Yıl: 2022 Cilt: 6 Sayı: 2 Sayfa Aralığı: 286 - 292 Metin Dili: İngilizce DOI: 10.46460/ijiea.1141731 İndeks Tarihi: 30-03-2023

EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS

Öz:
The adsorption-desorption characteristics of tetracycline and diclofenac onto two different agricultural soils (S1 and S2) were investigated using the batch equilibrium method. The adsorption experiments were used to optimize the two variable parameters (contact time (5-120 min), initial pollutant concentration (5-300 mg/L)) on the adsorption of tetracycline and diclofenac. The adsorption kinetics for tetracycline and diclofenac onto soil are well described by a bi-exponential adsorption model characterized by fast and slow adsorption rates. Non-linear adsorption curves fitted well to the Langmuir, Freundlich and Temkin equations. The maximum adsorption capacity (qm) of tetracycline and diclofenac onto the soils S1 and S2 were calculated to be 55.90 mg/g, 41.92 mg/g, 26 mg/g and 6.42 mg/g, respectively. Kd, Koc, foc and qa values were calculated. The adsorption efficiency of tetracycline and diclofenac by the soils S1 and S2 was over 97%. The Kd parameters for the adsorption of tetracycline and diclofenac onto the soils S1 and S2 were found to be 3537 L/kg, 654 L/kg, 1669 L/kg and 3105 L/kg, respectively. The reversibility of the adsorption process was evaluated by desorption experiments using different concentrations of HDTMA and Triton-x surfactants. The desorption rates were higher for diclofenac than for tetracycline.
Anahtar Kelime: Adsorption desorption diclofenac soil tetracycline

TARIM TOPRAKLARINDA TETRASİKLİN VE DİKLOFENAK ADSORPSİYONU/DESORPSİYONU İÇİN DENEYSEL VERILER VE MODELLEME

Öz:
Tetrasiklin ve diklofenakın iki farklı tarım toprağına (S1 ve S2) adsorpsiyon-desorpsiyon özellikleri kesikli denge yöntemi kullanılarak araştırılmıştır. Adsorpsiyon deneyleri, tetrasiklin ve diklofenak adsorpsiyonunda iki değişken parametreyi (temas süresi (5-120 dakika), başlangıç kirletici konsantrasyonu (5-300 mg/L)) optimize etmek için kullanılmıştır. Tetrasiklin ve diklofenak için toprak adsorpsiyon kinetiği, hızlı ve yavaş adsorpsiyon oranları ile karakterize edilen iki üslü bir adsorpsiyon modeli ile tanımlanmıştır. Non-linear adsorpsiyon izoterm eğrileri, Langmuir, Freundlich ve Temkin modellerine iyi uyum sağlamıştır. S1 ve S2 topraklarına tetrasiklin ve diklofenakın maksimum adsorpsiyon kapasitesi (qm) sırasıyla 55.90 mg/g, 41.92 mg/g, 26 mg/g ve 6.42 mg/g olarak hesaplanmıştır. Kd, Koc, foc ve qa değerleri hesaplanmıştır. Tetrasiklin ve diklofenakın S1 ve S2 toprakları tarafından adsorpsiyon etkinliği %97'nin üzerindedir. S1 ve S2 topraklarına tetrasiklin ve diklofenak adsorpsiyonu için Kd parametreleri sırasıyla 3537 L/kg, 654 L/kg, 1669 L/kg ve 3105 L/kg olarak bulunmuştur. Adsorpsiyon işleminin tersinebilirliği, farklı konsantrasyonlarda HDTMA ve Triton-x yüzey aktif maddeler kullanılarak desorpsiyon deneyleriyle değerlendirilmiştir. Desorpsiyon oranları diklofenak için tetrasikline göre daha yüksek bulunmuştur.
Anahtar Kelime: Adsorpsiyon desorpsiyon diklofenak tetrasiklin toprak

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA Guler U, Tuncel E (2022). EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS. , 286 - 292. 10.46460/ijiea.1141731
Chicago Guler Ulker Asli,Tuncel Eliza EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS. (2022): 286 - 292. 10.46460/ijiea.1141731
MLA Guler Ulker Asli,Tuncel Eliza EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS. , 2022, ss.286 - 292. 10.46460/ijiea.1141731
AMA Guler U,Tuncel E EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS. . 2022; 286 - 292. 10.46460/ijiea.1141731
Vancouver Guler U,Tuncel E EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS. . 2022; 286 - 292. 10.46460/ijiea.1141731
IEEE Guler U,Tuncel E "EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS." , ss.286 - 292, 2022. 10.46460/ijiea.1141731
ISNAD Guler, Ulker Asli - Tuncel, Eliza. "EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS". (2022), 286-292. https://doi.org/10.46460/ijiea.1141731
APA Guler U, Tuncel E (2022). EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS. International Journal of Innovative Engineering Applications, 6(2), 286 - 292. 10.46460/ijiea.1141731
Chicago Guler Ulker Asli,Tuncel Eliza EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS. International Journal of Innovative Engineering Applications 6, no.2 (2022): 286 - 292. 10.46460/ijiea.1141731
MLA Guler Ulker Asli,Tuncel Eliza EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS. International Journal of Innovative Engineering Applications, vol.6, no.2, 2022, ss.286 - 292. 10.46460/ijiea.1141731
AMA Guler U,Tuncel E EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS. International Journal of Innovative Engineering Applications. 2022; 6(2): 286 - 292. 10.46460/ijiea.1141731
Vancouver Guler U,Tuncel E EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS. International Journal of Innovative Engineering Applications. 2022; 6(2): 286 - 292. 10.46460/ijiea.1141731
IEEE Guler U,Tuncel E "EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS." International Journal of Innovative Engineering Applications, 6, ss.286 - 292, 2022. 10.46460/ijiea.1141731
ISNAD Guler, Ulker Asli - Tuncel, Eliza. "EXPERIMENTAL DATA AND MODELING FOR THE ADSORPTION/DESORPTION OF TETRACYCLINE AND DICLOFENAC ON THE AGRICULTURAL SOILS". International Journal of Innovative Engineering Applications 6/2 (2022), 286-292. https://doi.org/10.46460/ijiea.1141731