Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples

Iulia Gabriela DAVID, (Department of Analytical Chemistry, Faculty of Chemistry, University of Bucharest, Bucharest, Romania)
Irinel Adriana BADEA, (Department of Analytical Chemistry, Faculty of Chemistry, University of Bucharest, Bucharest, Romania)
Gabriel Lucian RADU (Department of Analytical Chemistry and Environmental Engineering,Faculty of Applied Chemistry and Material Science, University “Politehnica” Bucharest, Bucharest, Romania)
Turkish Journal of Chemistry
2 0
Yıl: 2013 Cilt: 37 Sayı: 1 Sayfa Aralığı: 91 - 100 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples

Öz:
Disposable sensors based on a pencil graphite electrode were described for detection of alkyl phenols. The performances of the disposable bare pencil graphite electrode (PGE) and PGE modified with carbon nanotubes, regarding the cyclic and differential pulse voltammetric determination of 4-nonylphenol, 4-octylphenol, and 4-tert-octylphenol, were compared. Some experimental variables of the electrode surface pretreatment and measurement parameters were optimized. Using a phosphate buffer solution (pH 7.40) as the supporting electrolyte, alkyl phenols gave a well-defined oxidation peak at about 700 mV vs. Ag/AgCl. The detection limits established for each alkyl phenol were: 0.25 μM for 4-octylphenol, 0.42 μM for 4-nonylphenol, and 0.77 μM for 4-tert-octylphenol. This method is suitable for the direct determination of the total content of these pollutants found at micromolar levels in water samples. The results obtained applying this method are in good agreement with those obtained by high-performance liquid chromatography. The developed sensor has shown some advantages such as low cost, sensitivity, and capability to generate reproducible results using a simple and direct electrochemical protocol. By using this type of commonly available disposable working electrode and a portable electrochemical analysis system, the developed method can be applied to the determination of alkyl phenols directly at the sampling point.
Anahtar Kelime:

Konular: Mühendislik, Kimya
Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
  • 1. Frenzel, W.; Frenzel, J. O.; Moeler, J. Anal. Chim. Acta 1992, 261, 253–259.
  • 2. Yi, H.; Wu, K.; Hu, S.; Cui. D. Talanta 2001, 55, 1205–1210.
  • 3. Cruz Moraes, F.; Tanimoto, S. T.; Salazar-Banda, G. R.; Spinola Machado, S. A.; Mascaroa, L. H. Electroanal. 2009, 21, 1091–1098.
  • 4. European Directive 2003/53/EC.
  • 5. US EPA Priority Pollutant List on EPA Website (http://water.epa.gov/scitech/methods/cwa/pollutants.cfm). US Environmental Protection Agency (EPA), 2006
  • 6. ISO 18857-1, Water Quality - Determination of Selected Alkylphenols - Part 1, 2005.
  • 7. Zgola-Grze´skowiak, A.; Grze´skowiak, T.; Rydlichowski, R.; Lukaszewski, Z. Chemosphere 2009, 75, 513–518.
  • 8. Brugnera, M. F.; Gon¸calves Trindade, M. A.; Boldrin Zanoni, M. V. Anal. Lett. 2010, 43, 2823–2836.
  • 9. Ngundi, M. M.; Sadik, O. A.; Yamagushi, T.; Suye, S. I. Electrochem. Commun. 2003, 5, 61–67.
  • 10. Evtugyn, G. A.; Eremin, S.A.; Shaljamova, R. P.; Ismagilova, A.R.; Budnikov, H. C. Biosens. & Bioelectron. 2006, 22, 56–62.
  • 11. Vega, D.; Agui, L.; Gonzalez-Cortes, A.; Yanez-Sedeno, P.; Pingarron, J. M. Talanta 2007, 71, 1031–1038.
  • 12. Huang, J.; Zhang, X.; Liu, S.; Lin, Q.; He, X.; Xing, X.; Lian, W.; Tang, D. Sens. & Actuat. B: Chemical 2011, 152, 292–298.
  • 13. Yang, C. H. Microchim. Acta 2004, 148, 87–92.
  • 14. Huang, W.; Yang, C. H.; Zhang, S. Anal. Bioanal. Chem. 2003, 375, 703-707.
  • 15. Stuart, E. J. E.; Pumera, M. J. Phys. Chem. C 2011, 115, 5530–5534.
  • 16. Gurban, A. M.; Rotariu, L.; Baibarac, M.; Baltog, I.; Bala, C. Talanta, 2011, 85, 2007–2013.
  • 17. Yang, P.; Li, L.; Cai, H.; Song, H.; Wan, Q. Conference on Environmental Pollution and Public Health, 2010, 1–2, 908–911.
  • 18. Aoki, K.; Okamoto, T.; Kaneko, H.; Nozaki, K.; Negishi, A. J. Electroanal. Chem. 1989, 263, 323–333.
  • 19. Blum, D.; Leyffer, W.; Holze, R. Electroanal. 1996, 8, 296–297.
  • 20. Bond, A. M.; Mahon, P. J.; Schiewe, J.; Beckett, V. V. Anal. Chim. Acta 1997, 345, 67–74.
  • 21. Majidi, M. R.; Asadpour-Zeynali, K.; Hafezi, B. Electrochim. Acta 2009, 54, 1119–1126.
  • 22. Reza Majidi, M.; Asadpour-Zeynali, K.; Hafezi, B. Int. J. Electrochem. Sci. 2011, 6, 162–170
  • 23. Kakizaki, T.; Hasebe, K. Fresenius J. Anal. Chem. 1998, 360, 175–178.
  • 24. Demetriades, D.; Economou, A.; Voulgaropoulos, A. Anal. Chim. Acta 2004, 519, 167–172.
  • 25. Rashmi, B. B. P.; Tiwari,M. P.; Sharma, P. S. Sens. & Actuat. B: Chemical 2010, 146, 321–330.
  • 26. Gao, W.; Song, J.; Naiying, W. J. Electroanal. Chem. 2005, 576, 1–7.
  • 27. ¨Ozcan, L.; S¸ahin, Y. Sens. & Actuat. B: Chemical, 2007, 127, 362–369.
  • 28. Levent, A.; Yardim, Y.; Senturk, Z. Electrochim. Acta 2009, 55, 190–195.
  • 29. Aladag, N.; Trnkova, L.; Kourilova, A.; Ozsoz, M.; Jelen, F. Electroanal. 2010, 22, 1675–1681.
  • 30. Keskin, E.; Yardım, Y.; S¸ent¨urk, Z. Electroanal. 2010, 22, 1191–1199.
  • 31. ¨Ozcan, A.; S¸ahin, Y. Biosens. & Bioelectron. 2010, 25, 2497–2502.
  • 32. ¨Ozcan, A.; S¸ahin, Y. Electroanal. 2009, 21, 2363–2370.
  • 33. Buratti, S.; Scampicchio, M.; Giovanelli, G.; Mannino, S. Talanta 2008, 75 312–316.
  • 34. King, D.; Friend, J.; Kariuki, J. J. Chem. Educ. 2010, 87, 507–509.
  • 35. Wang, J.; Kawde, A.; Sahlin, E. Analyst 2000, 125, 5–7.
  • 36. Yardım, Y.; Keskin, E.; Levent, A.; ¨ Ozs¨oz, M.; Sent¨urk, Z. Talanta 2010, 80, 1347–1355.
  • 37. Ozkan-Ariksoysal, D.; Tezcanli, B.; Kosova, B.; Ozsoz, M. Anal. Chem. 2008, 80, 588–596.
  • 38. ISO 5667–10. Water quality—sampling—part 10. Guidance on sampling of waste waters. International Standards for Business, Government and Society, 1992.
  • 39. Cruceru, I.; Florescu, A.; Badea, I. A.; Vladescu, L. Environ. Monit. Assess. DOI 10.1007/s10661-011-2403-1.
  • 40. Allen, B. W.; Piantadosi, C. A. Nitric Oxide 2003, 8, 243–252.
  • 41. Iotov, P. I.; Kalcheva, S. V. J. Electroanal. Chem. 1998, 442, 19–26.
  • 42. Andreescu, S.; Andreescu, D.; Sadik, O. A. Electrochem. Commun. 2003, 5, 681–688.
  • 43. de Carvalho, R. M.; Kubota, L. T.; Rath, S. J. Electroanal. Chem. 2003, 548, 19–26.
  • 44. Ferreira, M.; Varela, H.; Torresi, R. M.; Tremiliosi-Filho, G. Electrochim. Acta 2006, 52, 434–442.
  • 45. Kuramitz, H.; Saitoh, J.; Hattori, T.; Tanaka, S. Water Res. 2002, 36, 3323–3329.
  • 46. Green, J. M. Analytical Chemistry News & Features 1996, 1, 305A–309A.
APA DAVID I, BADEA I, RADU G (2013). Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples. , 91 - 100.
Chicago DAVID Iulia Gabriela,BADEA Irinel Adriana,RADU Gabriel Lucian Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples. (2013): 91 - 100.
MLA DAVID Iulia Gabriela,BADEA Irinel Adriana,RADU Gabriel Lucian Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples. , 2013, ss.91 - 100.
AMA DAVID I,BADEA I,RADU G Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples. . 2013; 91 - 100.
Vancouver DAVID I,BADEA I,RADU G Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples. . 2013; 91 - 100.
IEEE DAVID I,BADEA I,RADU G "Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples." , ss.91 - 100, 2013.
ISNAD DAVID, Iulia Gabriela vd. "Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples". (2013), 91-100.
APA DAVID I, BADEA I, RADU G (2013). Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples. Turkish Journal of Chemistry, 37(1), 91 - 100.
Chicago DAVID Iulia Gabriela,BADEA Irinel Adriana,RADU Gabriel Lucian Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples. Turkish Journal of Chemistry 37, no.1 (2013): 91 - 100.
MLA DAVID Iulia Gabriela,BADEA Irinel Adriana,RADU Gabriel Lucian Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples. Turkish Journal of Chemistry, vol.37, no.1, 2013, ss.91 - 100.
AMA DAVID I,BADEA I,RADU G Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples. Turkish Journal of Chemistry. 2013; 37(1): 91 - 100.
Vancouver DAVID I,BADEA I,RADU G Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples. Turkish Journal of Chemistry. 2013; 37(1): 91 - 100.
IEEE DAVID I,BADEA I,RADU G "Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples." Turkish Journal of Chemistry, 37, ss.91 - 100, 2013.
ISNAD DAVID, Iulia Gabriela vd. "Disposable carbon electrodes as an alternative for the direct voltammetric determination of alkyl phenols from water samples". Turkish Journal of Chemistry 37/1 (2013), 91-100.
Sayfa Oluşturulma Tarihi
22-04-2024 18:59

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