Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method

bagda, esra

doi:10.17350/HJSE19030000296

Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method

Esra BAĞDA (Sivas Cumhuriyet Üniversitesi, Temel Eczacılık Bilimleri Anabilim Dalı, Sivas, Türkiye)

Hittite Journal of Science and Engineering

11 7

Yıl: 2023 Cilt: 10 Sayı: 2 Sayfa Aralığı: 185 - 191 Metin Dili: İngilizce DOI: 10.17350/HJSE19030000296 İndeks Tarihi: 31-07-2023

Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method

Öz:

In the present study a new kinetic catalytic method was developed for the sensitive determination of selenium in pharmaceutical formulations. The reaction between basic blue 3 (BB3) and sulphide catalysed by Se (IV) in the presence of acetic-phosphoric-boric acid buffer system. The decrease in the absorbance at 654 nm indicated the reduction of BB3. The presence of selenium (IV) accelerated the reaction rate. The method based on the linear correlation between amount of Se(IV) and reaction rate. Under optimum conditions, the linear calibration range was found as 0.1-2.0 µg ml-1 by the fixed time method for the 0.5-5 min. The tolerance limits of various species was also studied. The interfering effect of some cations such as Cr3+, Fe3+, and Hg2+ was reduced with using cation exchange resin. The proposed method was successfully applied to spiked nasal spray and veterinary drug samples. Besides, total selenium, Se (IV) and Se (VI) speciation also conducted with reducing Se (VI) to Se (IV) with HCl in the synthetic mixtures.

Anahtar Kelime: Selenium pharmaceutical samples veterinary drug

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	bagda e (2023). Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method. , 185 - 191. 10.17350/HJSE19030000296
Chicago	bagda esra Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method. (2023): 185 - 191. 10.17350/HJSE19030000296
MLA	bagda esra Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method. , 2023, ss.185 - 191. 10.17350/HJSE19030000296
AMA	bagda e Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method. . 2023; 185 - 191. 10.17350/HJSE19030000296
Vancouver	bagda e Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method. . 2023; 185 - 191. 10.17350/HJSE19030000296
IEEE	bagda e "Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method." , ss.185 - 191, 2023. 10.17350/HJSE19030000296
ISNAD	bagda, esra. "Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method". (2023), 185-191. https://doi.org/10.17350/HJSE19030000296

APA	bagda e (2023). Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method. Hittite Journal of Science and Engineering, 10(2), 185 - 191. 10.17350/HJSE19030000296
Chicago	bagda esra Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method. Hittite Journal of Science and Engineering 10, no.2 (2023): 185 - 191. 10.17350/HJSE19030000296
MLA	bagda esra Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method. Hittite Journal of Science and Engineering, vol.10, no.2, 2023, ss.185 - 191. 10.17350/HJSE19030000296
AMA	bagda e Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method. Hittite Journal of Science and Engineering. 2023; 10(2): 185 - 191. 10.17350/HJSE19030000296
Vancouver	bagda e Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method. Hittite Journal of Science and Engineering. 2023; 10(2): 185 - 191. 10.17350/HJSE19030000296
IEEE	bagda e "Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method." Hittite Journal of Science and Engineering, 10, ss.185 - 191, 2023. 10.17350/HJSE19030000296
ISNAD	bagda, esra. "Determination and Speciation of Selenium in Pharmaceutical Samples, Spiked Veterinary Drug Samples with a Kinetic Catalytic Method". Hittite Journal of Science and Engineering 10/2 (2023), 185-191. https://doi.org/10.17350/HJSE19030000296