Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage

ABAY, Bayram; TUNÇ, Nihat; RAKAP, MURAT

Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage

Murat RAKAP, (Denizcilik Fakültesi, Yüzüncü Yıl Üniversitesi, Van, Türkiye)

Bayram ABAY, (Yüzüncü Yıl Üniversitesi, Kimya Bölümü, Van, Türkiye)

Nihat TUNÇ (Yüzüncü Yıl Üniversitesi, Kimya Bölümü, Van, Türkiye)

Turkish Journal of Chemistry

2 0

Yıl: 2017 Cilt: 41 Sayı: 2 Sayfa Aralığı: 221 - 232 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage

Öz:

For the first time the synthesis of poly(N -vinyl-2-pyrrolidone)-stabilized cobalt-palladium nanoparticles by an easy method, their characterization, and their use as active catalysts for hydrogen release from hydrolysis of ammonia borane and hydrazine borane is reported here. The catalyst is prepared by simultaneous reduction of suitable cobalt and palladium ions by sodium borohydride in the presence of poly(N -vinyl-2-pyrrolidone) as a stabilizer. They are characterized by UV-Vis spectroscopy, TEM analysis, X-ray diffraction, and X-ray photoelectron spectroscopy. They provide average turnover frequencies of 30 min −1 and 45 min −1 in the hydrolysis of ammonia borane and hydrazine borane. They also provide activation energies of 48.6 ± 2 and 50.6 ± 2 kJ mol −1 in the hydrolysis of ammonia borane and hydrazine borane.

Anahtar Kelime:

Konular: Mühendislik, Kimya

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	RAKAP M, ABAY B, TUNÇ N (2017). Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage. , 221 - 232.
Chicago	RAKAP MURAT,ABAY Bayram,TUNÇ Nihat Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage. (2017): 221 - 232.
MLA	RAKAP MURAT,ABAY Bayram,TUNÇ Nihat Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage. , 2017, ss.221 - 232.
AMA	RAKAP M,ABAY B,TUNÇ N Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage. . 2017; 221 - 232.
Vancouver	RAKAP M,ABAY B,TUNÇ N Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage. . 2017; 221 - 232.
IEEE	RAKAP M,ABAY B,TUNÇ N "Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage." , ss.221 - 232, 2017.
ISNAD	RAKAP, MURAT vd. "Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage". (2017), 221-232.

APA	RAKAP M, ABAY B, TUNÇ N (2017). Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage. Turkish Journal of Chemistry, 41(2), 221 - 232.
Chicago	RAKAP MURAT,ABAY Bayram,TUNÇ Nihat Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage. Turkish Journal of Chemistry 41, no.2 (2017): 221 - 232.
MLA	RAKAP MURAT,ABAY Bayram,TUNÇ Nihat Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage. Turkish Journal of Chemistry, vol.41, no.2, 2017, ss.221 - 232.
AMA	RAKAP M,ABAY B,TUNÇ N Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage. Turkish Journal of Chemistry. 2017; 41(2): 221 - 232.
Vancouver	RAKAP M,ABAY B,TUNÇ N Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage. Turkish Journal of Chemistry. 2017; 41(2): 221 - 232.
IEEE	RAKAP M,ABAY B,TUNÇ N "Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage." Turkish Journal of Chemistry, 41, ss.221 - 232, 2017.
ISNAD	RAKAP, MURAT vd. "Hydrolysis of ammonia borane and hydrazine borane by poly(NN-vinyl-2-pyrrolidone)-stabilized CoPd nanoparticles for chemical hydrogen storage". Turkish Journal of Chemistry 41/2 (2017), 221-232.