The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO
Yıl: 2023 Cilt: 13 Sayı: 4 Sayfa Aralığı: 1127 - 1139 Metin Dili: İngilizce DOI: 10.17714/gumusfenbil.1339172 İndeks Tarihi: 23-10-2023
The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO
Öz: Developing more biocompatible biomaterials with mechanical properties similar to those of cortical bone has long been a challenge for scientists. They are still working on new alloys and coating processes to meet this challenge. Among these biocompatible materials, ß-titanium alloys, which will prevent stress-shielding and have a Poisson’s ratio very close to the cortical bone, have been attracting the attention of scientists for a long time. In addition to this, the PEO method, which makes it possible to embed ions into the oxide layer, has also come to the fore in recent years as a surface treatment in order to increase the corrosion resistance, wear resistance and biocompatibility of biomaterials and also to provide antibacterial/antimicrobial properties. In this study, Ca and P-containing oxide layers with two different boron content and no boron content were successfully formed on Ti45Nb ß-titanium alloy substrate by using the PEO method. Surface characterization and corrosion resistance tests of these layers were carried out. The obtained results were compared with each other and with the uncoated substrate. XRD analysis showed that the coatings are primarily composed of two major polymorphs of TiO2, anatase and rutile. Static electrochemical measurements were made in diluted Foetal Bovine Serum (FBS) and hydrogen peroxide added serum. H2O2 was added to simulate the inflammatory state in the body. The measurements showed that all the coated samples had lower corrosion current densities compared to the uncoated ones both in serum and H2O2-added serum.
Anahtar Kelime: Elektrolit içerisindeki bor miktarının PEO ile kaplanan Ti45Nb'nin korozyon özelliklerine etkisi
Öz: Kortikal kemiğe benzer mekanik özelliklere sahip daha biyouyumlu biyomalzemeler geliştirmek uzun zamandır bilim adamları için bir zorluk olmuştur. Bu zorluğun üstesinden gelmek için hala yeni alaşımlar ve kaplama süreçleri üzerinde çalışmalar sürmektedir. Bu biyouyumlu malzemeler arasında stres kalkanı etkisini önleyecek ve kortikal kemiğe çok yakın Poisson oranına sahip ß-titanyum alaşımları uzun süredir bilim insanlarının ilgisini çekmektedir. Bunun yanı sıra oksit tabakasına iyon gömmeyi mümkün kılan PEO yöntemi, biyomalzemelerin korozyon direncini, aşınma direncini ve biyouyumluluğunu artırmak aynı zamanda antibakteriyel/antimikrobiyal özellikler sağlamak amacıyla son yıllarda bir yüzey işlemi olarak öne çıkmaktadır. Bu çalışmada, PEO yöntemi kullanılarak Ti45Nb ß-titanyum alaşımlı altlık üzerinde iki farklı bor içeriğine sahip ve bir de bor içermeyen Ca ve P içeren oksit tabakaları başarıyla oluşturulmuştur. Bu tabakaların yüzey karakterizasyonları ve korozyon dayanım testleri yapılmıştır. Elde edilen sonuçlar kendi aralarında ve kaplanmamış numuneler ile karşılaştırılmıştır. XRD analizlerinde kaplamaların temel olarak iki ana TiO2 polimorfundan, anataz ve rutilden oluştuğu görülmüştür. Seyreltilmiş Fetal Sığır Serumu (FBS) ve hidrojen peroksit eklenmiş serumda statik elektrokimyasal ölçümler yapılmıştır. H2O2 vücuttaki enflamatuar durumu simüle etmek için eklenmiştir. Ölçümler, kaplanmış tüm numunelerin hem serumda hem de H2O2 ilaveli serumda kaplanmamış olanlara kıyasla daha düşük korozyon akımı yoğunluklarına sahip olduğunu göstermiştir.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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| APA | Vangolu Y, Bayrak Ö (2023). The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO. , 1127 - 1139. 10.17714/gumusfenbil.1339172 |
| Chicago | Vangolu Yenal,Bayrak Özgü The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO. (2023): 1127 - 1139. 10.17714/gumusfenbil.1339172 |
| MLA | Vangolu Yenal,Bayrak Özgü The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO. , 2023, ss.1127 - 1139. 10.17714/gumusfenbil.1339172 |
| AMA | Vangolu Y,Bayrak Ö The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO. . 2023; 1127 - 1139. 10.17714/gumusfenbil.1339172 |
| Vancouver | Vangolu Y,Bayrak Ö The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO. . 2023; 1127 - 1139. 10.17714/gumusfenbil.1339172 |
| IEEE | Vangolu Y,Bayrak Ö "The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO." , ss.1127 - 1139, 2023. 10.17714/gumusfenbil.1339172 |
| ISNAD | Vangolu, Yenal - Bayrak, Özgü. "The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO". (2023), 1127-1139. https://doi.org/10.17714/gumusfenbil.1339172 |
| APA | Vangolu Y, Bayrak Ö (2023). The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO. Gümüşhane Üniversitesi Fen Bilimleri Dergisi, 13(4), 1127 - 1139. 10.17714/gumusfenbil.1339172 |
| Chicago | Vangolu Yenal,Bayrak Özgü The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO. Gümüşhane Üniversitesi Fen Bilimleri Dergisi 13, no.4 (2023): 1127 - 1139. 10.17714/gumusfenbil.1339172 |
| MLA | Vangolu Yenal,Bayrak Özgü The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO. Gümüşhane Üniversitesi Fen Bilimleri Dergisi, vol.13, no.4, 2023, ss.1127 - 1139. 10.17714/gumusfenbil.1339172 |
| AMA | Vangolu Y,Bayrak Ö The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO. Gümüşhane Üniversitesi Fen Bilimleri Dergisi. 2023; 13(4): 1127 - 1139. 10.17714/gumusfenbil.1339172 |
| Vancouver | Vangolu Y,Bayrak Ö The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO. Gümüşhane Üniversitesi Fen Bilimleri Dergisi. 2023; 13(4): 1127 - 1139. 10.17714/gumusfenbil.1339172 |
| IEEE | Vangolu Y,Bayrak Ö "The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO." Gümüşhane Üniversitesi Fen Bilimleri Dergisi, 13, ss.1127 - 1139, 2023. 10.17714/gumusfenbil.1339172 |
| ISNAD | Vangolu, Yenal - Bayrak, Özgü. "The effect of boron amount in the electrolyte on the corrosion properties of Ti45Nb coated by PEO". Gümüşhane Üniversitesi Fen Bilimleri Dergisi 13/4 (2023), 1127-1139. https://doi.org/10.17714/gumusfenbil.1339172 |
