Enzyme-Catalyzed Trans-Benzoin Condensation
Yıl: 2018 Cilt: 5 Sayı: 2 Sayfa Aralığı: 737 - 750 Metin Dili: İngilizce DOI: 10.18596/jotcsa.414603 İndeks Tarihi: 22-02-2020
Enzyme-Catalyzed Trans-Benzoin Condensation
Öz: Benzaldehyde lyase (BAL) is an enzyme that is used in the C-C bond cleavage andformation which was isolated first from Pseudomonas fluorescens Biovar I. It requires thiaminediphosphate (ThDP) and Mg(II) ions as cofactors. In this work, BAL was used as an enzymaticcatalyst for the trans-benzoin condensation reaction between racemic benzoins andbenzyloxyacetaldehyde to form unsymmetrical benzoin products with moderate enantiomericexcesses. (S)-benzoin derivatives remained unreacted at the end of the reaction. In thisenzymatic trans-benzoin condensation, benzyloxyacetaldehyde acted as acceptor and differentvariety of racemic benzoin derivatives were used as donor and (R)-2-hydroxy-1-phenylpropanone derivatives were synthesized up to 66% ee.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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| APA | BİLİR G, DEMİR A, Ozcubukcu S (2018). Enzyme-Catalyzed Trans-Benzoin Condensation. , 737 - 750. 10.18596/jotcsa.414603 |
| Chicago | BİLİR Gökçil,DEMİR Ayhan S.,Ozcubukcu Salih Enzyme-Catalyzed Trans-Benzoin Condensation. (2018): 737 - 750. 10.18596/jotcsa.414603 |
| MLA | BİLİR Gökçil,DEMİR Ayhan S.,Ozcubukcu Salih Enzyme-Catalyzed Trans-Benzoin Condensation. , 2018, ss.737 - 750. 10.18596/jotcsa.414603 |
| AMA | BİLİR G,DEMİR A,Ozcubukcu S Enzyme-Catalyzed Trans-Benzoin Condensation. . 2018; 737 - 750. 10.18596/jotcsa.414603 |
| Vancouver | BİLİR G,DEMİR A,Ozcubukcu S Enzyme-Catalyzed Trans-Benzoin Condensation. . 2018; 737 - 750. 10.18596/jotcsa.414603 |
| IEEE | BİLİR G,DEMİR A,Ozcubukcu S "Enzyme-Catalyzed Trans-Benzoin Condensation." , ss.737 - 750, 2018. 10.18596/jotcsa.414603 |
| ISNAD | BİLİR, Gökçil vd. "Enzyme-Catalyzed Trans-Benzoin Condensation". (2018), 737-750. https://doi.org/10.18596/jotcsa.414603 |
| APA | BİLİR G, DEMİR A, Ozcubukcu S (2018). Enzyme-Catalyzed Trans-Benzoin Condensation. Journal of the Turkish Chemical Society, Section A: Chemistry, 5(2), 737 - 750. 10.18596/jotcsa.414603 |
| Chicago | BİLİR Gökçil,DEMİR Ayhan S.,Ozcubukcu Salih Enzyme-Catalyzed Trans-Benzoin Condensation. Journal of the Turkish Chemical Society, Section A: Chemistry 5, no.2 (2018): 737 - 750. 10.18596/jotcsa.414603 |
| MLA | BİLİR Gökçil,DEMİR Ayhan S.,Ozcubukcu Salih Enzyme-Catalyzed Trans-Benzoin Condensation. Journal of the Turkish Chemical Society, Section A: Chemistry, vol.5, no.2, 2018, ss.737 - 750. 10.18596/jotcsa.414603 |
| AMA | BİLİR G,DEMİR A,Ozcubukcu S Enzyme-Catalyzed Trans-Benzoin Condensation. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(2): 737 - 750. 10.18596/jotcsa.414603 |
| Vancouver | BİLİR G,DEMİR A,Ozcubukcu S Enzyme-Catalyzed Trans-Benzoin Condensation. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(2): 737 - 750. 10.18596/jotcsa.414603 |
| IEEE | BİLİR G,DEMİR A,Ozcubukcu S "Enzyme-Catalyzed Trans-Benzoin Condensation." Journal of the Turkish Chemical Society, Section A: Chemistry, 5, ss.737 - 750, 2018. 10.18596/jotcsa.414603 |
| ISNAD | BİLİR, Gökçil vd. "Enzyme-Catalyzed Trans-Benzoin Condensation". Journal of the Turkish Chemical Society, Section A: Chemistry 5/2 (2018), 737-750. https://doi.org/10.18596/jotcsa.414603 |
