Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography

Yıl: 2023 Cilt: 27 Sayı: 5 Sayfa Aralığı: 1002 - 1007 Metin Dili: İngilizce DOI: 10.16984/saufenbilder.1265507 İndeks Tarihi: 26-10-2023

Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography

Öz:
In this study, a high performance liquid chromatography-ultraviolet detection method was introduced for the detection of cymoxanil. The experimental parameters of the procedure were thoroughly evaluated. Cymoxanil was eluted by ammonium formate buffer (50.0 mM, pH 4.0):acetonitrile (55:45 v/v) as mobile phase. Under the optimal conditions, the limits of detection and quantification (LOD and LOQ) were found as 7.4 – 24.8 µg kg-1, which allows trace determination of pesticides in food samples. Proposed method was then implemented for the determination of selected fungicide in potato flour samples with acceptable % recoveries in the range of 81.4–112.9%, while the values of relative standard deviation (RSD) were below 10% showing a satisfactory applicability for cymoxanil in such complex real samples matrix.
Anahtar Kelime: Cymoxanil potato flour high performance liquid chromatography fungidice

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
  • [1] F. M. Al-Nasir, A. G. Jiries, G. J. Al- Rabadi, M. H. Alu'datt, C. C. Tranchant, S. A. Al-Dalain, N. Alrabadi, O. Y. Madanat, R. S. Al- Dmour, "Determination of pesticide residues in selected citrus fruits and vegetables cultivated in the Jordan Valley" LWT, vol. 123, pp. 109005, 2020.
  • [2] A. Abbasalizadeh, S. M. Sorouraddin, M. A. Farajzadeh, M. Nemati, M. R. A. Mogoddam, "Dispersive solid phase extraction of several pesticides from fruit juices using a hydrophobic metal organic framework prior to HPLC- MS/MS determination" Journal of Food Composition and Analysis, vol. 114, pp. 104788, 2022.
  • [3] H. Serbest, "Determination of Resmethrin in Corn Silk Matrix by Gas Chromatography-Flame Ionization Detector (GC-FID)" Sakarya University Journal of Science, vol. 26(5), pp. 1022-1028, 2022.
  • [4] S. Amini, M. Amiri, H. Ebrahimzadeh, S. Seidi, S. H. kandeh, "Synthesis of magnetic Cu/CuFe2O4@ MIL-88A (Fe) nanocomposite and application to dispersive solid-phase extraction of chlorpyrifos and phosalone in water and food samples" Journal of Food Composition and Analysis, vol. 104, pp. 104128, 2021.
  • [5] R.C. Gilden, K. Huffling, B. Sattler, "Pesticides and health risks" Journal of Obstetric, Gynecologic & Neonatal Nursing, vol. 39(1), pp. 103-110, 2010.
  • [6] K. -H. Kim, E. Kabir, S. A. Jahan, "Exposure to pesticides and the associated human health effects" Science of the total environment, vol. 575, pp. 525-535, 2017.
  • [7] V. Feigenbrugel, S. Le Calvé, P. Mirabel, "Molar absorptivities of 2, 4- D, cymoxanil, fenpropidin, isoproturon and pyrimethanil in aqueous solution in the near-UV" Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 63(1), pp. 103-110, 2006.
  • [8] J. -Y. Yoon, J. E. Kim, H. J. Song, K. B. Oh, J. W. Jo, Y. -H. Yang, S. H. Lee, G. Kang, H. J. Kim, Y. -K. Choi, "Assessment of adsorptive behaviors and properties of grape pomace- derived biochar as adsorbent for removal of cymoxanil pesticide" Environmental Technology & Innovation, vol. 21, pp. 101242, 2021.
  • [9] X. Jiang, H. Jin, Y. Sun, R. Gui, "Colorimetric and fluorometric dual- channel ratiometric determination of fungicide cymoxanil based on analyte- induced aggregation of silver nanoparticles and dually emitting carbon dots" Microchimica Acta, vol. 186, pp. 1-12, 2019.
  • [10] H. Mercan, R. Inam, "Determination of Cymoxanil Fungicide in Commercial Formulation and Natural Water by Square wave Stripping Voltammetry" CLEAN–Soil, Air, Water, vol. 38(5 6), pp. 558-564, 2010.
  • [11] P. Fidente, C. D. Giovanni, S. Seccia, P. Morrica, "Determination of cymoxanil in drinking water and soil using high performance liquid chromatography" Biomedical Chromatography, vol. 19(10), pp. 766- 770, 2005.
  • [12] A. S. TP, K. Banerjee, M. Jadhav, R. Girame, S. Utture, S. Hingmire, D. Oulkar, "Residue dissipation and processing factor for dimethomorph, famoxadone and cymoxanil during raisin preparation" Food chemistry, vol. 170, pp. 180-185, 2015.
  • [13] M. J. Hengel, T. Shibamoto, "Development of a gas chromatographic method for fungicide cymoxanil analysis in dried hops" Journal of agricultural and food chemistry, vol. 49(2), pp. 570-573, 2001.
  • [14] D. Bavol, J. Zima, J. Barek, H. Dejmkova, "Voltammetric determination of cymoxanil and famoxadone at different types of carbon electrodes" Electroanalysis, vol. 28(5), pp. 1029-1034, 2016.
  • [15] K. Dost, M. Öksüz, M. Cittan, B. Mutlu, B. Tural, "Determination of boscalid, pyraclostrobin and trifloxystrobin in dried grape and apricot by HPLC/UV method" Journal of Food Composition and Analysis, vol. 115, pp. 104926, 2023.
  • [16] R. R. Pasupuleti, Z. -F. Wang, W. -J. Ya, C. -A. Kuo, Y. -Y Chao, Y. -L. Huang, "Extraction and detection of chlorophenols in water samples using deep eutectic solvent-based dispersive liquid–liquid microextraction coupled with HPLC-UV" Microchemical Journal, vol. 182, pp. 107843, 2022.
APA Unutkan" T (2023). Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. , 1002 - 1007. 10.16984/saufenbilder.1265507
Chicago Unutkan" Tuğçe Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. (2023): 1002 - 1007. 10.16984/saufenbilder.1265507
MLA Unutkan" Tuğçe Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. , 2023, ss.1002 - 1007. 10.16984/saufenbilder.1265507
AMA Unutkan" T Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. . 2023; 1002 - 1007. 10.16984/saufenbilder.1265507
Vancouver Unutkan" T Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. . 2023; 1002 - 1007. 10.16984/saufenbilder.1265507
IEEE Unutkan" T "Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography." , ss.1002 - 1007, 2023. 10.16984/saufenbilder.1265507
ISNAD Unutkan", Tuğçe. "Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography". (2023), 1002-1007. https://doi.org/10.16984/saufenbilder.1265507
APA Unutkan" T (2023). Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 27(5), 1002 - 1007. 10.16984/saufenbilder.1265507
Chicago Unutkan" Tuğçe Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi 27, no.5 (2023): 1002 - 1007. 10.16984/saufenbilder.1265507
MLA Unutkan" Tuğçe Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol.27, no.5, 2023, ss.1002 - 1007. 10.16984/saufenbilder.1265507
AMA Unutkan" T Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2023; 27(5): 1002 - 1007. 10.16984/saufenbilder.1265507
Vancouver Unutkan" T Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2023; 27(5): 1002 - 1007. 10.16984/saufenbilder.1265507
IEEE Unutkan" T "Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography." Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 27, ss.1002 - 1007, 2023. 10.16984/saufenbilder.1265507
ISNAD Unutkan", Tuğçe. "Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography". Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi 27/5 (2023), 1002-1007. https://doi.org/10.16984/saufenbilder.1265507