Yıl: 2018 Cilt: 9 Sayı: 6 Sayfa Aralığı: 1146 - 1156 Metin Dili: İngilizce DOI: 10.1016/j.apr.2018.05.001 İndeks Tarihi: 27-12-2019

Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation

Öz:
In this research, seasonal and spatial distributions of inorganic and organic pollutants (sulphur dioxide (SO 2 ),nitrogen dioxide (NO 2 ) and ozone (O 3 ) and also volatile organic compounds (VOCs)), were determined bypassive sampling technique. Fifty sampling sites were selected considering possible sources in the study area.The sampling area were classified as urban (n = 23), industrial (n = 17) and rural (n = 10) regions. Samplingcampaigns were carried out for two-week periods in fall, winter, spring and summer seasons in all regions.Benzene and toluene concentrations were found to be the highest in winter at the traffic-dense sites and lowestconcentrations were measured at rural sampling sites in summer. Concentrations of NO 2 were higher at samplingsites with high traffic density in winter. A much uniform distribution was observed for SO 2 in all seasons.However higher levels were observed in winter compared to other seasons due to use of coal for domesticheating. Low O 3 concentrations were measured in winter while higher concentrations were measured insummer. Based on principal component analysis (PCA), four factors (gasoline vehicle emissions, diesel vehicleemissions, industrial emissions and fossil fuel combustion) were identified that could explain about 78% of thesystem variance of the measured pollutants in the city. Health risk assessment revealed that the safe level of1 × 10 −6 (United States Environmental Protection Agency's (USEPA) acceptable risk value) was exceeded forbenzene in all sampling sites in whole region, but non-carcinogenic risk values were at safe level.
Anahtar Kelime:

Konular: Çevre Mühendisliği
Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Bibliyografik
  • Artun, G.K., Polat, N., Yay, O.D., Üzmez, Ö.Ö., Ari, A., Tuygun, G.T., Elbir, T., Altuğ, H., Dumanoğlu, Y., Döğeroğlu, T., Dawood, A., Odabaşı, M., Gaga, E.O., 2017. An in- tegrative approach for determination of air pollution and its health effects in a coal fired power plant area by passive sampling. Atmos. Environ. 150, 331–345.
  • Baklanov, A., Molina, L.T., Gauss, M., 2016. Megacities, air quality and climate. Atmos. Environ. 126, 235–249.
  • Bozkurt, Z., Doğan, G., Arslanbaş, D., Pekey, B., Pekey, H., Dumanoğlu, Y., Bayram, A., Tuncel, G., 2015. Determination of the personal, indoor and outdoor exposure levels of inorganic gaseous pollutants in different microenvironments in an industrial city. Environ. Moni. Assess. 187, 590.
  • Can, E., Uzmez, O.O., Dogeroglu, T., Gaga, E.O., 2015. Indoor air quality assessment in painting and printmaking department of a fine arts faculty building. Atmos. Pollut. Res. 6, 1035–1045.
  • Caselli, M., Gennaro, G., Marzocca, A., Trizio, L., Tutino, M., 2010. Assessment of the impact of the vehicular traffic on BTEX concentration in ring roads in urban areas of Bari (Italy). Chemosphere 81, 306–311.
  • Chan, C.Y., Chan, L.Y., Wang, X.M., Liu, Y.M., Lee, S.C., Zou, S.C., Sheng, G.Y., Fu, J.F., 2002. Volatile organic compounds in roadside microenvironments of metropolitan Hong Kong. Atmos. Environ. 36, 2039–2047.
  • Civan, M.Y., Yurdakul, S., Tuncel, G., 2012. Improvement of uptake rate equations de- pending on meteorological conditions for 25 volatile organic compounds. Talanta 99, 720–729.
  • Civan, M., Elbir, T., Seyfioğlu, R., Kuntasal, Ö., Bayram, A., Doğan, G., Yurdakul, S., Andiç, Ö., Müezzioğlu, A., Sofuoğlu, S., Pekey, H., Pekey, B., Bozlaker, A., Odabaşı, M., Tuncel, G., 2015. Spatial and temporal variations in atmospheric VOCs, NO 2 , SO 2 , and O 3 concentrations at a heavily industrialized region in Western Turkey, and as- sessment of the carcinogenic risk levels of benzene. Atmos. Environ. 103, 102–113. Düzce Directorate of Environment and Urbanization (DDEU), 2016. Düzce Provincial Environmental Status Report for 2015, Düzce.
  • Demirel, G., Özden, Ö., Döğeroğlu, T., Gaga, E.O., 2014. Personal exposure of primary school children to BTEX, NO 2 and ozone in Eskişehir, Turkey: relationship with in- door/outdoor concentrations and risk assessment. Sci. Total. Environ. 473 (474), 537–548.
  • Derwent, R.G., 1995. Sources, distributions, and fates of VOCs in the atmosphere. Environ. Sci. Tech. 4, 1–15.
  • Elbir, T., Cetin, B., Cetin, E., Bayram, A., Odabasi, M., 2007. Characterization of volatile organic compounds (VOCs) and their sources in the air of Izmir, Turkey. Environ. Monit. Assess. 133, 149–160.
  • Gaga, E.O., Döğeroğlu, T., Özden, Ö., Ari, A., Yay, O.D., Altuğ, H., Akyol, N., Örnektekin, S., Van Doorn, W., 2012. Evaluation of air quality by passive and active sampling in an urban city in Turkey: current status and spatial analysis of air pollution exposure. Environ. Sci. Pol. Res. 19, 3579–3596.
  • Gonzalez, C.M., Gomez, C.D., Rojas, N.Y., Acevedo, H., Aristizabal, B.H., 2017. Relative impact of on-road vehicular and point-source industrial emissions of air pollutants in a medium-sized Andean city. Atmos. Environ. 152, 279–289.
  • Gorecki, T., Namiesnik, J., 2002. Passive sampling. Trends Analy. Chem. 21 (4), 276–291.
  • Gül, H., Gaga, E.O., Döğeroğlu, T., Özden, Ö., Ayvaz, Ö., Özel, S., Güngör, G., 2011. Respiratory health symptoms among students exposed to different levels of air pol- lution in a Turkish City. Int. J. Environ. Res. Pub. Heal 8, 1110–1125.
  • Gulia, S., Nagendra, S.M.S., Khare, Mukesh, Khanna, I., 2015. Urban air quality management–A review. Atmos. Pollut. Res. 6, 286–304.
  • Guo, H., Wang, T., Louie, P.K.K., 2004. Source apportionment of ambient non–methane hydrocarbons in Hong Kong: application of a principal component analysis/absolute principal component scores (PCA/APCS) receptor model. Environ. Pol. 129, 489–498.
  • Guo, H., Cheng, H.R., Ling, Z.H., Louie, P.K.K., Ayoko, G.A., 2011. Which emission sources are responsible for the volatile organic compounds in the atmosphere of Pearl River Delta? J. Hazar. Mat. 188, 116–124.
  • Heiden, A.C., Hoffmann, T., Kahl, J., Kley, D., Klockow, D., Langebartels, C., Mehlborn, H., Sandermann, H., Schraudner, M., Schuh, G., Wildt, J., 1999. Emission of volatile organic compounds from ozone-exposed plants. Ecol. Appl. 9 (4), 1160–1167.
  • http-1: USEPA-IRIS (Integrated Risk Information System), 2015. https://cfpub.epa.gov/ ncea/iris2/atoz.cfm.
  • http-2: USEPA-RAIS (The Risk Assessment Information System), 2018. https://rais.ornl. gov/tools/metadata.php.
  • http-3: National Air Quality Assessment and Management Regulation. 2016. Official JournalNumber:26898.http://www.mevzuat.gov.tr/Metin.Aspx?MevzuatKod=7.5. 12188&MevzuatIliski=0&sourceXmlSearch=hava%20kalitesi.
  • http-4: The European Parliament and of The Council, Air Quality Standards. 2017. http:// ec.europa.eu/environment/air/quality/standards.htm.
  • http-5: USEPA SPECIATE data-base, version 4.5. 2016. https://www.epa.gov/air- emissions-modeling/speciate-version-45-through-40.
  • Hung-Lung, C., Jiun-Horng, T., Shih-Yu, C., Kuo-Hsiung, L., Sen-Yi, M., 2007. VOC con- centration profiles in an ozone non-attainment area: a case study in an urban and industrial complex metroplex in southern Taiwan. Atmos. Environ. 41 (9), 1848–1860.
  • Kjellstrom, T., Friel, S., Dixon, J., Corvalan, C., Rehfuess, E., Campbell-Lendrum, D., Gore, F., Bartram, J., 2007. Urban environmental health hazards and health equity. J. Urban Health 84 (S1), 86–97.
  • Kumar, A., Singh, D., Kumar, K., Singh, B.B., Jain, V.K., 2018. Distribution of VOCs in urban and rural atmospheres of subtropical India: temporal variation, source attri- bution, ratios, OFP and risk assessment. Sci. Total. Environ. 613–614, 492–501.
  • Lagrega, M.D., Buckingham, P.L., Evans, J.C., 1994. Hazar. Waste Manag. 837–885 McGraw Hill, New York, USA.
  • Lewne, M., Cyrys, J., Meliefste, K., Hoek, G., Brauer, M., Fischer, P., Gehring, U., Heinrich, J., Brunekreef, B., Bellander, T., 2004. Spatial variation in nitrogen dioxide in three European areas. Sci. Total. Environ. 332, 217–230.
  • Li, L., Li, H., Zhang, X., Wang, L., Xu, L., Wang, X., Yu, Y., Zhang, Y., Cao, G., 2014. Pollution characteristics and health risk assessment of benzene homologues in am- bient air in the northeastern urban area of Beijing, China. J. Environ. Sci. 26, 214–223.
  • Liu, P.W.G., Yao, Y.C., Tsai, J.H., Hsu, Y.C., Chang, L.P., Chang, K.H., 2008a. Source impacts by volatile organic compounds in an industrial city of southern Taiwan. Sci. Total. Environ. 398 (1–3), 154–163.
  • Liu, Y., Shao, M., Fu, L., Lu, S., Zeng, L., Tang, D., 2008b. Source profiles of volatile organic compounds (VOCs) measured in China: Part I. Atmos. Environ. 42–25, 6247–6260.
  • McCarthy, M.C., Aklilu, Y.A., Brown, S.G., Lyder, D.A., 2013. Source apportionment of volatile organic compounds measured in Edmonton, Alberta. Atmos. Environ. 81, 504–516.
  • Miller, L., Xu, X., Grgicak-Mannion, A., Brook, J., Wheeler, A., 2012. Multi-season, multi- year concentrations and correlations amongst the BTEX group of VOCs in an urba- nized industrial city. Atmos. Environ. 61, 305–315.
  • Moore, M., Gould, P., Keary, B.S., 2003. Global urbanization and impact on health. Int. J. Hyg. Environ. Health 206 (4–5), 269–278.
  • Mukhopadhyay, K., Forssell, O., 2005. An empirical investigation of air pollution from fossil fuel combustion and its impact on health in India during 1973–1974 to 1996–1997. Ecol. Econ. 55, 235–250.
  • Özden, Ö., 2005. Monitoring of Air Quality by Use of Passive Samplers. Master of Science Thesis. Anadolu University, Graduate School of Natural and Applied Sciences, Environmental Engineering Program, Eskişehir, Turkey.
  • Özden, Ö., Döğeroğlu, T., 2012. Performance evaluation of a tailor-made passive sampler for monitoring of troposheric ozone. Environ. Sci. Pol. Res. 19, 3200–3209.
  • Pekey, B., Özaslan, Ü., 2013. Spatial distribution of SO 2 , NO 2 , and O 3 concentrations in an industrial city of Turkey using a passive sampling method. Clean. – S., A., W. 41, 423–428.
  • Pekey, B., Yılmaz, H., 2011. The use of passive sampling to monitor spatial trends of volatile organic compounds (VOCs) at an industrial city of Turkey. Microchem. J. 97, 213–219.
  • Penuelas, J., Llusià, J., Gimeno, B., 1999. Effects of ozone concentrations on biogenic volatile organic compounds emission in the Mediterranean region. Environ. Pol. 105 (1), 17–23.
  • Pinault, L., Crouse, D., Jerrett, M., Brauer, M., Tjepkema, M., 2016. Spatial associations between socioeconomic groups and NO air pollution exposure within three large Canadian cities. Environ. Res. 147, 373–382.
  • Rolph, G., Stein, A., Stunder, B., 2017. Real-time environmental applications and display sYstem: ready. Environ. Mod. Soft. 95, 210–228.
  • Romanazzi, V., Casazza, M., Malandrino, M., Maurino, V., Piano, A., Schilirò, T., Gilli, G., 2014. PM10 size distribution of metals and environmental-sanitary risk analysis in the city of Torino. Chemosphere 112, 210–216.
  • Shrivastava, A., Gupta, V.B., 2011. Methods for the determination of limit of detection and limit of quantitation of the analytical methods. Chron. Young Sci. 2 (1), 21–25.
  • Song, Y., Dai, W., Shao, M., Liu, Y., Lu, S., Kuster, W., Goldan, P., 2008. Comparison of receptor models for source apportionment of volatile organic compounds in Beijing, China. Environ. Pol. 156, 174–183.
  • Sonibare, J.A., Akeredolu, F.A., 2004. Theoretical prediction of non-methane gaseous emissions from natural gas combustion. Energy Policy 32, 1653–1665.
  • Stein, A.F., Draxler, R.R., Rolph, G.D., Stunder, B.J.B., Cohen, M.D., Ngan, F., 2015. NOAA's HYSPLIT atmospheric transport and dispersion modeling system. Bull. Amer. Meteor.Soc. 96, 2059–2077.
  • Turkish Statistical Institute (TUİK), 2017. The Results of Address Based Population Registration System.
  • USEPA, 2011. Exposure Factors Handbook 2011 Edition (Final). U.S. Environmental Protection Agency, Washington, DC EPA/600/R-09/052F.
  • USEPA, 2013. Regional Screening Level (RSL) Summary Table (TR = 1E_6, HQ = 1). November 2013, < http://www.epa.gov/region9/superfund/prg/ > .
  • Wu, F., Yu, Y., Sun, J., Zhang, J., Wang, J., Tang, G., Wang, Y., 2016. Characteristics, source apportionment and reactivity of ambient volatile organic compounds at Dinghu Mountain in Guangdong Province, China. Sci. Total Environ. 548 (549), 347–359.
  • Yuan, B., Shao, M., Lu, S., Wang, B., 2010. Source profiles of volatile organic compounds associated with solvent use in Beijing, China. Atmos. Environ. 44, 1919–1926.
  • Yurdakul, S., Civan, M., Tuncel, G., 2013. Volatile organic compounds in suburban Ankara atmosphere, Turkey: sources and variability. Atmos. Res. 120, 121, 298–311.
  • Zhang, L., Lee, C.S., Zhang, R., Chen, L., 2017. Spatial and temporal evaluation of long term trend (2005–2014) of OMI retrieved NO 2 and SO 2 concentrations in Henan Province, China. Atmos. Environ. 154, 151–166.
APA BOZKURT Z, ÖZDEN ÜZMEZ Ö, DÖĞEROĞLU T, ARTUN G, GAGA E (2018). Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation. , 1146 - 1156. 10.1016/j.apr.2018.05.001
Chicago BOZKURT Zehra,ÖZDEN ÜZMEZ ÖZLEM,DÖĞEROĞLU TUNCAY,ARTUN Gülzade,GAGA Eftade O Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation. (2018): 1146 - 1156. 10.1016/j.apr.2018.05.001
MLA BOZKURT Zehra,ÖZDEN ÜZMEZ ÖZLEM,DÖĞEROĞLU TUNCAY,ARTUN Gülzade,GAGA Eftade O Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation. , 2018, ss.1146 - 1156. 10.1016/j.apr.2018.05.001
AMA BOZKURT Z,ÖZDEN ÜZMEZ Ö,DÖĞEROĞLU T,ARTUN G,GAGA E Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation. . 2018; 1146 - 1156. 10.1016/j.apr.2018.05.001
Vancouver BOZKURT Z,ÖZDEN ÜZMEZ Ö,DÖĞEROĞLU T,ARTUN G,GAGA E Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation. . 2018; 1146 - 1156. 10.1016/j.apr.2018.05.001
IEEE BOZKURT Z,ÖZDEN ÜZMEZ Ö,DÖĞEROĞLU T,ARTUN G,GAGA E "Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation." , ss.1146 - 1156, 2018. 10.1016/j.apr.2018.05.001
ISNAD BOZKURT, Zehra vd. "Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation". (2018), 1146-1156. https://doi.org/10.1016/j.apr.2018.05.001
APA BOZKURT Z, ÖZDEN ÜZMEZ Ö, DÖĞEROĞLU T, ARTUN G, GAGA E (2018). Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation. Atmospheric Pollution Research, 9(6), 1146 - 1156. 10.1016/j.apr.2018.05.001
Chicago BOZKURT Zehra,ÖZDEN ÜZMEZ ÖZLEM,DÖĞEROĞLU TUNCAY,ARTUN Gülzade,GAGA Eftade O Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation. Atmospheric Pollution Research 9, no.6 (2018): 1146 - 1156. 10.1016/j.apr.2018.05.001
MLA BOZKURT Zehra,ÖZDEN ÜZMEZ ÖZLEM,DÖĞEROĞLU TUNCAY,ARTUN Gülzade,GAGA Eftade O Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation. Atmospheric Pollution Research, vol.9, no.6, 2018, ss.1146 - 1156. 10.1016/j.apr.2018.05.001
AMA BOZKURT Z,ÖZDEN ÜZMEZ Ö,DÖĞEROĞLU T,ARTUN G,GAGA E Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation. Atmospheric Pollution Research. 2018; 9(6): 1146 - 1156. 10.1016/j.apr.2018.05.001
Vancouver BOZKURT Z,ÖZDEN ÜZMEZ Ö,DÖĞEROĞLU T,ARTUN G,GAGA E Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation. Atmospheric Pollution Research. 2018; 9(6): 1146 - 1156. 10.1016/j.apr.2018.05.001
IEEE BOZKURT Z,ÖZDEN ÜZMEZ Ö,DÖĞEROĞLU T,ARTUN G,GAGA E "Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation." Atmospheric Pollution Research, 9, ss.1146 - 1156, 2018. 10.1016/j.apr.2018.05.001
ISNAD BOZKURT, Zehra vd. "Atmospheric concentrations of SO 2 , NO 2 , ozone and VOCs in Düzce, Turkey using passive air samplers: Sources, spatial and seasonal variations and health risk estimation". Atmospheric Pollution Research 9/6 (2018), 1146-1156. https://doi.org/10.1016/j.apr.2018.05.001