Yıl: 2022 Cilt: 6 Sayı: 2 Sayfa Aralığı: 326 - 333 Metin Dili: Türkçe DOI: 10.46460/ijiea.1173064 İndeks Tarihi: 30-03-2023

METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI

Öz:
Atıklar, bol, ucuz ve yenilenebilir olması bakımından karbon malzemeleri hazırlamak için mükemmel bir başlangıç noktasıdır. Bu çalışmada, asetik asit ile muamele edilmiş metal katkılı atık asfalt katalizörü kullanılarak NaBH4 metanolizinde hidrojen sentezi gerçekleştirilmiştir. Farklı metal türleri denenerek en verimli metal türü belirlenmesinin ardından farklı oranlarda metal kullanılmış ve en etkin katalizör üretilmiştir. En verimli katalizör, 3M asetik asit ve % 30 Cu ile muamele edilmiş atık asfalt katalizörüdür. Seçilen katalizör varlığında, en yüksek hidrojen verimini elde etmek için farklı katalizör miktarları, farklı NaBH4 konsantrasyonları ve farklı sıcaklıklar kullanılarak deneyler yapılmış ve sonuçlar yorumlanmıştır. Maksimum hidrojen üretimi verimi 9518,3 ml dk-1 g-1 ve katalizörün aktivasyon enerjisi 38,2 kj/mol olarak belirlenmiştir.
Anahtar Kelime: Atık Asfalt Bakır Hidrojen Katalizör Metal

USAGE OF WASTE ASPHALT TREATED WITH METAL CONTAINED ACID SOLUTION AS A CATALYST IN HYDROGEN PRODUCTION

Öz:
Wastes are an excellent starting point for preparing carbon materials, as it is plentiful, inexpensive and renewable. In this study, hydrogen synthesis was carried out in the methanolysis of NaBH4 using a metal added waste asphalt catalyst treated with acetic acid. After trying different metal types and determining the most efficient metal type, different ratios of metal were used and the most effective catalyst was produced. The most efficient catalyst is waste asphalt catalyst treated with 3M acetic acid and 30% Cu. In the presence of the selected catalyst, experiments were carried out using different catalyst amounts, different NaBH4 concentrations and different temperatures to obtain the highest hydrogen yield, and the results were interpreted. The maximum hydrogen generation efficiency was determined as 9518.3 mL min-1 g-1 and the activation energy of the catalyst was determined as 38.2 kj/mol.
Anahtar Kelime: Catalyst copper hydrogen metal waste asphalt

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA Özarslan S, Durgun M, KAYA M (2022). METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI. , 326 - 333. 10.46460/ijiea.1173064
Chicago Özarslan Saliha,Durgun Mustafa,KAYA MUSTAFA METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI. (2022): 326 - 333. 10.46460/ijiea.1173064
MLA Özarslan Saliha,Durgun Mustafa,KAYA MUSTAFA METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI. , 2022, ss.326 - 333. 10.46460/ijiea.1173064
AMA Özarslan S,Durgun M,KAYA M METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI. . 2022; 326 - 333. 10.46460/ijiea.1173064
Vancouver Özarslan S,Durgun M,KAYA M METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI. . 2022; 326 - 333. 10.46460/ijiea.1173064
IEEE Özarslan S,Durgun M,KAYA M "METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI." , ss.326 - 333, 2022. 10.46460/ijiea.1173064
ISNAD Özarslan, Saliha vd. "METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI". (2022), 326-333. https://doi.org/10.46460/ijiea.1173064
APA Özarslan S, Durgun M, KAYA M (2022). METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI. International Journal of Innovative Engineering Applications, 6(2), 326 - 333. 10.46460/ijiea.1173064
Chicago Özarslan Saliha,Durgun Mustafa,KAYA MUSTAFA METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI. International Journal of Innovative Engineering Applications 6, no.2 (2022): 326 - 333. 10.46460/ijiea.1173064
MLA Özarslan Saliha,Durgun Mustafa,KAYA MUSTAFA METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI. International Journal of Innovative Engineering Applications, vol.6, no.2, 2022, ss.326 - 333. 10.46460/ijiea.1173064
AMA Özarslan S,Durgun M,KAYA M METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI. International Journal of Innovative Engineering Applications. 2022; 6(2): 326 - 333. 10.46460/ijiea.1173064
Vancouver Özarslan S,Durgun M,KAYA M METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI. International Journal of Innovative Engineering Applications. 2022; 6(2): 326 - 333. 10.46460/ijiea.1173064
IEEE Özarslan S,Durgun M,KAYA M "METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI." International Journal of Innovative Engineering Applications, 6, ss.326 - 333, 2022. 10.46460/ijiea.1173064
ISNAD Özarslan, Saliha vd. "METAL İÇERİKLİ ASİT ÇÖZELTİSİ İLE MUAMELE EDİLMİŞ ATIK ASFALTIN HİDROJEN ÜRETİMİNDE KATALİZÖR OLARAK KULLANIMI". International Journal of Innovative Engineering Applications 6/2 (2022), 326-333. https://doi.org/10.46460/ijiea.1173064