by ICP-OES. Bulletin of Environmental Contamination and Toxicology 2017; 99: 264-269.
  • 108. Yilmaz E, Soylak M. Ionic liquid-linked dual magnetic microextraction of lead (II) from environmental samples prior to its micro-sampling flame atomic absorption spectrometric determination. Talanta 2013; 116: 882-886.
  • 109. Khezeli T, Ghaedi M, Daneshfar A, Bahrani S, Asfaram A et al. Ionic liquids in separation and preconcentration of organic and inorganic species. New Generation Green Solvents for Separation and Preconcentration of Organic and Inorganic Species: Elsevier; 2020, pp. 267- 318.
  • 110. Tuzen M, Uluozlu OD, Mendil D, Soylak M, Machado LO et al. A simple, rapid and green ultrasound assisted and ionic liquid dispersive microextraction procedure for the determination of tin in foods employing ETAAS. Food Chemistry 2018; 245: 380-384.
  • 111. Unsal Y E, Soylak M, Tuzen M. Ultrasound-assisted ionic liquid-based dispersive liquid–liquid microextraction for preconcentration of patent blue V and its determination in food samples by UV–visible spectrophotometry. Environmental Monitoring and Assessment 2015; 187: 203.
  • 112. Soylak M, Yilmaz E. Determination of cadmium in fruit and vegetables by ionic liquid magnetic microextraction and flame atomic absorption spectrometry. Analytical Letters 2015; 48: 464-476.
  • 113. Unsal YE, Tuzen M, Soylak M. Ultrasound-Assisted Ionic Liquid-Dispersive Liquid–Liquid of Curcumin in Food Samples Microextraction and Its Spectrophotometric Determination. Journal of AOAC International 2019; 102: 217-221.
  • 114. Khan S, Kazi T G, Soylak M. Rapid ionic liquid-based ultrasound assisted dual magnetic microextraction to preconcentrate and separate cadmium-4-(2-thiazolylazo)-resorcinol complex from environmental and biological samples. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2014; 123: 194-199.
  • 115. Alothman ZA, Habila MA, Yilmaz E, Soylak M, Alfadul SM. Ultrasonic supramolecular microextration of nickel (II) as N,N′-Dihydroxy- 1,2-cyclohexanediimine chelates from water, tobacco and fertilizer samples before FAAS determination. Journal of Molecular Liquids 2016; 221: 773-777.
  • 116. Soylak M, Elci L, Dogan M. Flame atomic absorption spectrometric determination of cadmium, cobalt, copper, lead and nickel in chemical grade potassium salts after an enrichment and separation procedure. Journal of Trace and Microprobe Techniques 1999;17: 149-156.
  • 117. Chaikhan P, Udnan Y, Ampiah-Bonney RJ, Chaiyasith WC. Air-assisted solvent terminated dispersive liquid–liquid microextraction (AA-ST-DLLME) for the determination of lead in water and beverage samples by graphite furnace atomic absorption spectrometry. Microchemical Journal 2021; 162: 105828.
  • 118. El Sheikh R, Hassan WS, Youssef AM, Hameed AM, Subaihi A et al. Eco-friendlyultrasound-assisted ionic liquid-based dispersive liquid- liquid microextraction of nickel in water, food and tobacco samples prior to FAAS determination. International Journal of Environmental Analytical Chemistry 2020; 4: 899-910.
  • 119. Chromá R, Vilková M, Shepa I, Makoś-Chełstowska P, Andruch V. Investigation of tetrabutylammonium bromide-glycerol-based deep eutectic solvents and their mixtures with water by spectroscopic techniques. Journal of Molecular Liquids 2021; 330: 115617.
  • 120. Ji Y, Zhao M, Li A, Zhao L. Hydrophobic deep eutectic solvent-based ultrasonic-assisted dispersive liquid-liquid microextraction for preconcentration and determination of trace cadmium and arsenic in wine samples. Microchemical Journal 2021; 164: 105974.
  • 121. Dai S, Ju Y, Barnes C. Solvent extraction of strontium nitrate by a crown ether using room-temperature ionic liquids. Journal of the Chemical Society, Dalton Transactions 1999; 8: 1201-1202.
  • 122. Visser AE, Swatloski RP, Reichert WM, Griffin ST, Rogers RD. Traditional extractants in nontraditional solvents: Groups 1 and 2 extraction by crown ethers in room-temperature ionic liquids. Industrial & Engineering Chemistry Research 2000; 39: 3596-3604.
  • 123. Wei G-T, Yang Z, Chen CJ. Room temperature ionic liquid as a novel medium for liquid/liquid extraction of metal ions. Analytica Chimica Acta 2003; 488: 183-192. d
  • 124. Hirayama N, Deguchi M, Kawasumi H, Honjo T. Use of 1-alkyl-3-methylimidazolium hexafluorophosphate room temperature ionic liquids as chelate extraction solvent with 4, 4, 4-trifluoro-1-(2-thienyl)-1, 3-butanedione. Talanta 2005; 65: 255-260.
  • 125. Li Z, Wei Q, Yuan R, Zhou X, Liu H et al. A new room temperature ionic liquid 1-butyl-3-trimethylsilylimidazolium hexafluorophosphate as a solvent for extraction and preconcentration of mercury with determination by cold vapor atomic absorption spectrometry. Talanta 2007; 71: 68-72.
  • 126. Dadfarnia S, Shabani AMH, Bidabadi MS, Jafari AA. A novel ionic liquid/micro-volume back extraction procedure combined with flame atomic absorption spectrometry for determination of trace nickel in samples of nutritional interest. Journal of Hazardous Materials 2010; 173: 534-538.
  • 127. Li Z, Lu N, Zhou X, Song Q. Extraction spectrophotometric determination of aluminum in dialysis concentrates with 3, 5-ditertbutylsalicylfluorone and ionic liquid 1-butyl-3-trimethylsilylimidazolium hexafluorophosphate. Journal of Pharmaceutical and Biomedical Analysis 2007; 43: 1609-1614.
  • 128. Visser AE, Swatloski RP, Reichert WM, Mayton R, Sheff S et al. Task-specific ionic liquids for the extraction of metal ions from aqueous solutions. Chemical Communications 2001;1: 135-136.
  • 129. Visser, AE, Swatloski RP, Reichert WM, Mayton R, Sheff S et al. Task-specific ionic liquids incorporating novel cations for the coordination and extraction of Hg2+ and Cd2+: synthesis, characterization, and extraction studies. Environmental Science & Technology 2002; 36: 2523-2529.
  • 130. Tan Z Q, Liu J F, Pang L. Advances in analytical chemistry using the unique properties of ionic liquids. TRAC Trends in Analytical Chemistry 2012; 39: 218-227.
  • 131. 131.Liu H, Dasgupta P K. Analytical chemistry in a drop. Solvent extraction in a microdrop, Analytical Chemistry 1996; 68: 1817-1821.
  • 132. Liu S, Dasgupta PK. Liquid droplet. A renewable gas sampling interface. Analytical Chemistry 1995; 67: 2042-2049.
  • 133. Jeannot MA, Cantwell FF. Solvent microextraction into a single drop. Analytical Chemistry 1996; 68: 2236-2240.
  • 134. Jeannot MA, Cantwell FF. Mass transfer characteristics of solvent extraction into a single drop at the tip of a syringe needle. Analytical Chemistry 1997; 69: 235-239.
  • 135. He Y, Lee HK. Liquid-phase microextraction in a single drop of organic solvent by using a conventional microsyringe. Analytical Chemistry 1997; 69: 4634-4640.
  • 136. Vičkačkaitė V, Padarauskas A. Ionic liquids in microextraction techniques. Central European Journal of Chemistry 2012; 10: 652-674.
  • 137. Kamarei F, Ebrahimzadeh H, Yamini Y. Optimization of temperature-controlled ionic liquid dispersive liquid phase microextraction combined with high performance liquid chromatography for analysis of chlorobenzenes in water samples. Talanta 2010; 83: 36-41.
  • 138. Zhou Q, Zhang X, Xiao J. Ultrasound-assisted ionic liquid dispersive liquid-phase micro-extraction: A novel approach for the sensitive determination of aromatic amines in water samples. Journal of Chromatography A 2009; 1216: 4361-4365.
  • 139. Liu Y, Zhao E, Zhu W, Gao H, Zhou Z. Determination of four heterocyclic insecticides by ionic liquid dispersive liquid–liquid microextraction in water samples. Journal of Chromatography A 2009; 1216: 885-891.
  • 140. Cruz-Vera M, Lucena R, Cárdenas S, Valcárcel M. One-step in-syringe ionic liquid-based dispersive liquid–liquid microextraction. Journal of Chromatography A 2009; 1216: 6459-6465.
  • 141. Baghdadi M, Shemirani F. In situ solvent formation microextraction based on ionic liquids: a novel sample preparation technique for determination of inorganic species in saline solutions. Analytica Chimica Acta 2009; 634: 186-191.
  • 142. Joshi MD, Chalumot G, Kim YW, Anderson JL. Synthesis of glucaminium-based ionic liquids and their application in the removal of boron from water. Chemical Communications 2012; 48: 1410-1412.
  • 143. Clark KD, Emaus MN, Varona M, Bowers AN, Anderson JL. Ionic liquids: solvents and sorbents in sample preparation. Journal of Separation Science 2018; 41: 209-235.
  • 144. Gao J, Wang H, Qu J, Wang H, Wang X. Development and optimization of a naphthoic acid-based ionic liquid as a “non-organic solvent microextraction” for the determination of tetracycline antibiotics in milk and chicken eggs. Food Chemistry 2017; 215: 138-148.
  • 145. Marcinkowska R, Konieczna K, Marcinkowski Ł, Namieśnik J, Kloskowski A. Application of ionic liquids in microextraction techniques: Current trends and future perspectives. TRAC Trends in Analytical Chemistry 2019; 119: 115614.
  • 146. Zhang C, Cagliero C, Pierson SA, Anderson JL. Rapid and sensitive analysis of polychlorinated biphenyls and acrylamide in food samples using ionic liquid-based in situ dispersive liquid-liquid microextraction coupled to headspace gas chromatography. Journal of Chromatography A 2017; 1481: 1-11.
  • 147. Liu JF, Jiang GB, Chi YG, Cai YQ, Zhou QX et al. Use of ionic liquids for liquid-phase microextraction of polycyclic aromatic hydrocarbons. Analytical Chemistry 2003; 75: 5870-5876.
  • 148. Liu JF, Peng JF, Chi YG, Jiang GB. Determination of formaldehyde in shiitake mushroom by ionic liquid-based liquid-phase microextraction coupled with liquid chromatography. Talanta 2005; 65: 705-709.
  • 149. Peng JF, Liu JF, Jiang GB, Tai C, Huang MJ. Ionic liquid for high temperature headspace liquid-phase microextraction of chlorinated anilines in environmental water samples. Journal of Chromatography A 2005; 1072: 3-6.
  • 150. Ye CL, Zhou QX, Wang XM. Headspace liquid-phase microextraction using ionic liquid as extractant for the preconcentration of dichlorodiphenyltrichloroethane and its metabolites at trace levels in water samples. Analytica Chimica Acta 2006; 572: 165-171.
  • 151. Vidal L, Psillakis E, Domini CE, Grané N, Marken F et al. An ionic liquid as a solvent for headspace single drop microextraction of chlorobenzenes from water samples. Analytica Chimica Acta 2007; 584: 189-195.
  • 152. Aguilera-Herrador E, Lucena R, Cárdenas S, Valcárcel M. Ionic liquid-based single-drop microextraction/gas chromatographic/mass spectrometric determination of benzene, toluene, ethylbenzene and xylene isomers in waters. Journal of Chromatography A 2008; 1201: 106-111.
  • 153. Zhao F, Lu S, Du W, Zeng B. Ionic liquid-based headspace single-drop microextraction coupled to gas chromatography for the determination of chlorobenzene derivatives. Microchimica Acta 2009; 165: 29-33.
  • 154. Aguilera-Herrador E, Lucena R, Cardenas S, Valcarcel M. Determination of trihalomethanes in waters by ionic liquid-based single drop microextraction/gas chromatographic/mass spectrometry. Journal of Chromatography A 2008; 1209: 76-82.
  • 155. Liu Q, Liu Y, Chen S, Liu Q. Ionic liquid for single drop microextraction followed by high performance liquid chromatography ultraviolet detection to determine carbonyl compounds in environmental waters. Journal of Separation Science 2010; 33: 2376-2382.
  • 156. Rykowska I, Ziemblińska J, Nowak I. Modern approaches in dispersive liquid-liquid microextraction (DLLME) based on ionic liquids: A review. Journal of Molecular Liquids 2018;.259: 319-339.
  • 157. Garmangani B, Ghaderi E, Amiri AA. Extraction of pioglitazone via dispersive liquid–liquid microextraction based on ionic liquids and its measurement in drug samples using high-performance liquid chromatography. Journal of the Iranian Chemical Society 2021; 18:1741- 1748.
  • 158. Llaver M, Chapana A L, Wuilloud RG. Simultaneous and highly sensitive determination of selenium and tellurium species in environmental samples by on-line ionic liquid based in-situ solvent formation microextraction with hydride generation atomic fluorescence spectrometry detection. Talanta 2021; 222: 121460.
  • 159. Campillo N, Oller-Ruiz A, Hernández-Córdoba M, Viñas P. In situ generated ionic liquid and dispersive liquid-phase microextraction to determine chlorobenzenes in environmental samples by gas chromatography-mass spectrometry. Microchemical Journal 2020; 159: 105515.
  • 160. Huber S, Harder M, Funck K, Erharter K, Popp M, Bonn GK. Novel room temperature ionic liquid for liquid-phase. Microextraction of Cannabidiol from Natural Cosmetics Separations 2020; 7: 45.
  • 161. Anvar SA, Torbati M, Farajzadeh MA, Mogaddam MRA. Elevated temperature homogeneous liquid phase extraction coupled to ionic liquid–based dispersive liquid–liquid microextraction followed by high-performance liquid chromatography: application of water- miscible ionic liquids as extraction solvent in determination of carbamate pesticides. Food Analytical Methods 2020; 13: 1282-1291.
  • 162. Jia L, Yang J, Zhao W, Jing X. Air-assisted ionic liquid dispersive liquid–liquid microextraction based on solidification of the aqueous phase for the determination of triazole fungicides in water samples by high-performance liquid chromatography. RSC Advances 2019; 9: 36664-36669.
  • 163. Goh SXL, Goh HA, Lee HK. Automation of ionic liquid enhanced membrane bag-assisted-liquid-phase microextraction with liquid chromatography-tandem mass spectrometry for determination of glucocorticoids in water. Analytica Chimica Acta 2018; 1035: 77-86.
  • 164. Yue ME, Lin Q, Xu J, Jiang TF. Ionic liquid based headspace in tube liquid phase microextraction coupled with CE for sensitive detection of phenols. Electrophoresis 2018; 39: 1771-1776.
  • 165. Werner J. Ionic liquid ultrasound-assisted dispersive liquid-liquid microextraction based on solidification of the aqueous phase for preconcentration of heavy metals ions prior to determination by LC-UV. Talanta 2018; 182: 69-73.
  • 166. Guan L, Luo Q, Shi J, Yu W. Application of ionic liquid magnetized stirring bar liquid phase microextraction coupled with HPLC for the determination of naphthoquinones in Zicao. Journal of Separation Science 2018; 41: 868-876.
  • 167. Sun X, Tan J, Ding H, Tan X, Xing J et al. Detection of polycyclic aromatic hydrocarbons in water samples by annular platform-supported ionic liquid-based headspace liquid-phase microextraction. Journal of Analytical Methods in Chemistry 2018; 2018: 3765682.
  • 168. Altunay N, Ülüzger D, Gürkan R. Simple and fast spectrophotometric determination of low levels of thiabendazole residues in fruit and vegetables after pre-concentration with ionic liquid phase microextraction. Food Additives & Contaminants: Part A 2018; 35: 1139-1154.
  • 169. Biata NR, Nyaba L, Ramontja J, Mketo N, Nomngongo PN. Determination of antimony and tin in beverages using inductively coupled plasma-optical emission spectrometry after ultrasound-assisted ionic liquid dispersive liquid-liquid phase microextraction. Food Chemistry 2017; 237: 904-911.
  • 170. Xia Z, Li D, Li Q, Zhang Y, Kang W. Simultaneous determination of brazilin and protosappanin B in Caesalpinia sappan by ionic-liquid dispersive liquid-phase microextraction method combined with HPLC. Chemistry Central Journal 2017; 11: 1-11.
  • 171. Zare-Shahabadi V, Asaadi P, Abbasitabar F, Shirmardi A. Determination of traces of Ni, Cu, and Zn in wastewater and alloy samples by flame-AAS after ionic liquid-based dispersive liquid phase microextraction. Journal of the Brazilian Chemical Society 2017; 28: 887-894.
  • 172. Wang J, Huang S, Wang P, Yang Y. Method development for the analysis of phthalate esters in tea beverages by ionic liquid hollow fibre liquid-phase microextraction and liquid chromatographic detection. Food Control 2016; 67: 278-284.
  • 173. Fotouhi L, Seidi S, Shahsavari F. Optimization of temperature-controlled ionic liquid homogenous liquid phase microextraction followed by high performance liquid chromatography for analysis of diclofenac and mefenamic acid in urine sample. Journal of the Iranian Chemical Society 2016; 13: 1289-1299.
  • 174. Farzadbeh N, Vardini M T, Sheikhloie H. Trace determination of manganese (II) by temperature-controlled/assisted ionic liquid-based dispersive liquid-phase microextraction and electrothermal atomic absorption spectrometry. Journal of the Iranian Chemical Society 2016; 13: 715-722.
  • 175. Hsu KC, Lee CF, Chao YY, Hung CC, Chen CC et al. Ultrasound-assisted hollow fiber/ionic liquid-based liquid phase microextraction using an ionic liquid solvent for preconcentration of cobalt and nickel ions in urine samples prior to FAAS determination. Journal of Analytical Atomic Spectrometry 2016; 31: 2338-2345.
  • 176. Wang X, Li X, Li L, Li M, Wu Q et al. Green determination of aconitum alkaloids in Aconitum carmichaeli (Fuzi) by an ionic liquid aqueous two-phase system and recovery of the ionic liquid coupled with in situ liquid–liquid microextraction. Analytical Methods 2016; 8: 6566-6572.
  • 177. Hu L, Zhang P, Shan W, Wang X, Li S et al. In situ metathesis reaction combined with liquid-phase microextraction based on the solidification of sedimentary ionic liquids for the determination of pyrethroid insecticides in water samples. Talanta 2015; 144: 98-104.
  • 178. Saeidi I, Barfi B, Asghari A, Gharahbagh AA, Barfi A et al. Ionic-liquid-based hollow-fiber liquid-phase microextraction method combined with hybrid artificial neural network-genetic algorithm for speciation and optimized determination of ferro and ferric in environmental water samples. Environmental Monitoring and Assessment 2015; 187: 1-12.
  • 179. Wang Y, Sun Y, Xu B, Li X, Wang X et al. Matrix solid-phase dispersion coupled with magnetic ionic liquid dispersive liquid–liquid microextraction for the determination of triazine herbicides in oilseeds. Analytica Chimica Acta 2015; 888: 67-74.
  • 180. Jiang Y, Tang T, Cao Z, Shi G, Zhou T. Determination of three estrogens and bisphenol A by functional ionic liquid dispersive liquid phase microextraction coupled with ultra high performance liquid chromatography and ultraviolet detection. Journal of Separation Science 2015; 38: 2158-2166.
  • 181. Sha O, Zhu X, Feng Y, Ma W. Aqueous two-phase based on ionic liquid liquid–liquid microextraction for simultaneous determination of five synthetic food colourants in different food samples by high-performance liquid chromatography. Food Chemistry 2015; 174: 380-386.
  • 182. Zeeb M, Mirza B. Ionic liquid phase microextraction combined with fluorescence spectrometry for preconcentration and quantitation of carvedilol in pharmaceutical preparations and biological media. DARU Journal of Pharmaceutical Sciences 2015; 23: 1-7.
  • 183. Chen X. Analysis of methamphetamine in human urine using ionic liquid dispersive liquid-phase microextraction combined with HPLC. Chromatographia 2015; 78: 515-520.
  • 184. Zeng C, Li M, Xie Q, Yan H, Zhang X. UV–Vis Spectrophotometric Determination of Mercury Based on Room Temperature Ionic Liquids Enhanced Hollow-Fiber Liquid-Phase Microextraction. Spectroscopy Letters 2015; 48: 653-659.
  • 185. Wu L, Song Y, Hu M, Xu X, Zhang H et al. Determination of sulfonamides in butter samples by ionic liquid magnetic bar liquid-phase microextraction high-performance liquid chromatography. Analytical and Bioanalytical Chemistry 2015; 407: 569-580.
  • 186. Yang M, Zhang P, Hu L, Lu R, Zhou W et al. Ionic liquid-assisted liquid-phase microextraction based on the solidification of floating organic droplets combined with high performance liquid chromatography for the determination of benzoylurea insecticide in fruit juice. Journal of Chromatography A 2014; 1360: 47-56.
  • 187. Chen H, Han J, Wang Y, Hu Y, Ni L et al. Hollow fiber liquid-phase microextraction of cadmium (II) using an ionic liquid as the extractant. Microchimica Acta 2014; 181: 1455-1461.
  • 188. Rajabi M, Haji-Esfandiari S, Barfi B, Ghanbari H. Ultrasound-assisted temperature-controlled ionic-liquid dispersive liquid-phase microextraction method for simultaneous determination of anethole, estragole, and para-anisaldehyde in different plant extracts and human urine: a comparative study. Analytical and Bioanalytical Chemistry 2014; 406: 4501-4512.
  • 189. Zhou QX, Gao YY. Combination of ionic liquid dispersive liquid-phase microextraction and high performance liquid chromatography for the determination of triazine herbicides in water samples. Chinese Chemical Letters 2014; 25: 745-748.
  • 190. Tai Z, Li Y, Liu M, Hu X, Yang Y et al. Determination of bisphenol a and bisphenol af in vinegar samples by two-component mixed ionic iiquid dispersive liquid-phase microextraction coupled with high performance liquid chromatography. Journal of The Chemical Society of Pakistan 2014; 36: 63-67
  • 191. Bamdad F, Ardalani M, Sangi MR. Trace determination of cadmium ions by flame atomic absorption spectrometry after pre-concentration using temperature-controlled ionic liquid dispersive-liquid phase microextraction. Journal of the Brazilian Chemical Society 2014; 25: 246-252.
  • 192. Zou Y, Zhang Z, Shao X, Chen Y, Wu X et al. Hollow-fiber-supported liquid-phase microextraction using an ionic liquid as the extractant for the pre-concentration of bisphenol A, 17-β-estradiol, estrone and diethylstilbestrol from water samples with HPLC detection. Water Science and Technology 2014; 69: 1028-1035.
  • 193. Khan S, Soylak M, Kazi TG. Room temperature ionic liquid-based dispersive liquid phase microextraction for the separation/ preconcentration of trace Cd(2+) as 1-(2-pyridylazo)-2-naphthol (PAN) complex from environmental and biological samples and determined by FAAS. Biological Trace Element Research 2013; 156: 49-55.
  • 194. Wu H, Guo JB, Du LM, Tian H, Hao CX et al. A rapid shaking-based ionic liquid dispersive liquid phase microextraction for the simultaneous determination of six synthetic food colourants in soft drinks, sugar-and gelatin-based confectionery by high-performance liquid chromatography. Food Chemistry 2013; 141: 182-186.
  • 195. Alothman ZA, Yilmaz E, Habila M, Shabaka A, Soylak M. Ligandless temperature-controlled ionic liquid-phase microextraction of lead (II) ion prior to its determination by FAAS. Microchimica Acta 2013; 180: 669-674.
  • 196. Sun A, Xu Q, Yu X. Determination of Bisphenol A and 4-Nonylphenol in water using ionic liquid dispersive liquid phase microextraction. Polish Journal of Environmental Studies 2013; 22: 899-907.
  • 197. Gao Y, Zhou Q, Xie G, Yao Z. Temperature controlled ionic liquid dispersive liquid phase microextraction combined with HPLC with ultraviolet detector for the determination of fungicides. Journal of Separation Science 2012; 35: 3569-3574.
  • 198. Zhou Q, Gao Y, Xiao J, Xie G. Preconcentration and determination of aromatic amines with temperature-controlled ionic liquid dispersive liquid phase microextraction in combination with high performance liquid chromatography. Journal of AOAC International 2012; 95: 1534-1540.
  • 199. Wang S, Xiang B, Tang Q. Trace determination of dichlorvos in environmental samples by room temperature ionic liquid-based dispersive liquid-phase microextraction combined with HPLC. Journal of Chromatographic Science 2012; 50: 702-708.
  • 200. Berton P, Martinis EM, Martinez LD, Wuilloud RG. Selective determination of inorganic cobalt in nutritional supplements by ultrasound- assisted temperature-controlled ionic liquid dispersive liquid phase microextraction and electrothermal atomic absorption spectrometry. Analytica Chimica Acta 2012; 713: 56-62.
  • 201. Guo X, Yin D, Peng J, Hu X. Ionic liquid based single drop liquid phase microextraction combined with high performance liquid chromatography for the determination of sulfonamides in environmental water. Journal of Separation Science 2012; 35: 452-458.
  • 202. Escudero LB, Berton P, Martinis EM, Olsina RA, Wuilloud RG. Dispersive liquid–liquid microextraction and preconcentration of thallium species in water samples by two ionic liquids applied as ion-pairing reagent and extractant phase. Talanta 2012; 88: 277-283.
  • 203. Absalan G, Akhond M, Sheikhian L, Goltz DM. Temperature-controlled ionic liquid-based dispersive liquid-phase microextraction, preconcentration and quantification of nano-amounts of silver ion by using disulfiram as complexing agent. Analytical Methods 2011; 3: 2354-2359.
  • 204. Zhou Q, Gao Y, Xie G. Determination of bisphenol A, 4-n-nonylphenol, and 4-tert-octylphenol by temperature-controlled ionic liquid dispersive liquid-phase microextraction combined with high performance liquid chromatography-fluorescence detector. Talanta 2011; 85: 1598-1602.
  • 205. Zhou Q, Zhang X, Xie G. Simultaneous analysis of phthalate esters and pyrethroid insecticides in water samples by temperature-controlled ionic liquid dispersive liquid-phase microextraction combined with high-performance liquid chromatography. Analytical Methods 2011; 3: 1815-1820.
  • 206. Guo L, Lee HK. Ionic liquid based three-phase liquid–liquid–liquid solvent bar microextraction for the determination of phenols in seawater samples. Journal of Chromatography A 2011; 1218: 4299-4306.
  • 207. Wang S, Ren L, Xu Y, Liu F. Application of ultrasound-assisted ionic liquid dispersive liquid-phase microextraction followed high- performance liquid chromatography for the determination of fungicides in red wine. Microchimica Acta 2011; 173: 453-457.
  • 208. Zhou Q, Pang L, Xiao J. Ultratrace determination of carbamate pesticides in water samples by temperature controlled ionic liquid dispersive liquid phase microextraction combined with high performance liquid phase chromatography. Microchimica Acta 2011; 173: 477-483.
  • 209. Zhao RS, Wang SS, Cheng CG, Zhang LL, Wang X. Rapid enrichment and sensitive determination of tetrabromobisphenol A in environmental water samples with ionic liquid dispersive liquid-phase microextraction prior to HPLC–ESI-MS–MS. Chromatographia 2011; 73: 793-797.
  • 210. Zhou Q, Gao Y, Xiao J, Xie G. Sensitive determination of phenols from water samples by temperature-controlled ionic liquid dispersive liquid-phase microextraction. Analytical Methods 2011; 3: 653-658.
  • 211. Zhao RS, Wang X, Yuan JP, Wang SS, Cheng CG. Trace determination of hexabromocyclododecane diastereomers in water samples with temperature controlled ionic liquid dispersive liquid phase microextraction. Chinese Chemical Letters 2011; 22: 97-100.
  • 212. Zhou Q, Zhang X. Combination of ultrasound assisted ionic liquid dispersive liquid phase microextraction and high performance liquid chromatography for the sensitive determination of benzoylureas pesticides in environmental water samples. Journal of Separation Science 2010; 33: 3734-3740.
  • 213. Guo J, Li X, Cao X, Qu L, Hou D et al. Temperature-controlled ionic liquid dispersive liquid phase microextraction combined with ultra- high-pressure liquid chromatography for the rapid determination of triclosan, triclocarban and methyl-triclosan in aqueous samples. Science China Chemistry 2010; 53: 2600-2607.
  • 214. Wang S, Ren L, Liu C, Ge J, Liu F. Determination of five polar herbicides in water samples by ionic liquid dispersive liquid-phase microextraction. Analytical and Bioanalytical Chemistry 2010; 397: 3089-3095.
  • 215. Bai H, Zhou Q, Xie G, Xiao J. Temperature-controlled ionic liquid–liquid-phase microextraction for the pre-concentration of lead from environmental samples prior to flame atomic absorption spectrometry. Talanta 2010; 80: 1638-1642.
  • 216. Zhou Q, Zhang X, Xie G, Xiao J. Temperature controlled ionic liquid dispersive liquid phase microextraction for preconcentration of chlorotoluron, diethofencarb and chlorbenzuron in water samples. Journal of Separation Science 2009; 32: 3945-3950.
  • 217. Cruz-Vera M, Lucena R, Cardenas S, Valcárcel M. Determination of phenothiazine derivatives in human urine by using ionic liquid-based dynamic liquid-phase microextraction coupled with liquid chromatography. Journal of Chromatography B 2009; 877: 37-42.
  • 218. Zhou Q, Bai H, Xie G, Xiao J. Trace determination of organophosphorus pesticides in environmental samples by temperature-controlled ionic liquid dispersive liquid-phase microextraction. Journal of Chromatography A 2008; 1188: 148-153.
  • 219. Vidal L, Chisvert A, Canals A, Salvador A. Sensitive determination of free benzophenone-3 in human urine samples based on an ionic liquid as extractant phase in single-drop microextraction prior to liquid chromatography analysis. Journal of Chromatography A 2007; 1174: 95-103.
  • 220. Ye C, Zhou Q, Wang X, Xiao J. Determination of phenols in environmental water samples by ionic liquid based headspace liquid phase microextraction coupled with high performance liquid chromatography. Journal of Separation Science 2007; 30: 42-47.
APA Uzcan F, JAGIRANI M, Soylak M (2022). Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction. , 1755 - 1775. 10.55730/1300-0527.3479
Chicago Uzcan Furkan,JAGIRANI Muhammad Saqaf,Soylak Mustafa Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction. (2022): 1755 - 1775. 10.55730/1300-0527.3479
MLA Uzcan Furkan,JAGIRANI Muhammad Saqaf,Soylak Mustafa Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction. , 2022, ss.1755 - 1775. 10.55730/1300-0527.3479
AMA Uzcan F,JAGIRANI M,Soylak M Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction. . 2022; 1755 - 1775. 10.55730/1300-0527.3479
Vancouver Uzcan F,JAGIRANI M,Soylak M Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction. . 2022; 1755 - 1775. 10.55730/1300-0527.3479
IEEE Uzcan F,JAGIRANI M,Soylak M "Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction." , ss.1755 - 1775, 2022. 10.55730/1300-0527.3479
ISNAD Uzcan, Furkan vd. "Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction". (2022), 1755-1775. https://doi.org/10.55730/1300-0527.3479
APA Uzcan F, JAGIRANI M, Soylak M (2022). Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction. Turkish Journal of Chemistry, 46(6), 1755 - 1775. 10.55730/1300-0527.3479
Chicago Uzcan Furkan,JAGIRANI Muhammad Saqaf,Soylak Mustafa Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction. Turkish Journal of Chemistry 46, no.6 (2022): 1755 - 1775. 10.55730/1300-0527.3479
MLA Uzcan Furkan,JAGIRANI Muhammad Saqaf,Soylak Mustafa Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction. Turkish Journal of Chemistry, vol.46, no.6, 2022, ss.1755 - 1775. 10.55730/1300-0527.3479
AMA Uzcan F,JAGIRANI M,Soylak M Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction. Turkish Journal of Chemistry. 2022; 46(6): 1755 - 1775. 10.55730/1300-0527.3479
Vancouver Uzcan F,JAGIRANI M,Soylak M Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction. Turkish Journal of Chemistry. 2022; 46(6): 1755 - 1775. 10.55730/1300-0527.3479
IEEE Uzcan F,JAGIRANI M,Soylak M "Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction." Turkish Journal of Chemistry, 46, ss.1755 - 1775, 2022. 10.55730/1300-0527.3479
ISNAD Uzcan, Furkan vd. "Assessment of environmental pollutants at trace levels using ionic liquids-based liquid- phase microextraction". Turkish Journal of Chemistry 46/6 (2022), 1755-1775. https://doi.org/10.55730/1300-0527.3479