Yıl: 1998 Cilt: 22 Sayı: 1 Sayfa Aralığı: 47 - 53 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Electropolymerization of thiophene with and without aniline in acetonitrile

Öz:
The electrooxidation behaviors of thiophene and 3-methylthiophene on a Pt surface in acetoni-trile/tetrabutylammonium tetrafluoroborate solution were investigated using cyclic voltammetry. The electropolymerization of these monomers and electrochemical properties of polythiophene and poly(3-methylthiophene) were studied in neutral, acidic and basic media. Mechanisms related to the formation of polymers and electroactivity loss were proposed. The effect of thiophene on the electropreparation and properties of polyaniline were also investigated. The presence of thiophene in solutions of aniline in acetonitrile accelerates the formation and causes an improvement in the conductivity of polyaniline films. Thiophene, which catalyzes the polyaniline formation, enters into the structure of the polymer in solutions containing higher thiophene to aniline concentration ratios and forms a copolymer.
Anahtar Kelime:

Konular: Mühendislik, Kimya
Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
APA CAN M, PEKMEZ K, PEKMEZ N, YILDIZ A (1998). Electropolymerization of thiophene with and without aniline in acetonitrile. , 47 - 53.
Chicago CAN MUZAFFER,PEKMEZ KADİR,PEKMEZ Nuran,YILDIZ Attila Electropolymerization of thiophene with and without aniline in acetonitrile. (1998): 47 - 53.
MLA CAN MUZAFFER,PEKMEZ KADİR,PEKMEZ Nuran,YILDIZ Attila Electropolymerization of thiophene with and without aniline in acetonitrile. , 1998, ss.47 - 53.
AMA CAN M,PEKMEZ K,PEKMEZ N,YILDIZ A Electropolymerization of thiophene with and without aniline in acetonitrile. . 1998; 47 - 53.
Vancouver CAN M,PEKMEZ K,PEKMEZ N,YILDIZ A Electropolymerization of thiophene with and without aniline in acetonitrile. . 1998; 47 - 53.
IEEE CAN M,PEKMEZ K,PEKMEZ N,YILDIZ A "Electropolymerization of thiophene with and without aniline in acetonitrile." , ss.47 - 53, 1998.
ISNAD CAN, MUZAFFER vd. "Electropolymerization of thiophene with and without aniline in acetonitrile". (1998), 47-53.
APA CAN M, PEKMEZ K, PEKMEZ N, YILDIZ A (1998). Electropolymerization of thiophene with and without aniline in acetonitrile. Turkish Journal of Chemistry, 22(1), 47 - 53.
Chicago CAN MUZAFFER,PEKMEZ KADİR,PEKMEZ Nuran,YILDIZ Attila Electropolymerization of thiophene with and without aniline in acetonitrile. Turkish Journal of Chemistry 22, no.1 (1998): 47 - 53.
MLA CAN MUZAFFER,PEKMEZ KADİR,PEKMEZ Nuran,YILDIZ Attila Electropolymerization of thiophene with and without aniline in acetonitrile. Turkish Journal of Chemistry, vol.22, no.1, 1998, ss.47 - 53.
AMA CAN M,PEKMEZ K,PEKMEZ N,YILDIZ A Electropolymerization of thiophene with and without aniline in acetonitrile. Turkish Journal of Chemistry. 1998; 22(1): 47 - 53.
Vancouver CAN M,PEKMEZ K,PEKMEZ N,YILDIZ A Electropolymerization of thiophene with and without aniline in acetonitrile. Turkish Journal of Chemistry. 1998; 22(1): 47 - 53.
IEEE CAN M,PEKMEZ K,PEKMEZ N,YILDIZ A "Electropolymerization of thiophene with and without aniline in acetonitrile." Turkish Journal of Chemistry, 22, ss.47 - 53, 1998.
ISNAD CAN, MUZAFFER vd. "Electropolymerization of thiophene with and without aniline in acetonitrile". Turkish Journal of Chemistry 22/1 (1998), 47-53.