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ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI

A. Kadir ÖZER (Atatürk Üniversitesi, Kimya Mühendisliği Bölümü, Erzurum, Türkiye)
KSÜ Mühendislik Bilimleri Dergisi
1 0
Yıl: 2022 Cilt: 25 Sayı: 4 Sayfa Aralığı: 670 - 680 Metin Dili: Türkçe DOI: 10.17780/ksujes.1150877 İndeks Tarihi: 13-03-2023

ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI

Öz:
Bu çalışmada, kimyasal çöktürme yöntemi ile çinko hidroksi sülfat (Zn4SO4(OH)6)’ın sentezlenmesi esnasında ZnSO4 öncü madde olarak ve boraks (Na2B4O7.10H2O), hekzametilentetramin (CH2)6N4) (HMT) ve sodyum hidroksit (NaOH) bazik çöktürücüler olarak kullanılmıştır. Boraks ve HMT ortamlarında Zn4(OH)6SO4.3H20 ve NaOH ortamında Zn4(OH)6SO4.4H20'in sentezlendiği XRD sonuçları ile tespit edilmiştir. SEM analiz sonuçlarında boraks, HMT ve NaOH ortamlarında sentezlenen örneklerin hegzagonal yapıda tabakalardan oluştuğu görülmektedir. TG ve DSC analizlerinde her üç örnek içinde üç basamaklı bir ağırlık kaybının olduğu görülmektedir. Her bir basamakta sırası ile Zn4(OH)6SO4.0,5H20, Zn3O(SO4)2 ve ZnO’in oluştuğu tespit edilmiştir. Boraks ortamında 3-(N,N-dimetildodesilamonyum)-propansülfonat (SB12) sürfaktan ilave edilerek sentezlenen örneklerin sürfaktansız ortamda sentezlenen örneklere benzer hegzagonal yapıda olduğu görülmektedir. Sodyum dodesil sülfat (SDS) ve N-setil-N,N,N-trimetil-amonyum bromür (CTAB) sürfaktanları ilave edilerek sentezlenen örneklerin ise yaprak benzeri morfolojilere dönüştüğü tespit edilmiştir.
Anahtar Kelime: Kimyasal çöktürme yöntemi Zn4(OH)6SO4 ZnO

SYNTHESIS, CHARACTERIZATION AND THERMAL DECOMPOSITION OF ZINC HYDROXIDE SULFATE (Zn4(OH)6SO4) IN THREE DIFFERENT BASIC ENVIRONMENTS

Öz:
In this study, during the synthesis of zinc hydroxide sulfate (Zn4(OH)6SO4) by chemical precipitation method, ZnSO4 was used as precursor and borax (Na2B4O7.10H2O), hexamethylenetetramine (CH2)6N4) (HMT) and sodium hydroxide (NaOH) as basic precipitants. It was determined by XRD results that Zn4(OH)6SO4‧3H2O was synthesized in Borax and HMT environments and Zn4(OH)6SO4.4H2O was synthesized in NaOH environment. In the SEM analysis results, it is seen that the samples synthesized in borax, HMT and NaOH media consist of morphologically hexagonal layers. In TG and DSC analyzes, it is seen that there is a three-step weight loss in all three samples. In each step, Zn4(OH)6SO4‧0,5H2O, Zn3O(SO4)2 and ZnO are formed, respectively. It is seen that the samples synthesized by adding 3-(N,N-dimethyldodecylammonium)-propanesulfonate (SB12) surfactant in borax environment have a hexagonal structure similar to the samples synthesized in the absence of surfactant. It is seen that the samples synthesized by adding 3-(N,N-dimethyldodecylammonium)-propanesulfonate (SB12) surfactant in borax environment have a hexagonal structure similar to the samples synthesized in the absence of surfactant. It was determined that the samples synthesized by adding sodium dodecyl sulfate (SDS) and N-cetyl-N,N,N-trimethyl- ammonium bromide (CTAB) surfactants turned into leaf-like morphologies.
Anahtar Kelime: Chemical precipitation method Zn4(OH)6SO4 ZnO

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA Özer A (2022). ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI. , 670 - 680. 10.17780/ksujes.1150877
Chicago Özer A. Kadir ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI. (2022): 670 - 680. 10.17780/ksujes.1150877
MLA Özer A. Kadir ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI. , 2022, ss.670 - 680. 10.17780/ksujes.1150877
AMA Özer A ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI. . 2022; 670 - 680. 10.17780/ksujes.1150877
Vancouver Özer A ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI. . 2022; 670 - 680. 10.17780/ksujes.1150877
IEEE Özer A "ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI." , ss.670 - 680, 2022. 10.17780/ksujes.1150877
ISNAD Özer, A. Kadir. "ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI". (2022), 670-680. https://doi.org/10.17780/ksujes.1150877
APA Özer A (2022). ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI. KSÜ Mühendislik Bilimleri Dergisi, 25(4), 670 - 680. 10.17780/ksujes.1150877
Chicago Özer A. Kadir ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI. KSÜ Mühendislik Bilimleri Dergisi 25, no.4 (2022): 670 - 680. 10.17780/ksujes.1150877
MLA Özer A. Kadir ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI. KSÜ Mühendislik Bilimleri Dergisi, vol.25, no.4, 2022, ss.670 - 680. 10.17780/ksujes.1150877
AMA Özer A ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI. KSÜ Mühendislik Bilimleri Dergisi. 2022; 25(4): 670 - 680. 10.17780/ksujes.1150877
Vancouver Özer A ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI. KSÜ Mühendislik Bilimleri Dergisi. 2022; 25(4): 670 - 680. 10.17780/ksujes.1150877
IEEE Özer A "ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI." KSÜ Mühendislik Bilimleri Dergisi, 25, ss.670 - 680, 2022. 10.17780/ksujes.1150877
ISNAD Özer, A. Kadir. "ÇİNKO HİDROKSİ SÜLFAT (Zn4SO4(OH)6)’IN ÜÇ FARKLI BAZİK ORTAMDA SENTEZİ, KARAKTERİZASYONU VE TERMAL BOZUNMASI". KSÜ Mühendislik Bilimleri Dergisi 25/4 (2022), 670-680. https://doi.org/10.17780/ksujes.1150877
Sayfa Oluşturulma Tarihi
24-04-2024 14:30

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