Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine

Pekbelgin Karaoğlu, Hande; Kalkan Burat, Ayfer

doi:10.18596/jotcsa.870010

Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine

Ayfer KALKAN BURAT, (İstanbul Teknik Üniversitesi, Kimya Bölümü, İstanbul, Türkiye)

Hande Pekbelgin Karaoğlu (İstanbul Teknik Üniversitesi, Kimya Bölümü, İstanbul, Türkiye)

Journal of the Turkish Chemical Society, Section A: Chemistry

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Yıl: 2021 Cilt: 8 Sayı: 2 Sayfa Aralığı: 623 - 632 Metin Dili: İngilizce DOI: 10.18596/jotcsa.870010 İndeks Tarihi: 10-01-2023

Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine

Öz:

A novel unsymmetrically substituted zinc phthalocyanine (ZnPc) containing six hexylthio units and a morpholinoethoxy group was synthesized and characterized. Statistical condensation reaction of two different phthalonitriles was used for the preparation of unsymmetrical ZnPc. The novel compound was purified using chromatographic methods with the help of high solubility differences of phthalonitrile derivatives. Characterization of the compound was achieved by using NMR, FT-IR, UV-Vis, and mass spectroscopic methods. The photophysical measurements were made in tetrahydrofuran (THF). Fluorescent quantum yield (ΦF) and fluorescence lifetime (τF) of unsymmetrical ZnPc were determined. Fluorescent quenching experiments were done by adding benzoquinone (BQ) in THF, and Stern-Volmer constant (Ksv) and quenching constant (kq) values were calculated.

Anahtar Kelime: Fluorescence phthalocyanine quenching unsymmetric zinc

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	Kalkan Burat A, Pekbelgin Karaoğlu H (2021). Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine. , 623 - 632. 10.18596/jotcsa.870010
Chicago	Kalkan Burat Ayfer,Pekbelgin Karaoğlu Hande Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine. (2021): 623 - 632. 10.18596/jotcsa.870010
MLA	Kalkan Burat Ayfer,Pekbelgin Karaoğlu Hande Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine. , 2021, ss.623 - 632. 10.18596/jotcsa.870010
AMA	Kalkan Burat A,Pekbelgin Karaoğlu H Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine. . 2021; 623 - 632. 10.18596/jotcsa.870010
Vancouver	Kalkan Burat A,Pekbelgin Karaoğlu H Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine. . 2021; 623 - 632. 10.18596/jotcsa.870010
IEEE	Kalkan Burat A,Pekbelgin Karaoğlu H "Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine." , ss.623 - 632, 2021. 10.18596/jotcsa.870010
ISNAD	Kalkan Burat, Ayfer - Pekbelgin Karaoğlu, Hande. "Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine". (2021), 623-632. https://doi.org/10.18596/jotcsa.870010

APA	Kalkan Burat A, Pekbelgin Karaoğlu H (2021). Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine. Journal of the Turkish Chemical Society, Section A: Chemistry, 8(2), 623 - 632. 10.18596/jotcsa.870010
Chicago	Kalkan Burat Ayfer,Pekbelgin Karaoğlu Hande Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine. Journal of the Turkish Chemical Society, Section A: Chemistry 8, no.2 (2021): 623 - 632. 10.18596/jotcsa.870010
MLA	Kalkan Burat Ayfer,Pekbelgin Karaoğlu Hande Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine. Journal of the Turkish Chemical Society, Section A: Chemistry, vol.8, no.2, 2021, ss.623 - 632. 10.18596/jotcsa.870010
AMA	Kalkan Burat A,Pekbelgin Karaoğlu H Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine. Journal of the Turkish Chemical Society, Section A: Chemistry. 2021; 8(2): 623 - 632. 10.18596/jotcsa.870010
Vancouver	Kalkan Burat A,Pekbelgin Karaoğlu H Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine. Journal of the Turkish Chemical Society, Section A: Chemistry. 2021; 8(2): 623 - 632. 10.18596/jotcsa.870010
IEEE	Kalkan Burat A,Pekbelgin Karaoğlu H "Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine." Journal of the Turkish Chemical Society, Section A: Chemistry, 8, ss.623 - 632, 2021. 10.18596/jotcsa.870010
ISNAD	Kalkan Burat, Ayfer - Pekbelgin Karaoğlu, Hande. "Photophysical properties of a newly synthesized unsymmetrically substituted zinc phthalocyanine". Journal of the Turkish Chemical Society, Section A: Chemistry 8/2 (2021), 623-632. https://doi.org/10.18596/jotcsa.870010