USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER

DURGUT, MERVE; Kaya, Şefika; Aşçı, Yeliz

USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER

Merve DURGUT, (Eskişehir Osmangazi Üniversitesi, Kimya Mühendisliği Bölümü, Eskişehir, Türkiye)

Şefika KAYA, (Eskişehir Osmangazi Üniversitesi, Kimya Mühendisliği Bölümü, Eskişehir, Türkiye)

Yeliz AŞÇI (Eskişehir Osmangazi Üniversitesi, Kimya Mühendisliği Bölümü, Eskişehir, Türkiye)

Eskişehir Osmangazi Üniversitesi mühendislik ve mimarlık fakültesi dergisi (online)

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Yıl: 2021 Cilt: 29 Sayı: 1 Sayfa Aralığı: 110 - 117 Metin Dili: İngilizce İndeks Tarihi: 21-05-2021

USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER

Öz:

With the increase in industrialization, the unconscious use of surface and groundwater has led to the rapid pollution of water, which is the main source of life for all living things. As a result, the need for clean water has brought the global water crisis to the agenda. The textile industry is one of the largest producers of wastewater in the world. Textile industry wastewater contains high amounts of non-biodegradable organic compounds, high concentrations of dyestuffs, salt, detergent and soap. Therefore, it is of great importance to remove organic pollutants in this wastewater. Since traditional methods are insufficient to remove organic compounds in wastewater, advanced treatment methods are required. Advanced oxidation processes (AOPs) are one of the alternative treatment methods preferred in recent years. In this study, color removal from textile industry wastewater was researched by the heterogeneous Fenton process, which is an advanced oxidation process. The parameters such as catalyst dosage, pH, hydrogen peroxide concentration, temperature, reaction time and mixing speed that effect heterogeneous Fenton processes were investigated. Under optimum experimental conditions, the color removal efficiency was achieved as 84.4%.

Anahtar Kelime:

TEKSTİL ENDÜSTRİSİ ATIKSUYUNDA HETEROJEN FENTON PROSESİ İÇİN KATALİZÖR OLARAK DEMİR İÇEREN METAL OKSİT KULLANIMI

Öz:

Endüstrileşmenin artışıyla beraber yüzey ve yeraltı sularının bilinçsiz bir şekildekullanımı tüm canlılar için temel yaşam kaynağı olan suyun gün geçtikçe hızlı bir şekildekirlenmesine yol açmıştır. Bunun sonucunda temiz su ihtiyacı da küresel su krizinigündeme getirmiştir. Tekstil endüstrisi dünyadaki en büyük atıksu üreticilerinden biridir.Tekstil endüstrisi atıksuları, yüksek miktarlarda biyolojik olarak parçalanamayanorganik bileşikler, yüksek konsantrasyonlarda boyar maddeler, tuz, deterjan ve sabuniçerir. Bu nedenle atıksuyun içerisindeki organik kirleticilerin uzaklaştırılması büyükönem taşımaktadır. Atıksudaki organik bileşiklerin uzaklaştırılmasında gelenekselyöntemler yetersiz olduğundan, gelişmiş arıtma yöntemlerine ihtiyaç duyulmaktadır.İleri oksidasyon prosesleri (İOP) son yıllarda tercih edilen alternatif arıtımyöntemlerinden biridir. Bu çalışmada, tekstil endüstrisi atıksuyundan renk giderimi, ilerioksidasyon proseslerinden biri olan heterojen Fenton prosesi ile araştırılmıştır.Heterojen Fenton proseslerini etki eden katalizör dozajı, pH, hidrojen peroksitkonsantrasyonu, sıcaklık, reaksiyon süresi ve karıştırma hızı gibi parametrelerincelenmiştir. Optimum deneysel koşullar altında renk giderme verimi % 84.4 olarak eldeedilmiştir.

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

Aşçı, Y. (2013). Decolorization of Direct Orange 26 by heterogeneous Fenton oxidation. Desalination and Water Treatment, 51, 7612–7620. doi: https://doi.org/10.1080/19443994.2013.776504
Ayas, N., Asci, Y. & Yurdakul, M. (2016). Using of Fe/ZnO2 catalyst to remove direct Orange 26 from water by Fenton oxidation at wide pH values. Fresenius Environmental Bulletin, 25, 3272-3279.
Buthiyappan, A., Aziz A.R.A. & Daud, W.M.A.W. (2016). Recent advances and prospects of catalytic advanced oxidation process in treating textile effluents. Reviews in Chemical Engineering, 32(1), 1-47. doi: https://doi.org/10.1515/revce-2015-0034
Buthiyappan, A. & Raman, A.A.A. (2019). Energy intensified integrated advanced oxidation technology for the treatment of recalcitrant industrial wastewater. Journal of Cleaner Production, 206, 1025-1040. doi: https://doi.org/10.1016/ j.jclepro.2018.09.234
Chen, Y. (2006). Study on the kinetics of removal of microcystin-LR by Fenton reagent. Safety and Environmental Engineering, 13(4), 50-58.
Deng, J., Wen, X., Wang, Q. (2012). Solvothermal in situ synthesis of Fe3O4-multi-walled carbon nanotubes withenhanced heterogeneous Fenton-like activity. Materials Research Bulletin, 47, 3369-3376. doi: https://doi.org/10.1016/j.materresbull.2012.07.021
Devi, L.G., Kumar, S.G., Reddy, K.M. & Munikrishnappa, C. (2009). Photo degradation of Methyl Orange an azo dye by Advanced Fenton Process using zero valent metallic iron: Influence of various reaction parameters and its degradation mechanism. Journal of Hazardous Materials, 164, 459-467. doi: https://doi.org/10.1016/j.jhazmat.2008.08.017
Domingues, E., Assunçao, N., Gomes, J., Lopes, D.V., Frade, J.R., Quina, M.J., Quinta- Ferreira, R.M. & Martins, R.C. (2019). Catalytic efficiency of red mud for the degradation of olive mill wastewater through heterogeneous Fenton’s process. Water, 11, 1183. doi: https://doi.org/10.3390/w11061183
Feng, F., Xu, Z., Li, X., You, W. &Zhen, Y. (2010). Advanced treatment of dyeing wastewater towards reuse by the combined Fenton oxidation and membrane bioreactor process. Journal of Environmental Sciences, 22(11), 1657-1665. doi: https://doi.org/10.1016/S1001-0742(09)60303-X
Gan, P.P. & Li S.F.Y. (2013). Efficient removal of Rhodamine B using a rice hull-based silica supported iron catalyst by Fenton-like process. Chemical Engineering Journal, 229, 351-363. doi: https://doi.org/10.1016/j.cej.2013.06.020
Ghasemi, H., Aghabarari, B., Alizadeh, M., Khanlarkhani, A. & Abu-Zahra, N. (2020). High efficiency decolorization of wastewater by Fenton catalyst: Magnetic iron-copper hybrid oxides. Journal of Water Process Engineering, 37, 101540. doi: https://doi.org/10.1016/j.jwpe.2020.101540
Göde, J.N., Souza, D.H., Trevisan, V. & Skoronski, E. (2019). Application of the Fenton and Fenton-like Processes in the Landfill Leachate Tertiary Treatment. Journal of Environmental Chemical Engineering, 7(5), 103352. doi: https://doi.org/10.1016/j.jece.2019.103352
Guo, S., Zhang, G. & Wang, J. (2014). Photo-Fenton degradation of rhodamine B using Fe2O3-Kaolin as heterogeneous catalyst: Characterization, process optimization and mechanism. Journal of Colloid and Interface Science, 433, 1-8. doi: https://doi.org/10.1016/j.jcis.2014.07.017
Idel-aouad, R., Valiente, M., Yaacoubi, A., Tanouti, B. & Mesas, M.L. (2011). Rapid decolourization and mineralization of the azo dye C.I. Acid Red 14 by heterogeneous Fenton reaction. Journal of Hazardous Materials, 186, 745-750. doi: https://doi.org/10.1016/j.jhazmat.2010.11.056
Iranifam, M., Zarei, M. & Khataee, A.R. (2011). Decolorization of CI Basic Yellow 28 solution using supported ZnO nanoparticles coupled with photoelectro-Fenton process. Journal of Electroanalytical Chemistry, 659, 107-112. doi: https://doi.org/10.1016/j.jelechem.2011.05.010
Kantar, C., Oral, O., Urken, O. & Oz, N.A. (2019). Role of complexing agents on oxidative degradation of chlorophenolic compounds by pyrite-Fenton process: Batch and column experiments. Journal of Hazardous Materials, 373, 160-167. doi: https://doi.org/10.1016/j.jhazmat.2019.03.065
Kaya, S. & Asci, Y. (2019). Application of heterogeneous Fenton processes using Fe(III)/MnO2 and Fe(III)/SnO2 catalysts in the treatment of sunflower oil industrial wastewater. Desalination and Water Treatment, 171, 302-313. doi: https://doi.org/10.5004/dwt.2019.24797
Kwan, W.P. & Voelker, B.M. (2003). Rates of hydroxyl radical generation and organic compound oxidation in mineral-catalyzed Fenton-like systems. Environmental Science & Technology, 37, 1150-1158. doi: https://doi.org/10.1021/es020874g
Lin, H., Ma, X., Zhao, L. & Dong, Y. (2014). Kinetics and products of PCB28 degradation through a goethitecatalyzed Fenton-like reaction. Chemosphere, 101, 15-20. doi: https://doi.org/10.1016/ j.chemosphere.2013.11.063
Malakootian, M., Jafari, M.H., Moosavi, S. & Daneshpazhoh, M. (2013). Performance evaluation of Fenton process to remove chromium, COD and turbidity from electroplating industry wastewater. Water and Wastewater, 24, 2-10.
Mokhbi, Y., Korichi, M. & Akchiche, Z. (2019). Combined photocatalytic and Fenton oxidation for oily wastewater treatment. Applied Water Science, 9(35), 2-9. doi: https://doi.org/10.1007/s13201-019- 0916-x
Naseem, Z., Bhatti, H. N., Iqbal, M., Noreen, S. & Zahid, M. (2019). Fenton and photo-fenton oxidation for the remediation of textile effluents: An experimental study. Textiles and Clothing, 9, 235-251. doi: https://doi.org/10.1002/9781119526599.ch9
Nidheesh, P.V., Gandhimathi, R. & Ramesh, S.T. (2013). Degradation of dyes from aqueous solution by Fenton processes: a review. Environmental Science and Pollution Research, 20, 2099-2132. doi: https://doi.org/10.1007/s11356-012-1385-z
Qiao, R.P., Li, N., Qi, X.H., Wang, Q.S. & Zhuang, Y.Y. (2005). Degradation of microcystin-RR by UV radiation in the presence of hydrogenperoxide. Toxicon, 45, 745-752. doi: https://doi.org/10.1016/ j.toxicon.2005.01.012
Rehman, F., Sayed, M., Khan, J.A., Shah, L.A., Shah, N.S., Khan H.M. & Khattak, R. (2018). Degradation of Crystal Violet Dye by Fenton and Photo-Fenton Oxidation Processes. Zeitschrift für Physikalische Chemie, 232, 1771-1786. doi: https://doi.org/10.1515/zpch-2017-1099
Ribeiro, R.S., Silva, A.M.T., Figueiredo, J.L., Faria, J.L. & Gomes, H.T. (2016). Catalytic wet peroxide oxidation: a route towards the application of hybrid magnetic carbon nanocomposites for the degradation of organic pollutants. A review. Applied Catalysis B: Environmental, 187, 428-460. doi: https://doi.org/10.1016/j.apcatb.2016.01.033
Ruales-Lonfat, C., Barona, J.F., Sienkiewicz, A., Bensimon, M., Vélez-Colmenares, J., Benítez, N. & Pulgarín, C. (2015). Iron oxides semiconductors are efficients for solar water disinfection: A comparison with photoFenton processes at neutral pH. Applied Catalysis B: Environmental, 166-167, 497-508. doi: https://doi.org/10.1016/j.apcatb.2014.12.007
Sani, S., Dashti, A. F. & Adnan R. (2020). Applications of Fenton oxidation processes for decontamination of palm oil mill effluent: A review. Arabian Journal of Chemistry, 13, 7302-7323. doi: https://doi.org/10.1016/j.arabjc.2020.08.009
Soltani, R.D.C., Khataee, A.R., Safari, M. & Joo, S.W. (2013). Preparation of bio-silica/chitosan nanocomposite for adsorption of a textile dye in aqueous solutions. International Biodeterioration & Biodegradation, 85, 383-391. doi: https://doi.org/10.1016/j.ibiod.2013.09.004
Ukpaka, C.P. (2018). Model prediction on the characteristics of dipole atoms: The concept of Schrodinger’s equation. Chemistry International, 4, 146-153. doi: https://doi.org/10.31221/ osf.io/a249h
Verma, A.K., Dash, R.R. & Bhunia, P. (2012). A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters. Journal of Environmental Management, 93(1), 154-168. doi: https://doi.org/10.1016/j.jenvman.2011.09.012
Wang, N., Zheng, T., Zhang, G. & Wang, P. (2016). A review on Fenton-like processes for organic wastewater treatment. Journal of Environmental Chemical Engineering, 4, 762-787. doi: https://doi.org/10.1016/j.jece.2015.12.016
Xia, Q., Jiang, Z., Wang, J. & Yao, Z. (2017). A facile preparation of hierarchical dendriticzero-valent iron for Fenton-like degradation of phenol. Catalysis Communications, 100, 57-61. doi: https://doi.org/10.1016/j.catcom.2017.06.017
Zhang, X., Wang, L., Liu, C., Ding, Y., Zhang, S., Zeng, Y. & Luo, S. (2016). A bamboo-inspired hierarchical nanoarchitecture of Ag/CuO/TiO2 nanotube array for highly photocatalytic degradation of 2,4- dinitrophenol. Journal of Hazardous Materials, 313, 244-252. doi: https://doi.org/10.1016/ j.jhazmat.2016.03.094

APA	DURGUT M, Kaya Ş, Aşçı Y (2021). USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER. , 110 - 117.
Chicago	DURGUT MERVE,Kaya Şefika,Aşçı Yeliz USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER. (2021): 110 - 117.
MLA	DURGUT MERVE,Kaya Şefika,Aşçı Yeliz USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER. , 2021, ss.110 - 117.
AMA	DURGUT M,Kaya Ş,Aşçı Y USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER. . 2021; 110 - 117.
Vancouver	DURGUT M,Kaya Ş,Aşçı Y USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER. . 2021; 110 - 117.
IEEE	DURGUT M,Kaya Ş,Aşçı Y "USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER." , ss.110 - 117, 2021.
ISNAD	DURGUT, MERVE vd. "USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER". (2021), 110-117.

APA	DURGUT M, Kaya Ş, Aşçı Y (2021). USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER. Eskişehir Osmangazi Üniversitesi mühendislik ve mimarlık fakültesi dergisi (online), 29(1), 110 - 117.
Chicago	DURGUT MERVE,Kaya Şefika,Aşçı Yeliz USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER. Eskişehir Osmangazi Üniversitesi mühendislik ve mimarlık fakültesi dergisi (online) 29, no.1 (2021): 110 - 117.
MLA	DURGUT MERVE,Kaya Şefika,Aşçı Yeliz USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER. Eskişehir Osmangazi Üniversitesi mühendislik ve mimarlık fakültesi dergisi (online), vol.29, no.1, 2021, ss.110 - 117.
AMA	DURGUT M,Kaya Ş,Aşçı Y USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER. Eskişehir Osmangazi Üniversitesi mühendislik ve mimarlık fakültesi dergisi (online). 2021; 29(1): 110 - 117.
Vancouver	DURGUT M,Kaya Ş,Aşçı Y USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER. Eskişehir Osmangazi Üniversitesi mühendislik ve mimarlık fakültesi dergisi (online). 2021; 29(1): 110 - 117.
IEEE	DURGUT M,Kaya Ş,Aşçı Y "USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER." Eskişehir Osmangazi Üniversitesi mühendislik ve mimarlık fakültesi dergisi (online), 29, ss.110 - 117, 2021.
ISNAD	DURGUT, MERVE vd. "USING IRON-CONTAINING METAL OXIDE AS CATALYST FOR HETEROGENEOUS FENTONPROCESS IN TEXTILE INDUSTRY WASTEWATER". Eskişehir Osmangazi Üniversitesi mühendislik ve mimarlık fakültesi dergisi (online) 29/1 (2021), 110-117.