Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene
Yıl: 2021 Cilt: 5 Sayı: 1 Sayfa Aralığı: 33 - 41 Metin Dili: İngilizce DOI: 10.32571/ijct.755761 İndeks Tarihi: 29-07-2022
Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene
Öz: This study focused on the preparation of silica-coated Fe3O4(Fe3O4@SiO2) for the improvement of the vapor-phaseadsorption of benzene. The Fe3O4@SiO2 was prepared via theco-precipitation method, while its characterization was carriedout using FT-IR, SEM and BET surface area analyses. Theexperimental parameters were evaluated for the vapor-phaseadsorption of benzene using response surface methodology(RSM). The Fe3O4@SiO2 adsorbed 197.50 mg g-1 of the vaporphase benzene under the following optimum conditions: 39.93min residence time, 13.57 mg l-1 initial benzene concentrationand 26.87°C temperature. The vapor-phase adsorptionmechanism of benzene on the Fe3O4@SiO2 was clarified byinvestigating the isotherms including Dubinin-Radushkevich(D-R), Freundlich and Langmuir, and the experimenatal datawere well fitted to the D-R model. The vapor-phase adsorptionkinetics of benzene on the Fe3O4@SiO2 was clarified byinvestigating the kinetics such as pseudo first-order (PFO)model and pseudo second-order (PSO) model, and theexperimantal results obeyed the PSO model. This studydemonstrated the application potential of magneticFe3O4@SiO2 as promising low-cost nano-adsorbent.
Anahtar Kelime: Benzenin buhar-fazı adsorpsiyonunun iyileştirilmesi için etkili nano-adsorbentler olarak silika-kaplı manyetik Fe3O4 nanoparçacıkları
Öz: Bu çalışma, benzenin buhar-fazı adsorpsiyonunun iyileştirilmesi için silika-kaplı Fe3O4 (Fe3O4@SiO2) hazırlanmasına odaklandı. Fe3O4@SiO2 birlikte çökeltme yöntemi ile hazırlanırken karakterizasyonu FT-IR, SEM ve BET yüzey alanı analizleri kullanılarak gerçekleştirildi. Deneysel parametreler, yanıt yüzey metodolojisi (RSM) kullanılarak benzenin buhar-fazı adsorpsiyonu için değerlendirildi. Fe3O4@SiO2, aşağıdaki optimum koşullar altında 197,50 mg g-1 buhar-fazı benzeni adsorbe etti: 39,93 dakika kalma süresi, 13,57 mg l-1 başlangıç benzen konsantrasyonu ve 26,87°C sıcaklık. Benzenin Fe3O4@SiO2 üzerindeki buhar fazı adsorpsiyon mekanizması, DubininRadushkevich (D-R), Freundlich ve Langmuir dahil izotermler incelenerek netleştirildi ve deneysel veriler D-R modeline iyi bir şekilde uyduruldu. Benzenin Fe3O4@SiO2 üzerindeki buhar-fazı adsorpsiyon kinetiği, sözde birinci-dereceden (SBD) model ve sözde ikinci dereceden (SİD) model gibi kinetikler incelenerek netleştirildi, ve deneysel sonuçlar SİD modele uydu. Bu çalışma, Fe3O4@SiO2'nin umut verici düşük maliyetli nano-adsorbent olarak uygulama potansiyelini gösterdi.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
- 1. Ece, M. Ş.; Kutluay, S.; Şahin, Ö.; Horoz, S. Ind. Eng. Chem. Res. 2020, 59 (48), 21106-21123.
- 2. Kutluay, S. Fuel 2021, 287, 119691.
- 3. Kutluay, S.; Temel, F. Colloid Surf. A-Physicochem. Eng. Asp. 2021, 609, 125848.
- 4. Şahin, Ö.; Kutluay, S.; Horoz, S.; Ece, M. Ş. Environ. Sci. Pollut. Res. 2021, 28 (5), 5231-5253.
- 5. Wallace, L. A. Environ. Health Perspect. 1989, 82, 165-169.
- 6. Yang, X.; Yi, H.; Tang, X.; Zhao, S.; Yang, Z.; Ma, Y.; Feng, T.; Cui, X. J. Environ. Sci. 2018, 67, 104-114.
- 7. Wibowo, N.; Setyadhi, L.; Wibowo, D.; Setiawan, J.; Ismadji, S. J. Hazard. Mater. 2007, 146 (1-2), 237-242.
- 8. de las Nieves Piña, M.; Rodríguez, P.; Gutiérrez, M. S.; Quiñonero, D.; Morey, J.; Frontera, A. Chem. Eur. J. 2018, 24 (49), 12820-12826.
- 9. Connie, Z. Y.; Ariya, P. A. J. Environ. Sci. 2015, 31, 164-174.
- 10. Roto, R.; Yusran, Y.; Kuncaka, A. Appl. Surf. Sci. 2016, 377, 30-36.
- 11. Mohamed, E. F. Environ. Dev. Sustain. 2017, 6 (2).
- 12. Duan, S.; Xu, X.; Liu, X.; Wang, Y.; Hayat, T.; Alsaedi, A.; Meng, Y.; Li, J. J. Colloid Interface Sci. 2018, 513, 92-103.
- 13. Zandipak, R.; Sobhan Ardakani, S.; Shirzadi, A. Sep. Sci. Technol. 2020, 55 (3), 456-470.
- 14. Kutluay, S.; Baytar, O.; Şahin, Ö. J. Environ. Chem. Eng. 2019, 7 (2), 102947.
- 15. Zhao, Z.; Wang, S.; Yang, Y.; Li, X.; Li, J.; Li, Z. Chem. Eng. J. 2015, 259, 79-89.
- 16. Yousefi, V.; Tarhriz, V.; Eyvazi, S.; Dilmaghani, A. J. Nanobiotechnology 2020, 18 (1), 155.
- 17. Ma, C.; Li, C.; He, N.; Wang, F.; Ma, N.; Zhang, L.; Lu, Z.; Ali, Z.; Xi, Z.; Li, X. J. Biomed. Nanotechnol. 2012, 8 (6), 1000-1005.
- 18. Kutluay, S.; Ece, M. Ş.; Şahin, Ö. Int. J. Chem. Technol. 2020, 4 (2), 146-155.
- 19. Temel, F.; Kutluay, S. New J. Chem. 2020, 44 (30), 12949-12961.
- 20. Vohra, M. S. Arab. J. Sci. Eng. 2015, 40 (11), 3007- 3017.
- 21. Padmavathy, V. Bioresour. Technol. 2008, 99 (8), 3100-3109.
- 22. Kutluay, S.; Baytar, O.; Şahin, Ö. Res. Eng. Struct. Mater. 2019, 5 (3), 279-298.
- 23. Ali, R. M.; Hamad, H. A.; Hussein, M. M.; Malash, G. F. Ecol. Eng. 2016, 91, 317-332.
- 24. Vora, S.; Khimani, M.; De, C. Ecol. Eng. 2013, 34 (7), 947-956.
- 25. Salih, W. M.; Gzar, H. A.; Hassan, N. F. J. Eng. 2012, 18 (9), 1042-1054.
- 26. Laskar, I. I.; Hashisho, Z. Sep. Purif. Technol. 2020, 116681.
- 27. Abbas, A.; Abussaud, B. A.; Al-Baghli, N. A.; Khraisheh, M.; Atieh, M. A. J. Nanomater. 2016, 2016.
- 28. Hu, Q.; Zhang, Z. J. Mol. Liq. 2019, 277, 646-648.
- 29. Sadeghalvad, B.; Azadmehr, A.; Hezarkhani, A. RSC Adv. 2016, 6 (72), 67630-67642.
- 30. Wang, C.; Zhong, H.; Wu, W.; Pan, C.; Wei, X.; Zhou, G.; Yang, F. ACS Omega 2019, 4 (1), 1652-1661.
| APA | ECE M, KUTLUAY S, ŞAHİN Ö (2021). Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. , 33 - 41. 10.32571/ijct.755761 |
| Chicago | ECE MEHMET SAKIR,KUTLUAY SİNAN,ŞAHİN Ömer Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. (2021): 33 - 41. 10.32571/ijct.755761 |
| MLA | ECE MEHMET SAKIR,KUTLUAY SİNAN,ŞAHİN Ömer Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. , 2021, ss.33 - 41. 10.32571/ijct.755761 |
| AMA | ECE M,KUTLUAY S,ŞAHİN Ö Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. . 2021; 33 - 41. 10.32571/ijct.755761 |
| Vancouver | ECE M,KUTLUAY S,ŞAHİN Ö Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. . 2021; 33 - 41. 10.32571/ijct.755761 |
| IEEE | ECE M,KUTLUAY S,ŞAHİN Ö "Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene." , ss.33 - 41, 2021. 10.32571/ijct.755761 |
| ISNAD | ECE, MEHMET SAKIR vd. "Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene". (2021), 33-41. https://doi.org/10.32571/ijct.755761 |
| APA | ECE M, KUTLUAY S, ŞAHİN Ö (2021). Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. International Journal of Chemistry and Technology (IJCT), 5(1), 33 - 41. 10.32571/ijct.755761 |
| Chicago | ECE MEHMET SAKIR,KUTLUAY SİNAN,ŞAHİN Ömer Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. International Journal of Chemistry and Technology (IJCT) 5, no.1 (2021): 33 - 41. 10.32571/ijct.755761 |
| MLA | ECE MEHMET SAKIR,KUTLUAY SİNAN,ŞAHİN Ömer Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. International Journal of Chemistry and Technology (IJCT), vol.5, no.1, 2021, ss.33 - 41. 10.32571/ijct.755761 |
| AMA | ECE M,KUTLUAY S,ŞAHİN Ö Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. International Journal of Chemistry and Technology (IJCT). 2021; 5(1): 33 - 41. 10.32571/ijct.755761 |
| Vancouver | ECE M,KUTLUAY S,ŞAHİN Ö Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. International Journal of Chemistry and Technology (IJCT). 2021; 5(1): 33 - 41. 10.32571/ijct.755761 |
| IEEE | ECE M,KUTLUAY S,ŞAHİN Ö "Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene." International Journal of Chemistry and Technology (IJCT), 5, ss.33 - 41, 2021. 10.32571/ijct.755761 |
| ISNAD | ECE, MEHMET SAKIR vd. "Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene". International Journal of Chemistry and Technology (IJCT) 5/1 (2021), 33-41. https://doi.org/10.32571/ijct.755761 |
