Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells

Sinan Kutluay, (Siirt Üniversitesi, Kimya Mühendisliği Bölümü, Siirt, Türkiye)
Orhan Baytar, (Siirt Üniversitesi, Kimya Mühendisliği Bölümü, Siirt, Türkiye)
Ömer Şahin (Siirt Üniversitesi, Kimya Mühendisliği Bölümü, Siirt, Türkiye)
Research on Engineering Structures and Materials
1 0
Yıl: 2019 Cilt: 5 Sayı: 3 Sayfa Aralığı: 279 - 298 Metin Dili: İngilizce DOI: 10.17515/resm2019.73en1122 İndeks Tarihi: 30-06-2020

Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells

Öz:
Toluene is the primary material in chemical process industries and is often usedas a raw material in the production of many chemicals and as a solvent in manyengineering processes. In this study, the material of char, which is used as anadsorbent, was produced from almond shells. The adsorption process of gasphase toluene onto char was investigated using a laboratory-scale fixed-bedreactor under atmospheric pressure. The structure of the char was characterizedby BET and FTIR. The influences of adsorption parameters such as nitrogen (N2)flow rate as the gas-phase toluene carrier, char amount, gas-phase tolueneconcentration at the inlet and the adsorption temperature on both theadsorption capacity and adsorption efficiency were examined. It was found thatthe adsorption of the gas-phase toluene onto char could be well represented bythe pseudo-second-order kinetic model. Equilibrium isotherm data wereanalyzed by the Langmuir and Freundlich isotherm models and the resultsindicated that the adsorption process was described well by the Langmuirisotherm model. The maximum monolayer adsorption capacity (qmax) of the charwas determined as 15.42 mg g-1 for 303 K. Thermodynamic parameters such asΔG° = -7.93 kJ mol-1, ΔH°= -17.18 kJ mol-1, ΔS°= -0.013 kJ mol-1 K-1 showed that theadsorption process was spontaneous, exothermic and physical. The resultsshowed that the material of char produced from almond shells could be used asa biosorbent to remove the material of gas-phase toluene from various industrialand natural sources through the adsorption method.
Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
  • [1] Koppmann R. Volatile Organic Compounds in the Atmopshere. UK.: Blackwell Publishing Ltd.; 2007. https://doi.org/10.1002/9780470988657
  • [2] Ghoshal AK, Manjare SD. Selection of appropriate adsorption technique for recovery of VOCs: an analysis. Journal of Loss Prevention in the Process Industries. 2002;15(6):413-421. https://doi.org/10.1016/S0950-4230(02)00042-6
  • [3] Khan FI, Kr. Ghoshal A. Removal of Volatile Organic Compounds from polluted air. Journal of Loss Prevention in the Process Industries. 2000;13(6):527-545. https://doi.org/10.1016/S0950-4230(00)00007-3
  • [4] Pires J, Carvalho A, de Carvalho MB. Adsorption of volatile organic compounds in Y zeolites and pillared clays. Microporous and Mesoporous Materials. 2001;43(3):277- 287. https://doi.org/10.1016/S1387-1811(01)00207-4
  • [5] Srivastava NC, Eames IW. A review of adsorbents and adsorbates in solid–vapour adsorption heat pump systems. Applied Thermal Engineering. 1998;18(9):707-714. https://doi.org/10.1016/S1359-4311(97)00106-3
  • [6] Tsai W-T. A review of environmental hazards and adsorption recovery of cleaning solvent hydrochlorofluorocarbons (HCFCs). Journal of Loss Prevention in the Process Industries. 2002;15(2):147-157. https://doi.org/10.1016/S0950-4230(01)00023-7
  • [7] Hindarso H, Ismadji S, Wicaksana F, Mudjijati, Indraswati N. Adsorption of Benzene and Toluene from Aqueous Solution onto Granular Activated Carbon. Journal of Chemical & Engineering Data. 2001;46(4):788-791. https://doi.org/10.1021/je000176g
  • [8] Jones AP. Indoor air quality and health. Atmospheric Environment. 1999;33(28):4535- 4564. https://doi.org/10.1016/S1352-2310(99)00272-1
  • [9] Gupta VK, Verma N. Removal of volatile organic compounds by cryogenic condensation followed by adsorption. Chemical Engineering Science. 2002;57(14):2679-2696. https://doi.org/10.1016/S0009-2509(02)00158-6
  • [10] Hwang KS, Dae Ki C, Sung Yong G, Sung Yong C. Adsorption and thermal regeneration of methylene chloride vapor on an activated carbon bed. Chemical Engineering Science. 1997;52(7):1111-1123. https://doi.org/10.1016/S0009-2509(96)00470-8
  • [11] Naidu G, Jeong S, Johir MAH, Fane AG, Kandasamy J, Vigneswaran S. Rubidium extraction from seawater brine by an integrated membrane distillation-selective sorption system. Water Research. 2017;123:321-331. https://doi.org/10.1016/j.watres.2017.06.078
  • [12] Shahmirzadi MAA, Hosseini SS, Tan NR. Enhancing removal and recovery of magnesium from aqueous solutions by using modified zeolite and bentonite and process optimization. Korean Journal of Chemical Engineering. 2016;33(12):3529- 3540. https://doi.org/10.1007/s11814-016-0218-z
  • [13] Lillo-Ródenas MA, Cazorla-Amorós D, Linares-Solano A. Behaviour of activated carbons with different pore size distributions and surface oxygen groups for benzene and toluene adsorption at low concentrations. Carbon. 2005;43(8):1758-1767. https://doi.org/10.1016/j.carbon.2005.02.023
  • [14] Roop Chand Bansal, Goyal M. Activated Carbon Adsorption. 1 st ed. Boca Raton: Taylor & Francis Group; 2005. 263-265 p.
  • [15] Parra MA, Elustondo D, Bermejo R, Santamaría JM. Quantification of indoor and outdoor volatile organic compounds (VOCs) in pubs and cafés in Pamplona, Spain. Atmospheric Environment. 2008;42(27):6647-6654. https://doi.org/10.1016/j.atmosenv.2008.04.026
  • [16] Ruthven DM. Principles of Adsorption and Adsorption Processes. New York: John Wiley; 1984.
  • [17] Allen RWK, D Archer E, MacInnes J. Adsorption by Particles Injected into a Gas Stream. Chemical Engineering Journal - CHEM ENG J. 2001;83:165-174. https://doi.org/10.1016/S1385-8947(00)00264-3
  • [18] Allen RWK, Archer ED, MacInnes JM. Theoretical account of a dry sorption injection experiment. AIChE. 2001;47(12):2684-2695. https://doi.org/10.1002/aic.690471208
  • [19] Archer ED, Allen RWK, MacInnes JM. Measurements of VOC take-up by adsorbing particles in a gas stream. Filtration & Separation. 2000;37(10):32-39. https://doi.org/10.1016/S0015-1882(00)80250-5
  • [20] Balathanigaimani MS, Shim W-G, Lee M-J, Lee J-W, Moon H. Adsorption Isotherms of Benzene and Toluene on Corn Grain-Based Carbon Monolith at (303.15, 313.15, and 323.15) K. Journal of Chemical & Engineering Data. 2008;53(3):732-736. https://doi.org/10.1021/je700575g
  • [21] Kutluay S, Baytar O, Şahin Ö. Equilibrium, kinetic and thermodynamic studies for dynamic adsorption of benzene in gas phase onto activated carbon produced from elaeagnus angustifolia seeds. Journal of Environmental Chemical Engineering. 2019;7(2):102947. https://doi.org/10.1016/j.jece.2019.102947
  • [22] Hassan AF, Abdel-Mohsen AM, Fouda MMG. Comparative study of calcium alginate, activated carbon, and their composite beads on methylene blue adsorption. Carbohydrate Polymers. 2014; 102:192-198. https://doi.org/10.1016/j.carbpol.2013.10.104
  • [23] Noorimotlagh Z, Darvishi Cheshmeh Soltani R, Khataee AR, Shahriyar S, Nourmoradi H. Adsorption of a textile dye in aqueous phase using mesoporous activated carbon prepared from Iranian milk vetch. Journal of the Taiwan Institute of Chemical Engineers. 2014;45(4):1783-1791. https://doi.org/10.1016/j.jtice.2014.02.017
  • [24] Bazrafshan E., Faridi H., M.F. K, A.H. M. Arsenic removal from aqueous environments using moringa peregrina seed extract as a natural coagulant. Asian Journal of Chemistry. 2013;25:3557-3561. https://doi.org/10.14233/ajchem.2013.13647
  • [25] de Luna MDG, Flores ED, Genuino DAD, Futalan CM, Wan M-W. Adsorption of Eriochrome Black T (EBT) dye using activated carbon prepared from waste rice hulls— Optimization, isotherm and kinetic studies. Journal of the Taiwan Institute of Chemical Engineers. 2013;44(4):646-653. https://doi.org/10.1016/j.jtice.2013.01.010
  • [26] Hameed BH, El-Khaiary MI. Equilibrium, kinetics and mechanism of malachite green adsorption on activated carbon prepared from bamboo by K2CO3 activation and subsequent gasification with CO2. Journal of Hazardous Materials. 2008;157(2):344- 351. https://doi.org/10.1016/j.jhazmat.2007.12.105
  • [27] Ramirez D, Qi S, Rood MJ, Hay KJ. Equilibrium and Heat of Adsorption for Organic Vapors and Activated Carbons. Environmental Science & Technology. 2005;39(15):5864-5871. https://doi.org/10.1021/es048144r
  • [28] M. M. Vargas A, L. Cazetta A, Kunita M, L. Silva T, Almeida V. Adsorption of methylene blue on activated carbon produced from flamboyant pods ( Delonix regia): Study of adsorption isotherms and kinetic models. Chemical Engineering Journal. 2011;168(2):722-730. https://doi.org/10.1016/j.cej.2011.01.067
  • [29] Ammendola P, Raganati F, Chirone R. CO2 adsorption on a fine activated carbon in a sound assisted fluidized bed: Thermodynamics and kinetics. Chemical Engineering Journal. 2017;322:302-313. https://doi.org/10.1016/j.cej.2017.04.037
  • [30] Gürses A, Doğar Ç, Yalçın M, Açıkyıldız M, Bayrak R, Karaca S. The adsorption kinetics of the cationic dye, methylene blue, onto clay. Journal of Hazardous Materials. 2006;131(1):217-228. https://doi.org/10.1016/j.jhazmat.2005.09.03
  • [31] Sari A, Tuzen M, Citak D, Soylak M. Equilibrium, kinetic and thermodynamic studies of adsorption of Pb(II) from aqueous solution onto Turkish kaolinite clay. Journal of Hazardous Materials. 2007; 149(2):283-291. https://doi.org/10.1016/j.jhazmat.2007.03.078
  • [32] Dursun AY, Kalayci ÇS. Equilibrium, kinetic and thermodynamic studies on the adsorption of phenol onto chitin. Journal of Hazardous Materials. 2005;123(1):151- 157. https://doi.org/10.1016/j.jhazmat.2005.03.034
  • [33] Magdy YH, Daifullah AAM. Adsorption of a basic dye from aqueous solutions onto sugar-industry-mud in two modes of operations. Waste Management. 1998;18(4):219- 226. https://doi.org/10.1016/S0956-053X(98)00022-1
  • [34] El-Bindary AA, Hussien MA, Diab MA, Eessa AM. Adsorption of Acid Yellow 99 by polyacrylonitrile/activated carbon composite: Kinetics, thermodynamics and isotherm studies. Journal of Molecular Liquids. 2014;197:236-242. https://doi.org/10.1016/j.molliq.2014.05.003
  • [35] Langmuir I. The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 1918;40:1361–1368. https://doi.org/10.1021/ja02242a004
  • [36] Freundlich HMF. Over the Adsorption in Solution. The Journal of Physical Chemistry. 1906;57:385-471.
  • [37] Guo Y, Li Y, Zhu T, Wang J, Ye M. Modeling of dioxin adsorption on activated carbon. Chemical Engineering Journal. 2016;283:1210-1215. https://doi.org/10.1016/j.cej.2015.08.067
  • [38] A.O D, Olalekan A, Olatunya A, Dada AO. Langmuir, Freundlich, Temkin and Dubinin– Radushkevich Isotherms Studies of Equilibrium Sorption of Zn 2+ Unto Phosphoric Acid Modified Rice Husk. IOSR Journal of Applied Chemistry (IOSR-JAC). 2012;3:38-45. https://doi.org/10.9790/5736-0313845
  • [39] A.A. Adelodun, J.C. Ngila, D.-G. Kim, Jo YM. Isotherm, Thermodynamic and Kinetic Studies of Selective CO2 Adsorption on Chemically Modified Carbon Surfaces. Aerosol and Air Quality Research. 2016:3312–3329.
  • [40] Hauchhum L, Mahanta P. Carbon dioxide adsorption on zeolites and activated carbon by pressure swing adsorption in a fixed bed. International Journal of Energy and Environmental Engineering. 2014;5(4):349-356. https://doi.org/10.1007/s40095- 014-0131-3
  • [41] Singh VK, Anil Kumar E. Measurement and analysis of adsorption isotherms of CO2 on activated carbon. Applied Thermal Engineering. 2016;97:77-86. https://doi.org/10.1016/j.applthermaleng.2015.10.052
  • [42] He J, Hong S, Zhang L, Gan F, Ho Y-S. Equilibrium and Thermodynamic Parameters of Adsorption of Methylene Blue onto Rectorite. Fresenius Environmental Bulletin. 2010;19:2651–2656.
  • [43] Duranoğlu D, Trochimczuk AW, Beker U. Kinetics and thermodynamics of hexavalent chromium adsorption onto activated carbon derived from acrylonitrile-divinylbenzene copolymer. Chemical Engineering Journal. 2012;187:193-202. https://doi.org/10.1016/j.cej.2012.01.120
APA KUTLUAY S, BAYTAR O, ŞAHİN Ö (2019). Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells. , 279 - 298. 10.17515/resm2019.73en1122
Chicago KUTLUAY SİNAN,BAYTAR Orhan,ŞAHİN ÖMER Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells. (2019): 279 - 298. 10.17515/resm2019.73en1122
MLA KUTLUAY SİNAN,BAYTAR Orhan,ŞAHİN ÖMER Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells. , 2019, ss.279 - 298. 10.17515/resm2019.73en1122
AMA KUTLUAY S,BAYTAR O,ŞAHİN Ö Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells. . 2019; 279 - 298. 10.17515/resm2019.73en1122
Vancouver KUTLUAY S,BAYTAR O,ŞAHİN Ö Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells. . 2019; 279 - 298. 10.17515/resm2019.73en1122
IEEE KUTLUAY S,BAYTAR O,ŞAHİN Ö "Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells." , ss.279 - 298, 2019. 10.17515/resm2019.73en1122
ISNAD KUTLUAY, SİNAN vd. "Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells". (2019), 279-298. https://doi.org/10.17515/resm2019.73en1122
APA KUTLUAY S, BAYTAR O, ŞAHİN Ö (2019). Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells. Research on Engineering Structures and Materials, 5(3), 279 - 298. 10.17515/resm2019.73en1122
Chicago KUTLUAY SİNAN,BAYTAR Orhan,ŞAHİN ÖMER Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells. Research on Engineering Structures and Materials 5, no.3 (2019): 279 - 298. 10.17515/resm2019.73en1122
MLA KUTLUAY SİNAN,BAYTAR Orhan,ŞAHİN ÖMER Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells. Research on Engineering Structures and Materials, vol.5, no.3, 2019, ss.279 - 298. 10.17515/resm2019.73en1122
AMA KUTLUAY S,BAYTAR O,ŞAHİN Ö Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells. Research on Engineering Structures and Materials. 2019; 5(3): 279 - 298. 10.17515/resm2019.73en1122
Vancouver KUTLUAY S,BAYTAR O,ŞAHİN Ö Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells. Research on Engineering Structures and Materials. 2019; 5(3): 279 - 298. 10.17515/resm2019.73en1122
IEEE KUTLUAY S,BAYTAR O,ŞAHİN Ö "Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells." Research on Engineering Structures and Materials, 5, ss.279 - 298, 2019. 10.17515/resm2019.73en1122
ISNAD KUTLUAY, SİNAN vd. "Adsorption kinetics, equilibrium and thermodynamics of gas-phase toluene onto char produced from almond shells". Research on Engineering Structures and Materials 5/3 (2019), 279-298. https://doi.org/10.17515/resm2019.73en1122
Sayfa Oluşturulma Tarihi
23-04-2024 12:29

İLETİŞİM

TÜBİTAK ULAKBİM TR Dizin

Yüzüncüyıl, İşçi Blokları Mahallesi

Muhsin Yazıcıoğlu Caddesi No:51/C

06530 Çankaya / ANKARA +90 (312) 298 92 00

trdizin@tubitak.gov.tr

TÜBİTAK ULAKBİM Ulusal Akademik Ağ ve Bilgi Merkezi Cahit Arf Bilgi Merkezi © Tüm Hakları Saklıdır. Gizlilik Politikası Kullanım Şartları