Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi
Yıl: 2023 Cilt: 38 Sayı: 3 Sayfa Aralığı: 1505 - 1518 Metin Dili: Türkçe DOI: 10.17341/gazimmfd.1008501 İndeks Tarihi: 23-03-2023
Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi
Öz: Antibiyotik kalıntılarının su kaynaklarındaki toksisitesi çevreyi olumsuz etkilemektedir. Son yıllarda yapılan çalışmalar antibiyotikler gibi organik kirleticilerin ucuz ve çevreye uyumlu adsorbentlerle sulu çözeltilerden giderimine odaklanmıştır. Bu çalışmada, doğal Manisa-Gördes klinoptiloliti oksitetrasiklin hidroklorür (OTC-HCL) adsorpsiyonu, kesikli sisteminde 298-323 K'de incelenmiştir. pH, başlangıç konsantrasyonu, adsorban dozu, temas süresi, karıştırma hızı ve sıcaklığın adsorpsiyon üzerindeki etkileri incelenmiş ve optimum parametreler belirlenmiştir. Adsorpsiyon izotermleri Langmuir, Freundlich, Dubinin-Radushkevich (D-R), Temkin modelleri kullanılarak analiz edilmiştir. Kinetik sabitler yalancı birinci derece, yalancı ikinci derece, inratapartikül difüzyon ve Elovich modelleriyle belirlenmiştir. Doğal zeolitin OTC-HCL adsorpsiyonu, en iyi Freundlich izotermine ve sözde ikinci dereceden kinetik modeline uymuştur. Doğal zeolitin maksimum adsorpsiyon kapasitesi 323 K'de 60,97 mg/g olarak belirlenmiştir. Termodinamik çalışmalar, OTC-HCL’nin doğal zeolit ile adsorpsiyonunun kendiliğinden ve endotermik olduğunu göstermiştir. Doğal zeolitin fizikokimyasal karakterizasyonu adsorpsiyondan önce ve sonra, $N_2$ adsorpsiyon-desorpsiyon, XRD, FTIR, SEM-EDX analizleri ile gerçekleştirilmiştir. Doğal zeolitin BET spesfik yüzey alanı, adsorpsiyon sürecine bağlı olarak adsorpsiyon sonrasında azalmıştır. Karakterizasyon sonuçları, doğal zeolit yüzeyinde OTC-HCL moleküllerinin başarılı bir adsorbe olduğunu göstermiştir.
Anahtar Kelime: Removal of oxytetracycline hydrochloride from aqueous solutions using natural zeolite
Öz: The toxicity of antibiotic residues in water resources adversely affects the environment. Recent studies have focused on the removal of organic pollutants such as antibiotics from aqueous solutions with cheap and environmentally compatible adsorbents. In this study, adsorption of oxytetracycline hydrochloride (OTC- HCL) on the natural Manisa-Gördes clinoptilolite was investigated in the batch system at 298-323 K. Effects of pH, initial concentration, adsorbent dosage, contact time, stirring speed and temperature on adsorption were examined and optimum parameters were determined. Isotherm models including Langmuir, Freundlich, Dubinin-Radushkevich (D-R), Temkin were applied to analyze the adsorption data. Kinetic constants were determined by pseudo-first order (PFO), pseudo-second order (PSO), intraparticle diffusion and Elovich models. Adsorption of OTC-HCL on natural zeolite fitted well to the Freundlich and pseudo-second order models. The maximum adsorption capacity of natural zeolite was determined as 60.97 mg/g at 323 K. Thermodynamic studies indicated that the adsorption of OTC-HCL on natural zeolite was spontaneous and endothermic. Physicochemical characterization of natural zeolite was conducted by $N_2$ adsorption- desorption, XRD, FTIR, SEM-EDX analyses before and after adsorption. SBET, specific surface area of the natural zeolite decreased after adsorption process. Characterization results showed that OTC-HCL molecules were successfully adsorbed on the natural zeolite surface.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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| APA | MERSİN G, Açıkel Ü, Levent M (2023). Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. , 1505 - 1518. 10.17341/gazimmfd.1008501 |
| Chicago | MERSİN Gülşah,Açıkel Ünsal,Levent Menderes Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. (2023): 1505 - 1518. 10.17341/gazimmfd.1008501 |
| MLA | MERSİN Gülşah,Açıkel Ünsal,Levent Menderes Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. , 2023, ss.1505 - 1518. 10.17341/gazimmfd.1008501 |
| AMA | MERSİN G,Açıkel Ü,Levent M Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. . 2023; 1505 - 1518. 10.17341/gazimmfd.1008501 |
| Vancouver | MERSİN G,Açıkel Ü,Levent M Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. . 2023; 1505 - 1518. 10.17341/gazimmfd.1008501 |
| IEEE | MERSİN G,Açıkel Ü,Levent M "Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi." , ss.1505 - 1518, 2023. 10.17341/gazimmfd.1008501 |
| ISNAD | MERSİN, Gülşah vd. "Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi". (2023), 1505-1518. https://doi.org/10.17341/gazimmfd.1008501 |
| APA | MERSİN G, Açıkel Ü, Levent M (2023). Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 38(3), 1505 - 1518. 10.17341/gazimmfd.1008501 |
| Chicago | MERSİN Gülşah,Açıkel Ünsal,Levent Menderes Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 38, no.3 (2023): 1505 - 1518. 10.17341/gazimmfd.1008501 |
| MLA | MERSİN Gülşah,Açıkel Ünsal,Levent Menderes Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, vol.38, no.3, 2023, ss.1505 - 1518. 10.17341/gazimmfd.1008501 |
| AMA | MERSİN G,Açıkel Ü,Levent M Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 2023; 38(3): 1505 - 1518. 10.17341/gazimmfd.1008501 |
| Vancouver | MERSİN G,Açıkel Ü,Levent M Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 2023; 38(3): 1505 - 1518. 10.17341/gazimmfd.1008501 |
| IEEE | MERSİN G,Açıkel Ü,Levent M "Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi." Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 38, ss.1505 - 1518, 2023. 10.17341/gazimmfd.1008501 |
| ISNAD | MERSİN, Gülşah vd. "Oksitetrasiklin hidroklorürün doğal zeolit ile sulu çözeltilerden giderimi". Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 38/3 (2023), 1505-1518. https://doi.org/10.17341/gazimmfd.1008501 |
