An investigation of fastness properties of textile materials colored with azo dyes

AKSU, İlker; karapinar, EMİN

An investigation of fastness properties of textile materials colored with azo dyes

Emin KARAPINAR, (Pamukkale Üniversitesi, Fen Fakültesi, Kimya Bölümü, Denizli, Türkiye,)

İlker AKSU (Deniz Tekstil Fabrikası, Organize Sanayi Bölgesi, Denizli, Türkiye,)

Tekstil ve Mühendis

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Yıl: 2013 Cilt: 20 Sayı: 90 Sayfa Aralığı: 17 - 24 Metin Dili: Türkçe İndeks Tarihi: 29-07-2022

An investigation of fastness properties of textile materials colored with azo dyes

Öz:

Bu çalışmada, literatürde bulunan bir seri disazo-3-metil-1H-pirazol-5-on türevleri (5a-e) yeniden sentezlenmiştir. Yapıları FT-IR ve erime noktası ile doğrulanmıştır. Sentezlenen boyarmaddeler ile multifibre kumaş üzerine boyama ön denemeleri yapılmıştır. Boyarmaddelerin naylon 6,6 ve poliesteri boyayabildiği görülmüştür. Naylon 6,6 ve poliester kumaş üzerine laboratuar ortamında boyamalar yapılmış ve bu tekstil malzemelerini boyama özellikleri incelenmiştir. ISO standartlarına göre, suya karşı, asidik ve bazik tere karşı, $40^{0}C$ ve $60^{0}C$ yıkamaya karşı, 20 ppm klorlu suya karşı, yaş ve kuru sürtmeye karşı haslıkları incelenmiştir. Bulunan haslık sonuçları bunlara yakın renk veren ticari boyalar (T1 ve T2) ile kıyaslanmıştır. Yapılan haslık testlerinin sonuçları incelendiğinde, sentezlenen 5a, 5b, 5c, 5d ve 5e boyarmaddelerinin özellikle naylon, asetat ve PES elyaflarını kirletme değerleri T1 ve T2 ye nazaran daha iyi, buna karşın yaş ve kuru sürtme değerlerinin yarım ile 3 puan arası kötü olduğu şeklinde özetlenebilir. Tüm boyaların klorlu su haslıkları ve renk değişimleri birbirine denktir.

Anahtar Kelime:

Azo boyarmaddeler ile boyanan tekstil malzemelerinin haslık özelliklerinin incelenmesi

Öz:

In this study, a series of disazo-3-methyl-1H-pyrazole-5-on derivatives (5a-e) ,which can also be found in previous studies, has been re-synthesized. Their structures were verified with FT-IR results and the melting points. Preliminary dyeing experiments with synthesized dyes had been applied to multifiber fabric. All dyeing experiments to Nylon 6,6 (PA6.6) and Polyester (PES) fabric were made in the laboratory and dyeing properties of textile materials used were investigated. In the end, it was found that the synthesized dyes could be applied to fabric, which is made of PA6.6 and PES.Fastnesses were examined according to ISO standards. The following were the applied fastnesses: water, perspiration, washing at $40^{0}C$ and $60^{0}C$, in pool water with 20 ppm, and wet/dry rubbing. All results were compared with closest commercial dyes (T1 and T2). As the results of the fastness tests have been investigated, it can be summarized that staining values of synthesized 5a, 5b, 5c, 5d and 5e dyes, especially for nylon, acetate and PES fibers, are better than T1 and T2, whereas wet and dry rubbing values are worse being between 0.5 and 3s. Chlorined water fastness and color changes of all dyes are equal to each other.

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

1. Karci, F., Sener, N., Yamac, M., Sener, I., Demircali, A., (2009), The synthesis, antimicrobial activity and absorption characteristics of some novel heterocyclic disazo dyes, Dyes and Pigments., 80(1): 47-52.
2. Sabnis, R.W., Rangnekar, D.W., (1990), Synthesis of 2-azo- 3-cyano-5-carbethoxy thiophene derivatives and their application on polyester fibres, J. Chem. Tech. Biotechnol., 47(1): 3946.
3. Karci, F., (2005), Synthesis of disazo dyes derived from heterocyclic components, Coloration Technology., 121(5): 275-280.
4. Hanna, M.A., Girges, M.M., Fadda, A.A., (1992), New Dyestuffs for Polyester Fibres-Synthesis and comparative Tinctorial Behaviour of 3-Alkyl-4-aryl hidrazono-N1-picolinoyl-2- pyrazolin-5-ones and their isomeric pyrid-3-and-4-yl Anologues. J. Chem. Tech. Biotechnol., 55(1): 9-16.
5. Abdel-Latif, F.M., Barsy, M.A., Elbadry, E.A., Hassan, M., (1999), New routes for novel pyrazolo[3,4-b][1,6]- naphthyridine, pyrazolo [3,4-b] pyridine and pyrazolo [3,4:2,3] pyrido [6,1-a] benzimidazole derivatives, J. Chem. Res. (S)., 12: 696-697.
6. Elagamey, A.G.A., Mohamed, F., Eltaweel, A.A., (1991), Nitriles In Heterocyclic Synthesis -Synthesis of Pyrazolo[ 1,5-a]Pyrimidine, Pyrazolo[1,5-c][1,2,4]Triazine And Pyrazolo[4,3-e][1,2,4]Triazine Derivatives. J. Prakt. Chem., 333(2): 333-338.
7. Ho, Y.W., (2005), Synthesis of some new azo pyrazolo[1,5- a] pyrimidine-thieno[2,3-b]pyridine derivatives and their application as disperse dyes, Dyes and Pigments., 64(3): 223- 230.
8. Tsai, P.C., Wang, I.J., (2005), Synthesis and solvatochromic properties of some disazo dyes derived from pyrazolo[1,5- a]pyrimidine derivatives, Dyes and Pigments., 64(3): 259-264.
9. Ozcan, Y., (1984), Textile Fibers and Dyeing Technique, Istanbul University Publications, No:3176, Istanbul.
10. TS 837 EN ISO 105-E03/April, (2006): Textile- Color Fastness Tests- Volume: E03: Color fastness to chlorinated water( swimming pool water)tests methods, Ankara.
11. TS 717 EN ISO 105-X12/ April, (2006): Textile- Color Fastness Tests- Volume:X12: Color fastness to rubbing test methods, Ankara.
12. TS 396 EN ISO 105-E01/ April, (2006): Textile- Color Fastness Tests- Volume:E01: Color fastness to water test methods, Ankara.
13. TS 7584 EN ISO 105-C06/November, (1989): Color fastness test methods for dyed and/or printed textile products-Colour fastness to domestic and commercial laundering process, Ankara.
14. TS 398 EN ISO 105-E04/ April, (2006): Textile- Color Fastness Tests- Volume:E04: Color fastness to perspiration test methods, Ankara.
15.Demircali, A., (2006), Synthesis Of New Disazo Dyes And Investigated Of Their Absorption Properties, M. Sc. Thesis in Chemistry, Pamukkale University, Graduate School of Education Sciences, Denizli.

APA	karapinar E, AKSU İ (2013). An investigation of fastness properties of textile materials colored with azo dyes. , 17 - 24.
Chicago	karapinar EMİN,AKSU İlker An investigation of fastness properties of textile materials colored with azo dyes. (2013): 17 - 24.
MLA	karapinar EMİN,AKSU İlker An investigation of fastness properties of textile materials colored with azo dyes. , 2013, ss.17 - 24.
AMA	karapinar E,AKSU İ An investigation of fastness properties of textile materials colored with azo dyes. . 2013; 17 - 24.
Vancouver	karapinar E,AKSU İ An investigation of fastness properties of textile materials colored with azo dyes. . 2013; 17 - 24.
IEEE	karapinar E,AKSU İ "An investigation of fastness properties of textile materials colored with azo dyes." , ss.17 - 24, 2013.
ISNAD	karapinar, EMİN - AKSU, İlker. "An investigation of fastness properties of textile materials colored with azo dyes". (2013), 17-24.

APA	karapinar E, AKSU İ (2013). An investigation of fastness properties of textile materials colored with azo dyes. Tekstil ve Mühendis, 20(90), 17 - 24.
Chicago	karapinar EMİN,AKSU İlker An investigation of fastness properties of textile materials colored with azo dyes. Tekstil ve Mühendis 20, no.90 (2013): 17 - 24.
MLA	karapinar EMİN,AKSU İlker An investigation of fastness properties of textile materials colored with azo dyes. Tekstil ve Mühendis, vol.20, no.90, 2013, ss.17 - 24.
AMA	karapinar E,AKSU İ An investigation of fastness properties of textile materials colored with azo dyes. Tekstil ve Mühendis. 2013; 20(90): 17 - 24.
Vancouver	karapinar E,AKSU İ An investigation of fastness properties of textile materials colored with azo dyes. Tekstil ve Mühendis. 2013; 20(90): 17 - 24.
IEEE	karapinar E,AKSU İ "An investigation of fastness properties of textile materials colored with azo dyes." Tekstil ve Mühendis, 20, ss.17 - 24, 2013.
ISNAD	karapinar, EMİN - AKSU, İlker. "An investigation of fastness properties of textile materials colored with azo dyes". Tekstil ve Mühendis 20/90 (2013), 17-24.