Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane

Serdar AKBAYRAK, (Necmettin Erbakan Üniversitesi, Mühendislik Fakültesi, Temel Bilimler Bölümü, Konya, Türkiye)
Yalçın TONBUL, (Dicle Üniversitesi, Ziya Gökalp Eğitim Fakültesi, Diyarbakır, Türkiye)
Saim ÖZKAR (Orta Doğu Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Ankara, Türkiye)
Turkish Journal of Chemistry
6 0
Yıl: 2023 Cilt: 47 Sayı: 5 Sayfa Aralığı: 1224 - 1238 Metin Dili: İngilizce DOI: 10.55730/1300-0527.3607 İndeks Tarihi: 21-11-2023

Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane

Öz:
Reducible WO3 powder with a mean diameter of 100 nm is used as support to stabilize ruthenium(0) nanoparticles. Ruthenium(0) nanoparticles are obtained by $NaBH_4$ reduction of ruthenium(III) precursor on the surface of $WO_3$ support at room temperature. Ruthenium(0) nanoparticles are uniformly dispersed on the surface of tungsten(VI) oxide. The obtained $R^u0/WO_3$ nanoparticles are found to be active catalysts in hydrolytic dehydrogenation of ammonia borane. The turnover frequency (TOF) values of the $R^u0/WO_3$ nanocatalysts with the metal loading of 1.0%, 2.0%, and 3.0% wt. Ru are 122, 106, and 83 $min^{–1}$, respectively, in releasing hydrogen gas from the hydrolysis of ammonia borane at 25.0 °C. As the $R^u0/WO_3$ (1.0% wt. Ru) nanocatalyst with an average particle size of 2.6 nm provides the highest activity among them, it is extensively investigated. Although the Ru0/WO3 (1.0% wt. Ru) nanocatalyst is not magnetically separable, it has extremely high reusability in the hydrolysis reaction as it preserves 100% of initial catalytic activity even after the 5th run of hydrolysis. The high activity and reusability of $R^u0/WO_3$ (1.0% wt. Ru) nanocatalyst are attributed to the favorable metal-support interaction between the ruthenium(0) nanoparticles and the reducible tungsten(VI) oxide. The high catalytic activity and high stability of $R^u0/WO_3$ nanoparticles increase the catalytic efficiency of precious ruthenium in hydrolytic dehydrogenation of ammonia borane.
Anahtar Kelime: Ruthenium tungsten(vi) oxide catalytic activity ammonia borane reusability hydrolytic dehydrogenation

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA Akbayrak S, TONBUL Y, Özkar S (2023). Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane. , 1224 - 1238. 10.55730/1300-0527.3607
Chicago Akbayrak Serdar,TONBUL YALCIN,Özkar Saim Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane. (2023): 1224 - 1238. 10.55730/1300-0527.3607
MLA Akbayrak Serdar,TONBUL YALCIN,Özkar Saim Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane. , 2023, ss.1224 - 1238. 10.55730/1300-0527.3607
AMA Akbayrak S,TONBUL Y,Özkar S Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane. . 2023; 1224 - 1238. 10.55730/1300-0527.3607
Vancouver Akbayrak S,TONBUL Y,Özkar S Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane. . 2023; 1224 - 1238. 10.55730/1300-0527.3607
IEEE Akbayrak S,TONBUL Y,Özkar S "Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane." , ss.1224 - 1238, 2023. 10.55730/1300-0527.3607
ISNAD Akbayrak, Serdar vd. "Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane". (2023), 1224-1238. https://doi.org/10.55730/1300-0527.3607
APA Akbayrak S, TONBUL Y, Özkar S (2023). Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane. Turkish Journal of Chemistry, 47(5), 1224 - 1238. 10.55730/1300-0527.3607
Chicago Akbayrak Serdar,TONBUL YALCIN,Özkar Saim Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane. Turkish Journal of Chemistry 47, no.5 (2023): 1224 - 1238. 10.55730/1300-0527.3607
MLA Akbayrak Serdar,TONBUL YALCIN,Özkar Saim Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane. Turkish Journal of Chemistry, vol.47, no.5, 2023, ss.1224 - 1238. 10.55730/1300-0527.3607
AMA Akbayrak S,TONBUL Y,Özkar S Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane. Turkish Journal of Chemistry. 2023; 47(5): 1224 - 1238. 10.55730/1300-0527.3607
Vancouver Akbayrak S,TONBUL Y,Özkar S Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane. Turkish Journal of Chemistry. 2023; 47(5): 1224 - 1238. 10.55730/1300-0527.3607
IEEE Akbayrak S,TONBUL Y,Özkar S "Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane." Turkish Journal of Chemistry, 47, ss.1224 - 1238, 2023. 10.55730/1300-0527.3607
ISNAD Akbayrak, Serdar vd. "Reducible tungsten(VI) oxide-supported ruthenium(0) nanoparticles: highly active catalyst for hydrolytic dehydrogenation of ammonia borane". Turkish Journal of Chemistry 47/5 (2023), 1224-1238. https://doi.org/10.55730/1300-0527.3607
Sayfa Oluşturulma Tarihi
24-04-2024 9:47

İLETİŞİM

TÜBİTAK ULAKBİM TR Dizin

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06530 Çankaya / ANKARA +90 (312) 298 92 00

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