1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini

Tabanlıgil Calam, Tuğba

doi:10.17341/gazimmfd.543608

1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini

Tuğba TABANLIGİL CALAM (Gazi Üniversitesi, Teknik Bilimler Meslek Yüksekokulu, Kimya ve Kimyasal İşleme Teknolojileri Bölümü, Ankara, Türkiye)

Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi

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Yıl: 2020 Cilt: 35 Sayı: 2 Sayfa Aralığı: 835 - 844 Metin Dili: Türkçe DOI: 10.17341/gazimmfd.543608 İndeks Tarihi: 11-01-2021

1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini

Öz:

Bu çalışmada, 1H-1,2,4-triazole-3-thiol (T3T) ile altın (Au) elektrot yüzeyi kaplanarak Au-T3T elektroduhazırlanmıştır. Kaplama işlemi, dönüşümlü voltametri (CV) yöntemi kullanılarak 1×10-3 mol L-1 T3Tçözeltisi içerisinde, 0,1 V s-1 tarama hızıyla -0,8 V ile +1,5 V arasında, 30 çevrim sayısı ilegerçekleştirilmiştir. Hazırlanan Au-T3T elektrodu yüzeyinde dönüşümlü voltametri (CV) ve diferansiyelpuls voltametrisi (DPV) teknikleri kullanılarak fenolün (Ph) elektrokimyasal davranışı incelenmiş ve DPVtekniği ile voltametrik tayini gerçekleştirilmiştir. Au-T3T elektrodu ile Ph tayini için uygun olan destekelektrolit ve pH gibi optimum çalışma şartları belirlenmiştir. En uygun destek elektrolit ortamının pH 1.0HClO4 çözeltisi olduğu belirlenmiştir. Au elektrot yüzeyinin T3T ile modifiye edilmesiyle, fenolünyükseltgenme pikinin akım değerinde 3,41 kat artış olduğu belirlenmiştir. Au-T3T modifiye elektrot ile Phiçin çalışma aralığı 1,010-7–3,610-5 M ve gözlenebilme sınırı (LOD) 1,210-8 M olarak belirlenmiştir. AuT3T elektrodunun Ph tayininde iyi bir tekrarlanabilirlik, kararlılık ve seçiciliğe sahip olduğu tespit edilmiştir.Modifiye elektrotla, musluk suyunda standart ekleme yöntemi kullanarak düşük bağıl standart sapma (BSS)ve iyi bir geri kazanım değerleri ile Ph tayini gerçekleştirilmiştir

Anahtar Kelime:

Investigation of the electrochemical behavior of phenol using 1H-1, 2, 4-triazole-3-thiol modified gold electrode and its voltammetric determination

Öz:

In this study, the Au-T3T modified electrode was prepared by coating the surface of gold (Au) electrode with 1H-1, 2, 4-triazole-3-thiol (T3T). Deposition of T3T was performed by cyclic voltammetry scanning from -0.8 V to +1.5 V at a sweep rate of 100 mV s-1 for 30 cycles in 1 mM T3T solution. The electrochemical behavior of phenol (Ph) was investigated by using voltammetry (CV) and differential pulse voltammetry (DPV) techniques on the Au-T3T electrode surface and voltammetric determination was performed. Optimum working conditions such as supporting electrolyte and its pH value, which are suitable for determination of Ph have been determined by Au-T3T electrode. The suitable support electrolyte was determined to be pH 1.0 HClO4 solution. By modifying the Au electrode surface with T3T, it was determined that the current value of the oxidation peak of the phenol increased by 3.41 times. The calibration curve and limit of detection (LOD) were obtained in the range of 1.0×10-7 - 3.6×10-5 M and 1.2×10-8 M on the Au-T3T modified electrode, respectively. The Au-T3T electrode has been seen to have good repeatability, stability, and selectivity in the determination of Ph. Determination of Ph on the Au-T3T modified electrode was performed with low standard deviation (BSS) and good recovery values using standard addition method in tap water.

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	Tabanlıgil Calam T (2020). 1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini. , 835 - 844. 10.17341/gazimmfd.543608
Chicago	Tabanlıgil Calam Tuğba 1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini. (2020): 835 - 844. 10.17341/gazimmfd.543608
MLA	Tabanlıgil Calam Tuğba 1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini. , 2020, ss.835 - 844. 10.17341/gazimmfd.543608
AMA	Tabanlıgil Calam T 1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini. . 2020; 835 - 844. 10.17341/gazimmfd.543608
Vancouver	Tabanlıgil Calam T 1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini. . 2020; 835 - 844. 10.17341/gazimmfd.543608
IEEE	Tabanlıgil Calam T "1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini." , ss.835 - 844, 2020. 10.17341/gazimmfd.543608
ISNAD	Tabanlıgil Calam, Tuğba. "1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini". (2020), 835-844. https://doi.org/10.17341/gazimmfd.543608

APA	Tabanlıgil Calam T (2020). 1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 35(2), 835 - 844. 10.17341/gazimmfd.543608
Chicago	Tabanlıgil Calam Tuğba 1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 35, no.2 (2020): 835 - 844. 10.17341/gazimmfd.543608
MLA	Tabanlıgil Calam Tuğba 1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, vol.35, no.2, 2020, ss.835 - 844. 10.17341/gazimmfd.543608
AMA	Tabanlıgil Calam T 1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 2020; 35(2): 835 - 844. 10.17341/gazimmfd.543608
Vancouver	Tabanlıgil Calam T 1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 2020; 35(2): 835 - 844. 10.17341/gazimmfd.543608
IEEE	Tabanlıgil Calam T "1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini." Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 35, ss.835 - 844, 2020. 10.17341/gazimmfd.543608
ISNAD	Tabanlıgil Calam, Tuğba. "1H-1, 2, 4-triazole-3-thiol modifiye altın elektrot kullanılarak fenolün elektrokimyasal davranışının incelenmesi ve voltametrik tayini". Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 35/2 (2020), 835-844. https://doi.org/10.17341/gazimmfd.543608