Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries
Yıl: 2023 Cilt: 47 Sayı: 2 Sayfa Aralığı: 495 - 503 Metin Dili: İngilizce DOI: 10.55730/1300-0527.3554 İndeks Tarihi: 12-06-2023
Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries
Öz: In this study, a facile approach has been developed to fabricate $GO/SiO_2$ nanosheets by the hydrolysis of tetraethyl orthosilicate (TEOS) in the graphene oxide (GO) solution with the assistance of the ultrasonication. The morphology and structure of the $SiO_2/GO$ nanosheets were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR) and Raman spectroscopy. The results showed that the covalently bonded SiO2 nanoparticles onto the GO sheets were dense and uniform. The agglomeration of the nanosheets was prevented by the ultrasonication and the layer sizes decreased throughout the synthesis process. The size and thickness of the $SiO_2$ nanoparticles were determined by the initially and externally added TEOS amounts, respectively, on the GO surface. The anode performance of the thermally reduced $rGO/SiO_2$ nanosheets was also observed in the Li-ion half-cell. The reversible capacity of the synthesized TrGOSN-1.5 anode was 424 mA $h g^{–1} at a current density of 100 mA g^{–1}$.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
- 1. Fichtner M, Edström K, Ayerbe E, Berecibar M, Bhowmik A et al. Rechargeable batteries of the future-the state of the art from a battery 2030+ perspective. Advanced Energy Materials 2021; (2102904): 1-25. https://doi.org/10.1002/aenm.202102904
- 2. Lökçü E, Toparli Ç, Anik M. Electrochemical performance of (MgCoNiZn)1-xLixO high-entropy oxides in lithium-ion batteries. ACS Applied Materials & Interfaces 2020; 12 (21): 23860-23866. https://doi.org/10.1021/acsami.0c03562
- 3. Ja’farawy MS, Hikmah DN, Riyadi U, Purwanto A, Widiyandari H. A review: The development of SiO2/C anode materials for lithium-ion batteries. Journal of Electronic Materials 2021; 50 (12): 6667–6687. https://doi.org/10.1007/s11664-021-09187-x
- 4. Jiao M, Wang Y, Ye C, Wang C, Zhang W et al. High-capacity SiOx (0≤x≤2) as promising anode materials for next-generation lithium-ion batteries. Journal of Alloys and Compounds 2020; 842 (155774): 1-21. https://doi.org/10.1016/j.jallcom.2020.155774
- 5. Marco MLD, Semlali S, Korgel BA, Barois P, Drisko GL et al. Silicon-based dielectric metamaterials: focus on the current synthetic challenges. Angewandte Chemie International Edition 2018; 57: 4478-4498. https://doi.org/10.1002/anie.201709044
- 6. Li X, Yan C, Wang J, Graff A, Schweizer SL et al. Stable silicon anodes for lithium-ion batteries using mesoporous metallurgical silicon. Advanced Energy Materials 2014; 1401556: 1-6. https://doi.org/10.1002/aenm.201401556
- 7. Zheng G, Xiang Y, Xu L, Luo H, Wang B et al. Controlling surface oxides in Si/C nanocomposite anodes for high-performance li-ion batteries. Advanced Energy Materials 2018; 1801718: 1-12. https://doi.org/10.1002/aenm.201801718
- 8. Buga MR, Spinu-Zaulet AA, Ungureanu CG, Mitran RA, Vasile E et al. Carbon-coated $SiO_2$ composites as promising anode material for li-ion batteries. Molecules 2021; 26 (15): 1-15. https://doi.org/10.3390/molecules26154531
- 9. Çelikbilek Z, Can S, Lökçü E, Anik M. Effect of rGO loading on the electrochemical performance of $Li_{22}Si_5/rGO$ composite anodes for lithium-ion batteries. International Journal of Energy Research 2021; 46: 1137-1145. https://doi.org/10.1002/er.7234
- 10. Zhou X, Wan LJ, Guo YG. Electrospun silicon nanoparticle/porous carbon hybrid nanofibers for lithium-ion batteries. Small 2013; 9 (16): 2684–2688. https://doi.org/10.1002/smll.201202071
- 11. Chen Y, Du N, Zhang H, Yang D. Firmly bonded graphene-silicon nanocomposites as high-performance anode materials for lithium-ion batteries. RSC Advances 2015; 5: 46173–46180. https://doi.org/10.1039/C5RA05869D
- 12. Lu Z, Zhu J, Sim D, Zhou W, Hng H et al. Synthesis of ultrathin silicon nanosheets by using graphene oxide as template. Chemistry of Materials 2011; 23: 5293−5295. https://doi.org/10.1021/cm202891p
- 13. Zhao Y, Sun B, Huang X, Liu H, Su D et al. Porous graphene wrapped CoO nanoparticles for highly efficient oxygen evolution. Journal of Materials Chemistry A 2015; 3: 5402–5408. https://doi.org/10.1039/C5TA00158G
- 14. Kou L, Gao C. Making silica nanoparticle-covered graphene oxide nanohybrids as general building blocks for large-area super hydrophilic coatings. Nanoscale 2011; 3: 519–528. https://doi.org/10.1039/C0NR00609B
- 15. Singh VK, Elomaa O, Sisko JL, Hannula S, Koskinen J. Lubricating properties of silica/graphene oxide composite powders. Carbon 2014; 79: 227–235. https://doi.org/10.1016/j.carbon.2014.07.063
- 16. Ma Y, Di H, Yu Z, Liang L, Lv L. Fabrication of silica-decorated graphene oxide nanohybrids and the properties of composite epoxy coatings research. Applied Surface Science 2016; 36: 936–945. https://doi.org/10.1016/j.apsusc.2015.11.088
- 17. Agnello S, Alessi A, Buscarino G, Piazza A, Maio A et al. Structural and thermal stability of graphene oxide-silica nanoparticles nanocomposites. Journal of Alloys Compounds 2017; 695: 2054–2064. https://doi.org/10.1016/j.jallcom.2016.11.044
- 18. Ling W, Choi H. Silica-graphene oxide hybrid composite particles and their electroresponsive characteristics. Langmuir 2012; 28: 7055– 7062. https://doi.org/10.1021/la3009283
- 19. Hintze C, Morita K, Riedel R, Lonescu E, Mera G. Facile sol-gel synthesis of reduced graphene oxide/silica nanocomposites. Journal of Europen Ceramic Society 2016; 36: 2923–2930. https://doi.org/10.1016/j.jeurceramsoc.2015.11.033
- 20. Lei Y, Hu Z, Cao B, Chen X, Song H et al. Enhancements of thermal insulation and mechanical property of silica aerogel monoliths by mixing graphene oxide. Materials Chemistry and Physics 2017; 187: 183–190. https://doi.org/10.1016/j.matchemphys.2016.11.064
- 21. Yan H, Jiang L, Xu X, Li Y, Shen Y et al. Ultrastrong composite film of Chitosan and silica-coated graphene oxide sheets. International Journal of Biological Macromolecules 2017; 104: 936–943. https://doi.org/10.1016/j.ijbiomac.2017.07.003
- 22. Sadroddini M, Razzaghi-Kashani M. Silica-decorated reduced graphene oxide $(SiO_2@rGO)$ as hybrid fillers for enhanced dielectric and actuation behavior of polydimethylsiloxane composites. Smart Materials and Structures 2019; 29 (1): 1-28. https://doi.org/10.1088/1361- 665X/ab57e8
- 23. Alrahlah A, Khan R, Al-Odayni AB, Saeed WS, Bautista LS et al. Evaluation of synergic potential of $rGO/SiO_2$ as hybrid filler for BisGMA/ TEGDMA dental composites. Polymers 2020; 12 (3025): 1-16. https://doi.org/10.3390/polym12123025
- 24. Muzyka R, Drewniak S, Pustelny T, Chrubasik M, Gryglewicz G. Characterization of graphite oxide and reduced graphene oxide obtained from different graphite precursors and oxidized by different methods using raman spectroscopy. Materials 2018; 11 (7): 15-17. https://doi. org/ 10.3390/ma14040769
- 25. Sun J, Xu Z, Li W, Shen X. Effect of $nano-SiO_2$ on the early hydration of alite-sulphoaluminate cement. Nanomaterials 2017; 7 (102): 1-15. https://doi.org/10.3390/nano7050102
- 26. Bertoluzza A, Fagnano C, Morelli M, Gottardi V, Guglielmi M. Raman and infrared spectra on silica gel evolving toward glass. Journal of Non-Crystalline Solids 1982; 48 (1): 117–128. https://doi.org/10.1016/0022-3093 (82)90250-2
- 27. Gómez-Navarro C, Weitz RT, Bittner AM, Scolari M, Mews A et al. Electronic transport properties of individual chemically reduced graphene oxide sheets. Nano Letters 2007; 7 (11): 3499–3503. doi:10.1021/nl072090c
- 28. Yan N, Wang F, Zhong H, Li Y, Wang Y. Hollow porous $SiO_2$ nanocubes towards high-performance anodes for lithium-ion batteries. Scientific Reports 2013; 3: 1-6. https://doi.org/10.1038/srep01568
- 29. Guo B, Shu J, Wang Z, Yang H, Shi L. Electrochemical reduction of $nano-SiO_2$ in hard carbon as anode material for lithium ion batteries. Electrochemical Communication 2008; 10: 1876–1878. https://doi.org/10.1016/j.elecom.2008.09.032
- 30. Wang Y, Zhou W, Zhang L, Song G, Cheng S. $SiO_2@NiO$ core-shell nanocomposites as high performance anode materials for lithium-ion batteries. RSC Advances 2015; 5: 63012–63016. https://doi.org/10.1039/C5RA11243E
- 31. Sun L, Liu Y, Wu J, Shao R, Jiang R et al. A review on recent advances for boosting initial coulombic efficiency of silicon anodic lithium ion batteries. Small 2022; 18 (2102894): 1-19. https://doi.org/10.1002/smll.202102894
- 32. Yan MY, Li G, Zhang J, Tian YF, Yin YX et al. Enabling SiOx/C anode with high initial coulombic efficiency through a chemical pre- lithiation strategy for high energy density lithium-ion batteries. ACS Applied Materials & Interfaces 2020; 12 (24): 27202-27209. https:// doi.org/10.1021/acsami.0c05153
- 33. Bannov AG, Popov MV, Kurmashov PB. Thermal analysis of carbon nanomaterials: advantages and problems of interpretation. Journal of Thermal Analysis and Calorimetry 2020; 142: 349–370. https://doi.org/10.1007/s10973-020-09647-2
- 34. Farah S, Farkas A, Madarász J, László K. Comparison of thermally and chemically reduced graphene oxides by thermal analysis and Raman spectroscopy. Journal of Thermal Analysis and Calorimetry 2020; 142: 331–337. https://doi.org/10.1007/s10973-020-09719-3
| APA | Lökçü E, CAN S, Anik M (2023). Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries. , 495 - 503. 10.55730/1300-0527.3554 |
| Chicago | Lökçü Ersu,CAN SÜLEYMAN,Anik Mustafa Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries. (2023): 495 - 503. 10.55730/1300-0527.3554 |
| MLA | Lökçü Ersu,CAN SÜLEYMAN,Anik Mustafa Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries. , 2023, ss.495 - 503. 10.55730/1300-0527.3554 |
| AMA | Lökçü E,CAN S,Anik M Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries. . 2023; 495 - 503. 10.55730/1300-0527.3554 |
| Vancouver | Lökçü E,CAN S,Anik M Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries. . 2023; 495 - 503. 10.55730/1300-0527.3554 |
| IEEE | Lökçü E,CAN S,Anik M "Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries." , ss.495 - 503, 2023. 10.55730/1300-0527.3554 |
| ISNAD | Lökçü, Ersu vd. "Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries". (2023), 495-503. https://doi.org/10.55730/1300-0527.3554 |
| APA | Lökçü E, CAN S, Anik M (2023). Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries. Turkish Journal of Chemistry, 47(2), 495 - 503. 10.55730/1300-0527.3554 |
| Chicago | Lökçü Ersu,CAN SÜLEYMAN,Anik Mustafa Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries. Turkish Journal of Chemistry 47, no.2 (2023): 495 - 503. 10.55730/1300-0527.3554 |
| MLA | Lökçü Ersu,CAN SÜLEYMAN,Anik Mustafa Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries. Turkish Journal of Chemistry, vol.47, no.2, 2023, ss.495 - 503. 10.55730/1300-0527.3554 |
| AMA | Lökçü E,CAN S,Anik M Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries. Turkish Journal of Chemistry. 2023; 47(2): 495 - 503. 10.55730/1300-0527.3554 |
| Vancouver | Lökçü E,CAN S,Anik M Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries. Turkish Journal of Chemistry. 2023; 47(2): 495 - 503. 10.55730/1300-0527.3554 |
| IEEE | Lökçü E,CAN S,Anik M "Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries." Turkish Journal of Chemistry, 47, ss.495 - 503, 2023. 10.55730/1300-0527.3554 |
| ISNAD | Lökçü, Ersu vd. "Ultrasound-assisted synthesis of rGO/SiO2-based nanosheets and their electrochemical performances in Li-ion batteries". Turkish Journal of Chemistry 47/2 (2023), 495-503. https://doi.org/10.55730/1300-0527.3554 |
