The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites

tasdelen, mehmet atilla; Bekin Acar, Seda; Karaagac, Bagdagul

doi:10.55730/1300-0527.3548

The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites

Seda Bekin Acar, (Yalova Üniversitesi, Mühendislik Fakültesi, Polimer Malzeme Mühendisliği Bölümü, Yalova, Türkiye)

Mehmet Atilla TAŞDELEN, (Yalova Üniversitesi, Mühendislik Fakültesi, Polimer Malzeme Mühendisliği Bölümü, Yalova, Türkiye)

Bagdagul Karaagac (Kocaeli Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü, Kocaeli, Türkiye)

Turkish Journal of Chemistry

3 0

Yıl: 2023 Cilt: 47 Sayı: 2 Sayfa Aralığı: 417 - 425 Metin Dili: İngilizce DOI: 10.55730/1300-0527.3548 İndeks Tarihi: 12-06-2023

The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites

Öz:

The effect of octaisobutyl-polyhedral oligomeric silsesquioxane (OIB-POSS) as a nanosized reinforcement on the cure kinetics, crosslinking density, and mechanical properties of styrene-butadiene rubber (SBR) nanocomposites was examined in this study. For this purpose, SBR compounds with various OIB-POSS nanoparticle loadings at 1, 3, and 5 phr were prepared and their results were compared with a reference compound without OIB-POSS. When 1 phr of OIB-POSS was added to the rubber matrix, the elongation at break values and tensile strength of the corresponding nanocomposite increased by 24.1% and 29.2% compared to the reference sample, respectively. The presence of OIB-POSS nanoparticles and their random distribution in the SBR matrix was confirmed by transmission electron microscopy. The crosslinking density of nanocomposites was calculated by the Flory-Rehner method and a decrease was observed with the addition of OIB-POSS nanoparticles. In addition, thermal aging process as 70 °C for 70 h was applied to vulcanized samples. It was noted that the mechanical properties of SBR/OIB-POSS nanocomposites remarkably improved, whereas their crosslinking densities gradually decreased after thermal aging.

Anahtar Kelime: Nanocomposites nanoparticles polyhedral oligomeric silsesquioxane rubber styrene-butadiene rubber

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	Bekin Acar S, tasdelen m, Karaagac B (2023). The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites. , 417 - 425. 10.55730/1300-0527.3548
Chicago	Bekin Acar Seda,tasdelen mehmet atilla,Karaagac Bagdagul The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites. (2023): 417 - 425. 10.55730/1300-0527.3548
MLA	Bekin Acar Seda,tasdelen mehmet atilla,Karaagac Bagdagul The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites. , 2023, ss.417 - 425. 10.55730/1300-0527.3548
AMA	Bekin Acar S,tasdelen m,Karaagac B The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites. . 2023; 417 - 425. 10.55730/1300-0527.3548
Vancouver	Bekin Acar S,tasdelen m,Karaagac B The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites. . 2023; 417 - 425. 10.55730/1300-0527.3548
IEEE	Bekin Acar S,tasdelen m,Karaagac B "The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites." , ss.417 - 425, 2023. 10.55730/1300-0527.3548
ISNAD	Bekin Acar, Seda vd. "The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites". (2023), 417-425. https://doi.org/10.55730/1300-0527.3548

APA	Bekin Acar S, tasdelen m, Karaagac B (2023). The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites. Turkish Journal of Chemistry, 47(2), 417 - 425. 10.55730/1300-0527.3548
Chicago	Bekin Acar Seda,tasdelen mehmet atilla,Karaagac Bagdagul The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites. Turkish Journal of Chemistry 47, no.2 (2023): 417 - 425. 10.55730/1300-0527.3548
MLA	Bekin Acar Seda,tasdelen mehmet atilla,Karaagac Bagdagul The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites. Turkish Journal of Chemistry, vol.47, no.2, 2023, ss.417 - 425. 10.55730/1300-0527.3548
AMA	Bekin Acar S,tasdelen m,Karaagac B The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites. Turkish Journal of Chemistry. 2023; 47(2): 417 - 425. 10.55730/1300-0527.3548
Vancouver	Bekin Acar S,tasdelen m,Karaagac B The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites. Turkish Journal of Chemistry. 2023; 47(2): 417 - 425. 10.55730/1300-0527.3548
IEEE	Bekin Acar S,tasdelen m,Karaagac B "The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites." Turkish Journal of Chemistry, 47, ss.417 - 425, 2023. 10.55730/1300-0527.3548
ISNAD	Bekin Acar, Seda vd. "The effect of POSS nanoparticles on crosslinking of styrene-butadiene rubber nanocomposites". Turkish Journal of Chemistry 47/2 (2023), 417-425. https://doi.org/10.55730/1300-0527.3548