Yıl: 2021 Cilt: 14 Sayı: 1 Sayfa Aralığı: 73 - 80 Metin Dili: İngilizce DOI: 10.25135/acg.oc.96.2012.1902 İndeks Tarihi: 24-06-2021

Swelling and durability performance of surface-grafted polymer brushes and brush gels

Öz:
Polymer brushes and brush gels were prepared by RAFT polymerization. Prepared surfaces werecharacterized by XPS, AFM, ellipsometry, and water contact angle measurements. The swelling properties andstability of surfaces were compared. It was determined that the swelling ratio decreased with increasing graftingdensity and cross-linker ratio for polymer brushes and brush gels, respectively. As a result, it was observed that crosslinked polymer brushes were more stable than polymer brushes, and the stability and swelling properties of polymerbrushes could be controlled by cross-linking.
Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
  • [1] Plechkova, N. V.; Seddon, K. R. Applications of ionic liquids in chemical industry. Chem. Soc. Rev. 2008, 37, 123-150.
  • [2] Zhang, Q.; Zhang, S.; Deng, Y. Recent advances in ionic liquid catalysis. Green Chem. 2011, 13, 2619- 2637.
  • [3] Watanabe, M.; Thomas, M. L.; Zhang, S.; Ueno, K.; Yasuda, T.; Dokko K. Application of ionic liquids to energy storage and conversion materials and devices. Chem. Rev. 2017, 117, 7190-7239.
  • [4] Zhu, S.; Wu, Y.; Chen, Q.; Yu, Z.; Wang, C.; Jin, S.; Ding, Y.; Wu, G. Dissolution of cellulose with ionic liquids and its application: A mini-review. Green Chem. 2006, 8, 325-327.
  • [5] Devasurendra, A. M.; Zhang, C.; Young, J. A.; Tillekeratne, L. M. V.; Anderson, J. L.; Kirchhoff, J. R. Electropolymerized pyrrole-based conductive polymeric ionic liquids and their application for solid-phase microextraction. ACS Appl. Mater. Interfaces 2017, 9, 24955-24963.
  • [6] Grygiel, K.; Lee, J.-S.; Sakaushi, K.; Antonietti, M.; Yuan, Y. Thiazolium poly(ionic liquid)s: Synthesis and application as binder for lithium-ion batteries. ACS Macro Lett. 2015, 4, 1312-1316.
  • [7] Dong, Y.-S.; Xiong, X.-H.; Lu, X.-W.; Wu, Z.-Q.; Chen, H. Antibacterial surfaces based on poly(cationic liquid) brushes: Switchability between killing and releasing via anion counterion switching. J. Mater. Chem. B 2016, 4, 6111-6116.
  • [8] Tauber, K.; Dani, A.; Yuan, J. Covalent cross-linking of porous poly(ionic liquid) membrane via a triazine network. ACS Macro Lett. 2017, 6, 1-5.
  • [9] Giussi, J. M.; Cortez, M. L.; Marmisolle, W. A.; Azzaroni, O. Practical use of polymer brushes in sustainable energy applications: interfacial nanoarchitectonics for high-efficiency devices. Chem. Soc. Rev. 2019, 48, 814-849.
  • [10] Demirci, S.; Kinali-Demirci, S.; Jiang, S. A switchable polymer brush system for antifouling and controlled detection. Chem. Commun. 2017, 53, 3713-3716.
  • [11] Wang, P.; Koberstein, J. T., Morphology of immiscible polymer blend thin films prepared by spin-coating. Macromolecules 2004, 37, 5671-5681.
  • [12] Peng, S.; Bhushan, B. Smart polymer brushes and their emerging applications. RSC Adv. 2012, 2, 8557- 8578.
  • [13] Demirci, S.; Caykara, T. High density cationic polymer brushes from combined “click chemistry” and RAFT‐mediated polymerization. J. Polym. Sci., Part A: Polym. Chem. 2012, 50, 2999-3007.
  • [14] Chen, W.-L.; Cordero, R.; Tran, H.; Ober, C. K. 50th Anniversary Perspective: Polymer Brushes: Novel Surfaces for Future Materials. Macromolecules 2017, 50, 4089-4113.
  • [15] Ozturk, E. A.; Eroglu, M. S.; Caykara, T. Synthesis of hyaluronated poly(exo‑7‑oxabicyclo[2.2.1]hept‑5‑en‑2,3‑dicarboxylic anhydride) brushes via a combination of surface‑initiated ring‑opening metathesis polymerization and thiol‑ene click reaction. Chemical Papers 2020. DOI: 10.1007/s11696-020-01418-5
  • [16] Demirci, S.; Kinali-Demirci, S.; Caykara, T. Stimuli‐responsive diblock copolymer brushes via combination of “click chemistry” and living radical polymerization. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 2677-2685.
  • [17] Edmondson, S.; Osborne, V. L.; Huck, W. T. S. Polymer brushes via surface-initiated polymerizations. Chem. Soc. Rev. 2004, 33, 14-22.
  • [18] Zhao, B.; Brittain, W. J. Polymer brushes: surface-immobilized macromolecules. Prog. Polym. Sci. 2000, 25, 677-710.
  • [19] Welch, M. E.; Ober, C. K. Responsive and patterned polymer brushes. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 1457-1472.
  • [20] Demirci, S.; Kinali-Demirci, S.; VanVeller, B. Surface-grafted polymeric ionic liquids with tunable morphology via in/ex situ cross-linking methods. ACS Macro Lett. 2020, 9, 1806-1811.
  • [21] Dehghani, E. S.; Spencer, N. D.; Ramakrishna, S. N.; Benetti, E. M. Cross-linking polymer brushes with ethylene glycol-containing segments: influence on physicochemical and antifouling properties. Langmuir 2016, 32, 10317-10327.
  • [22] Demirci, S. Crosslinked-polymer brushes with switchable capture and release capabilities. Polymers 2018, 10, 956.
  • [23] Moncy, P.; Klok, H.-A. Reversibly cross-linking polymer brushes using interchain disulfide bonds. Macromolecules 2020, 53, 731-740.
  • [24] Zhang, J.; Xu, D.; Guo, J.; Sun, Z.; Qian, W.; Zhang, Y.; Yan, F. CO2 responsive imidazolium-type poly(ionic liquid) gels. Macromol. Rapid Commun. 2016, 37, 1194-1199.
  • [25] Taghavikish, M.; Subianto, S.; Dutta, N. K.; de Campo, L.; Mata, J. P.; Rehm, C.; Choudhury, N. R. Polymeric ionic liquid nanoparticle emulsions as a corrosion inhibitor in anticorrosion coatings. ACS Omega 2016, 1, 29-40.
  • [26] Demirci, S.; Kinali-Demirci, S.; Caykara, T. Novel pH-responsive mixed-charge copolymer brushes based on carboxylic acid and quaternary amine monomers. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 1612- 1619.
  • [27] Demirci, S.; Caykara, T. RAFT-mediated synthesis of cationic poly[(ar-vinylbenzyl)trimethylammonium chloride] brushes for quantitative DNA immobilization. Mater. Sci. Eng., C 2013, 33, 111-120.
  • [28] Demirci, S.; Kinali-Demirci, S.; VanVeller, B. Controlled supramolecular complexation of cyclodextrinfunctionalized polymeric ionic liquid brushes. ACS Appl. Polym. Mater. 2020, 2, 751-757.
  • [29] Malham, I. B.; Bureau, L. Density effect on collapse, compression and adhesion of thermoresponsive polymer brushes. Langmuir 2010, 26, 4762-4768.
APA KINALI DEMIRCI S, Demirci S (2021). Swelling and durability performance of surface-grafted polymer brushes and brush gels. , 73 - 80. 10.25135/acg.oc.96.2012.1902
Chicago KINALI DEMIRCI Selin,Demirci Serkan Swelling and durability performance of surface-grafted polymer brushes and brush gels. (2021): 73 - 80. 10.25135/acg.oc.96.2012.1902
MLA KINALI DEMIRCI Selin,Demirci Serkan Swelling and durability performance of surface-grafted polymer brushes and brush gels. , 2021, ss.73 - 80. 10.25135/acg.oc.96.2012.1902
AMA KINALI DEMIRCI S,Demirci S Swelling and durability performance of surface-grafted polymer brushes and brush gels. . 2021; 73 - 80. 10.25135/acg.oc.96.2012.1902
Vancouver KINALI DEMIRCI S,Demirci S Swelling and durability performance of surface-grafted polymer brushes and brush gels. . 2021; 73 - 80. 10.25135/acg.oc.96.2012.1902
IEEE KINALI DEMIRCI S,Demirci S "Swelling and durability performance of surface-grafted polymer brushes and brush gels." , ss.73 - 80, 2021. 10.25135/acg.oc.96.2012.1902
ISNAD KINALI DEMIRCI, Selin - Demirci, Serkan. "Swelling and durability performance of surface-grafted polymer brushes and brush gels". (2021), 73-80. https://doi.org/10.25135/acg.oc.96.2012.1902
APA KINALI DEMIRCI S, Demirci S (2021). Swelling and durability performance of surface-grafted polymer brushes and brush gels. Organic Communications, 14(1), 73 - 80. 10.25135/acg.oc.96.2012.1902
Chicago KINALI DEMIRCI Selin,Demirci Serkan Swelling and durability performance of surface-grafted polymer brushes and brush gels. Organic Communications 14, no.1 (2021): 73 - 80. 10.25135/acg.oc.96.2012.1902
MLA KINALI DEMIRCI Selin,Demirci Serkan Swelling and durability performance of surface-grafted polymer brushes and brush gels. Organic Communications, vol.14, no.1, 2021, ss.73 - 80. 10.25135/acg.oc.96.2012.1902
AMA KINALI DEMIRCI S,Demirci S Swelling and durability performance of surface-grafted polymer brushes and brush gels. Organic Communications. 2021; 14(1): 73 - 80. 10.25135/acg.oc.96.2012.1902
Vancouver KINALI DEMIRCI S,Demirci S Swelling and durability performance of surface-grafted polymer brushes and brush gels. Organic Communications. 2021; 14(1): 73 - 80. 10.25135/acg.oc.96.2012.1902
IEEE KINALI DEMIRCI S,Demirci S "Swelling and durability performance of surface-grafted polymer brushes and brush gels." Organic Communications, 14, ss.73 - 80, 2021. 10.25135/acg.oc.96.2012.1902
ISNAD KINALI DEMIRCI, Selin - Demirci, Serkan. "Swelling and durability performance of surface-grafted polymer brushes and brush gels". Organic Communications 14/1 (2021), 73-80. https://doi.org/10.25135/acg.oc.96.2012.1902