Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes
Yıl: 2018 Cilt: 5 Sayı: 2 Sayfa Aralığı: 785 - 800 Metin Dili: İngilizce DOI: 10.18596/jotcsa.324878 İndeks Tarihi: 22-02-2020
Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes
Öz: This article describes the synthesis of isonitrosomethyl-p-tolyl ketone [HL] as the startingcompound and then we prepared the new oxime ligand from the reactions of the amine materialswith 1,2-diaminobenzene [H2L1]. (1E, 2E, 1'E, 2'E) - 3,3'-bis [(4-tolyl ketone) - (1,2 phenylenediimine)]. Acetaldehyde dioxime ligand was used to synthesize the metal complexes. The complexeswere elucidated by FT-IR, elemental analysis, magnetic moment measurements, molar conductivity,mass spectra, and TGA studies. The free ligand was also described with its 13C and 1H-NMR spectra.For complexes using spectroscopic and stoichiometric data of the complexes showed thatmetal:ligand ratio of mononuclear copper(II) complex was found to be 1:1 while this ratio was 2:1in homo- and heterodinuclear copper(II) complex and 3:2 in the trinuclear copper(II) complex. Allthese data show us that the proposed structure is consistent with the obtained data.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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| APA | TOPAL T, KARAPINAR E (2018). Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes. , 785 - 800. 10.18596/jotcsa.324878 |
| Chicago | TOPAL T.,KARAPINAR E. Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes. (2018): 785 - 800. 10.18596/jotcsa.324878 |
| MLA | TOPAL T.,KARAPINAR E. Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes. , 2018, ss.785 - 800. 10.18596/jotcsa.324878 |
| AMA | TOPAL T,KARAPINAR E Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes. . 2018; 785 - 800. 10.18596/jotcsa.324878 |
| Vancouver | TOPAL T,KARAPINAR E Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes. . 2018; 785 - 800. 10.18596/jotcsa.324878 |
| IEEE | TOPAL T,KARAPINAR E "Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes." , ss.785 - 800, 2018. 10.18596/jotcsa.324878 |
| ISNAD | TOPAL, T. - KARAPINAR, E.. "Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes". (2018), 785-800. https://doi.org/10.18596/jotcsa.324878 |
| APA | TOPAL T, KARAPINAR E (2018). Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes. Journal of the Turkish Chemical Society, Section A: Chemistry, 5(2), 785 - 800. 10.18596/jotcsa.324878 |
| Chicago | TOPAL T.,KARAPINAR E. Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes. Journal of the Turkish Chemical Society, Section A: Chemistry 5, no.2 (2018): 785 - 800. 10.18596/jotcsa.324878 |
| MLA | TOPAL T.,KARAPINAR E. Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes. Journal of the Turkish Chemical Society, Section A: Chemistry, vol.5, no.2, 2018, ss.785 - 800. 10.18596/jotcsa.324878 |
| AMA | TOPAL T,KARAPINAR E Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(2): 785 - 800. 10.18596/jotcsa.324878 |
| Vancouver | TOPAL T,KARAPINAR E Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018; 5(2): 785 - 800. 10.18596/jotcsa.324878 |
| IEEE | TOPAL T,KARAPINAR E "Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes." Journal of the Turkish Chemical Society, Section A: Chemistry, 5, ss.785 - 800, 2018. 10.18596/jotcsa.324878 |
| ISNAD | TOPAL, T. - KARAPINAR, E.. "Synthesis and characterization of new homo and heteronuclear Schiff base copper(II) complexes". Journal of the Turkish Chemical Society, Section A: Chemistry 5/2 (2018), 785-800. https://doi.org/10.18596/jotcsa.324878 |
