Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi
Yıl: 2023 Cilt: 38 Sayı: 1 Sayfa Aralığı: 71 - 84 Metin Dili: Türkçe DOI: 10.17341/gazimmfd.1011296 İndeks Tarihi: 23-03-2023
Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi
Öz: Metanın kuru reformlanması ile sentez gazı üretimi için karbon oluşumunu azaltabilecek Zr içerikli SBA-15 destekli Ni katalizörlerin geliştirilmesi amaçlanmıştır. Bu çalışmada, Zr içerikli SBA-15 destek malzemeleri HCl (A), NaCl (S) ve HCl ile NaCl’ün (B) birlikte ilave edildiği farklı koşullardaki tek-kap hidrotermal sentez yöntemiyle hazırlanmıştır. Zr-SBA-15 malzemelerinin destek olarak kullanıldığı Ni katalizörleri emdirme yöntemi ile hazırlanmıştır. Farklı sentez koşullarında hazırlanan Zr-SBA-15 destekli Ni katalizörlerinin aktiviteleri metanın kuru reformlanma reaksiyonunda sabit yatak reaktör sisteminde 750 °C’de test edilmiştir. Katalitik aktivite ve katalizör özellikleri arasındaki ilişkinin açıklanabilmesi amacıyla reaksiyon öncesi ve/veya sonrası XRD, N2 adsorpsiyon-desorpsiyon, ICP-OES, DRIFTS, SEM, TEM ve TG analizleri gerçekleştirilmiştir. HCl varlığında sentezlenen Zr-SBA-15 destekli Ni (5Ni@10Zr ̶ A) katalizörde diğer iki katalizörden (5Ni@10Zr ̶ B ve 5Ni@10Zr ̶ S) farklı olarak kısa ve hekzagonal şeklinde yapıların oluşumu gözlenmiştir. Farklı morfolojiye sahip olan 5Ni@10Zr ̶ A katalizörünün yapısında bulunan kütlece % 4,5 Zr miktarının katalizörün aktivitesini artırdığı (%85 CH4 ve %88 CO2 dönüşümü) ve karbon birikimini önemli derecede azalttığı belirlenmiştir. Bunun yanı sıra en yüksek H2/CO oranı ve H2 verimi sırasıyla 0,79 ve 1,37 olarak 5Ni@10Zr ̶ A katalizörü ile elde edilmiştir.
Anahtar Kelime: Development of Zr-SBA-15 supported Ni catalysts reducing carbon formation in dry reforming of methane: Effect of synthesis media
Öz: It is aimed to develop SBA-15 supported Ni catalysts with Zr incorporation that can reduce carbon formation for synthesis gas production via dry reforming methane. In this study, Zr-containing SBA-15 support materials were synthesized following a one-pot hydrothermal synthesis method in three different synthesis conditions using HCl (A), NaCl (S) and both HCl and NaCl (B). Ni catalysts containing Zr-SBA-15 support materials were prepared by an impregnation method. Zr-SBA-15 prepared under different synthesis conditions supported Ni catalysts were tested in dry reforming of methane at 750°C. All catalysts were characterized by XRD, N2 adsorption-desorption isotherms, ICP-OES, DRIFTS, SEM, TEM and TG techniques before and/or after reaction tests in order to explain the relationship between catalytic activity and catalyst properties. Unlike the other two catalysts (5Ni@10Zr ̶ B and 5Ni@10Zr ̶ S), the formation of hexagonal platelet and short mesochannels was observed in the Zr-SBA-15 supported Ni (5Ni@10Zr ̶ A) catalyst synthesized in the presence of HCl. It was determined that Zr (4.5% by weight) incorporated into the structure of 5Ni@10Zr ̶ A catalyst improved the catalytic activity (85% CH4 and 88% CO2 conversions) and significantly reduced carbon formation. In addition, the highest H2/CO ratio and H2 yield were obtained with 5Ni@10Zr ̶ A catalyst as 0.79 and 1.37, respectively.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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| APA | OKUTAN Ç, Arbag H, Yaşyerli N, Yasyerli S (2023). Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi. , 71 - 84. 10.17341/gazimmfd.1011296 |
| Chicago | OKUTAN ÇİĞDEM,Arbag Huseyin,Yaşyerli Nail,Yasyerli Sena Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi. (2023): 71 - 84. 10.17341/gazimmfd.1011296 |
| MLA | OKUTAN ÇİĞDEM,Arbag Huseyin,Yaşyerli Nail,Yasyerli Sena Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi. , 2023, ss.71 - 84. 10.17341/gazimmfd.1011296 |
| AMA | OKUTAN Ç,Arbag H,Yaşyerli N,Yasyerli S Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi. . 2023; 71 - 84. 10.17341/gazimmfd.1011296 |
| Vancouver | OKUTAN Ç,Arbag H,Yaşyerli N,Yasyerli S Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi. . 2023; 71 - 84. 10.17341/gazimmfd.1011296 |
| IEEE | OKUTAN Ç,Arbag H,Yaşyerli N,Yasyerli S "Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi." , ss.71 - 84, 2023. 10.17341/gazimmfd.1011296 |
| ISNAD | OKUTAN, ÇİĞDEM vd. "Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi". (2023), 71-84. https://doi.org/10.17341/gazimmfd.1011296 |
| APA | OKUTAN Ç, Arbag H, Yaşyerli N, Yasyerli S (2023). Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 38(1), 71 - 84. 10.17341/gazimmfd.1011296 |
| Chicago | OKUTAN ÇİĞDEM,Arbag Huseyin,Yaşyerli Nail,Yasyerli Sena Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 38, no.1 (2023): 71 - 84. 10.17341/gazimmfd.1011296 |
| MLA | OKUTAN ÇİĞDEM,Arbag Huseyin,Yaşyerli Nail,Yasyerli Sena Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, vol.38, no.1, 2023, ss.71 - 84. 10.17341/gazimmfd.1011296 |
| AMA | OKUTAN Ç,Arbag H,Yaşyerli N,Yasyerli S Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 2023; 38(1): 71 - 84. 10.17341/gazimmfd.1011296 |
| Vancouver | OKUTAN Ç,Arbag H,Yaşyerli N,Yasyerli S Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 2023; 38(1): 71 - 84. 10.17341/gazimmfd.1011296 |
| IEEE | OKUTAN Ç,Arbag H,Yaşyerli N,Yasyerli S "Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi." Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 38, ss.71 - 84, 2023. 10.17341/gazimmfd.1011296 |
| ISNAD | OKUTAN, ÇİĞDEM vd. "Metanın kuru reformlanma reaksiyonunda karbon oluşumunu azaltan Zr-SBA-15 destekli Ni katalizörlerin geliştirilmesi: Sentez ortamının etkisi". Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 38/1 (2023), 71-84. https://doi.org/10.17341/gazimmfd.1011296 |
