Yıl: 2020 Cilt: 8 Sayı: 1 Sayfa Aralığı: 22 - 27 Metin Dili: İngilizce İndeks Tarihi: 23-09-2020

Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones

Öz:
In general, Suzuki-Miyaura coupling reaction between aryl bromide and arylboronic acids formthe new C-C bond in the presence of Pd-catalyst. In the present study, 2-bromo-3-ferrocenyl1,4-naphthoquinone 2 intermediate is synthesized by starting from 2,3-dibromo-1,4-naphthoquinone via Suzuki-Miyaura Coupling reaction. Then, it is investigated that the reactionbetween 2 and arylboronic acids give a new rearrangement reaction involving free radicals.Ferrocene structure displays critical roles for the formation of 2,3-diaryl-1,4-naphthoquinones.This reaction could be first example for the radical C-C bond cleavage reactions includingferrocene.
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Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA ERTAS N, Kivrak A (2020). Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. , 22 - 27.
Chicago ERTAS Nevroz Aslan,Kivrak Arif Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. (2020): 22 - 27.
MLA ERTAS Nevroz Aslan,Kivrak Arif Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. , 2020, ss.22 - 27.
AMA ERTAS N,Kivrak A Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. . 2020; 22 - 27.
Vancouver ERTAS N,Kivrak A Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. . 2020; 22 - 27.
IEEE ERTAS N,Kivrak A "Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones." , ss.22 - 27, 2020.
ISNAD ERTAS, Nevroz Aslan - Kivrak, Arif. "Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones". (2020), 22-27.
APA ERTAS N, Kivrak A (2020). Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. Manas Journal of Engineering, 8(1), 22 - 27.
Chicago ERTAS Nevroz Aslan,Kivrak Arif Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. Manas Journal of Engineering 8, no.1 (2020): 22 - 27.
MLA ERTAS Nevroz Aslan,Kivrak Arif Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. Manas Journal of Engineering, vol.8, no.1, 2020, ss.22 - 27.
AMA ERTAS N,Kivrak A Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. Manas Journal of Engineering. 2020; 8(1): 22 - 27.
Vancouver ERTAS N,Kivrak A Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones. Manas Journal of Engineering. 2020; 8(1): 22 - 27.
IEEE ERTAS N,Kivrak A "Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones." Manas Journal of Engineering, 8, ss.22 - 27, 2020.
ISNAD ERTAS, Nevroz Aslan - Kivrak, Arif. "Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones". Manas Journal of Engineering 8/1 (2020), 22-27.