The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC
Yıl: 2020 Cilt: 10 Sayı: 1 Sayfa Aralığı: 378 - 390 Metin Dili: İngilizce DOI: 10.37094/adyujsci.706982 İndeks Tarihi: 14-12-2021
The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC
Öz: In this work, ZnO nanopowders with different morphology such as nanoleafy and nanosphere were synthesized by hydrothermal method. The X-ray Diffraction (XRD) spectra have showed that ZnO nanopowders synthesized in different morphologies have a highly crystallized hexagonal structure. Scanning Electron Microscopy (SEM) was used to examine the morphology of nanopowders and revealed that they were formed in the nanoleafy and nanosphere structure. Dye-Sensitized Solar Cell (DSSC) fabrication was performed by using ZnO nanopowders as a photoelectrode. The Dye-Sensitized Solar Cells (DSSCs) were immersed in N719 dye at 4h and the performance of the cells (conversion efficiency, open circuit voltage, fill factor and short circuit current) of ZnO-DSSCs were obtained. It has been observed the highest efficiency value of 1.59% for nanosphere ZnO:DSSC. Keywords: ZnO nanopowders; Hydrothermal method; DSSC.
Anahtar Kelime: ZnO-DSSC’lerin Fotovoltaik Özelliklerine Fotoanodun Morfolojisinin Etkisi
Öz: Bu çalışmada, nano küre ve yaprak benzeri gibi farklı morfolojiye sahip ZnO nanotozları hidrotermal yöntemle sentezlenmiştir. Farklı morfolojilerde sentezlenen ZnO nanotozlarının, hegzagonal yapıda kristallendikleri XRD spektrumlarından belirlenmiştir. Nanotozların morfolojisini incelemek için Taramalı Elektron Mikroskobu (SEM) kullanılmış ve yapılarda nano boyutta yaprağımsı ve küresel fomlar gözlenmiştir. DSSC fabrikasyonu, farklı morfolojilerde ZnO tozları kullanılarak yapılmıştır. DSSC’ler 4 saat N719 boyasına daldırılmış ve ZnODSSC’lerin hücrelerinin pil performansları (kısa devre akımı, açık devre voltajı, verimi ve dolum faktörü) belirlenmiştir. En yüksek verim değeri, küre benzeri nano yapıya sahip ZnO: DSSC için %1.59 olarak bulunmuştur. Anahtar Kelimeler: ZnO nanotozları; Hidrotermal metot; DSSC.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
- Baxter, J.B., Aydil, E.S., Dye-sensitized solar cells based on semiconductor morphologies with ZnO nanowires, Solar Energy Materials and Solar Cells, 90(5), 607–622, 2006.
- Chandiran, A.K., Abdi-Jalebi, M., Nazeeruddin, M.K., Grätzel, M., Analysis of Electron Transfer Properties of ZnO and TiO2 Photoanodes for Dye-Sensitized Solar Cells, ACS Nano, 8(3), 2261–2268, 2014.
- Xu, F., Sun, L., Solution-derived ZnO nanostructures for photoanodes of dye-sensitized solar cells, Energy & Environmental Science, 4(3), 818–841, 2011.
- Qiu, Y., Chen, W., Yang, S., Facile hydrothermal preparation of hierarchically assembled, porous single-crystalline ZnO nanoplates and their application in dye-sensitized solar cells, Journal of Materials Chemistry, 20(5), 1001–1006, 2010.
- Alp, E., Araz, E.C., Buluç, A.F., Güner, Y., Değer, Y., Eşgin, H., Dermenci, K.B., Kazmanlı, M.K., Turan, S., Genç, A., Mesoporous nanocrystalline ZnO microspheres by ethylene glycol mediated thermal decomposition, Advanced Powder Technology, 29(12), 2018.
- Krishnapriya, R., Praneetha, S., Murugan, A.V., Investigation of the effect of reaction parameters on the microwave-assisted hydrothermal synthesis of hierarchical jasmine-flowerlike ZnO nanostructures for dye-sensitized solar cells, New Journal of Chemistry, 40(6), 5080– 5089, 2016.
- Rani, S., Suri, P., Shishodia, P.K., Mehra, R.M., Synthesis of nanocrystalline ZnO powder via sol–gel route for dye-sensitized solar cells, Solar Energy Materials and Solar Cells, 92(12), 1639–1645, 2008.
- Xu, H., Wang, H., Zhang, Y., He, W., Zhu, M., Wang, B., Yan, H., Hydrothermal synthesis of zinc oxide powders with controllable morphology, Ceramics International, 30(1), 93– 97, 2004.
- Zhu, S., Tian, X., Chen, J., Shan, L., Xu, X., Zhou, Z., A Facile Approach to Construct Multiple Structured ZnO Crystals by Trisodium Citrate-Assisted Hydrothermal Growth Toward Performance Enhancement of Dye-Sensitized Solar Cells, Journal of Physical Chemistry C, 118(30), 16401–16407, 2013.
- Wang, C., Zhang, X., Wang, D., Yang, Z., Ji, W., Zhang, C., Zhao, Y., Synthesis of nanostructural ZnO using hydrothermal method for dye-sensitized solar cells, Science China Technological Sciences, 53(4), 1146–1149, 2010.
- Li, D., Li, Y., Zhang, Y., Chang, F., Facile synthesis of three-dimensional ZnO hierarchical microspheres composed of well-ordered nanorods by hydrothermal method, Results in Physics, 12, 953–958, 2019.
- Hongsith, K., Hongsith, N., Wongratanaphisan, D., Gardchareon, A., Phadungdhitidhada, S., Singjai, P., Choopun, S., Sparking deposited ZnO nanoparticles as double-layered photoelectrode in ZnO dye-sensitized solar cell, Thin Solid Films, 539, 260–266, 2013.
- Khan, M.Z.H., Al-Mamun, M.R., Halder, P.K., Aziz, M.A., Performance improvement of modified dye-sensitized solar cells, Renewable and Sustainable Energy Reviews, 71, 602–617, 2017.
- Rathnasamy, R., Thangasamy, P., Thangamuthu, R., Sampath, S., Alagan, V., Green synthesis of ZnO nanoparticles using Carica papaya leaf extracts for photocatalytic and photovoltaic applications, Journal of Materials Science: Materials in Electronics, 28(14), 10374– 10381, 2017.
| APA | EŞGİN H, Caglar Y (2020). The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC. , 378 - 390. 10.37094/adyujsci.706982 |
| Chicago | EŞGİN HALİL,Caglar Yasemin The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC. (2020): 378 - 390. 10.37094/adyujsci.706982 |
| MLA | EŞGİN HALİL,Caglar Yasemin The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC. , 2020, ss.378 - 390. 10.37094/adyujsci.706982 |
| AMA | EŞGİN H,Caglar Y The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC. . 2020; 378 - 390. 10.37094/adyujsci.706982 |
| Vancouver | EŞGİN H,Caglar Y The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC. . 2020; 378 - 390. 10.37094/adyujsci.706982 |
| IEEE | EŞGİN H,Caglar Y "The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC." , ss.378 - 390, 2020. 10.37094/adyujsci.706982 |
| ISNAD | EŞGİN, HALİL - Caglar, Yasemin. "The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC". (2020), 378-390. https://doi.org/10.37094/adyujsci.706982 |
| APA | EŞGİN H, Caglar Y (2020). The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC. Adıyaman Üniversitesi Fen Bilimleri Dergisi, 10(1), 378 - 390. 10.37094/adyujsci.706982 |
| Chicago | EŞGİN HALİL,Caglar Yasemin The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC. Adıyaman Üniversitesi Fen Bilimleri Dergisi 10, no.1 (2020): 378 - 390. 10.37094/adyujsci.706982 |
| MLA | EŞGİN HALİL,Caglar Yasemin The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC. Adıyaman Üniversitesi Fen Bilimleri Dergisi, vol.10, no.1, 2020, ss.378 - 390. 10.37094/adyujsci.706982 |
| AMA | EŞGİN H,Caglar Y The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC. Adıyaman Üniversitesi Fen Bilimleri Dergisi. 2020; 10(1): 378 - 390. 10.37094/adyujsci.706982 |
| Vancouver | EŞGİN H,Caglar Y The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC. Adıyaman Üniversitesi Fen Bilimleri Dergisi. 2020; 10(1): 378 - 390. 10.37094/adyujsci.706982 |
| IEEE | EŞGİN H,Caglar Y "The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC." Adıyaman Üniversitesi Fen Bilimleri Dergisi, 10, ss.378 - 390, 2020. 10.37094/adyujsci.706982 |
| ISNAD | EŞGİN, HALİL - Caglar, Yasemin. "The Effect of Morphology of Photoanode on Photovoltaic Properties of ZnO-DSSC". Adıyaman Üniversitesi Fen Bilimleri Dergisi 10/1 (2020), 378-390. https://doi.org/10.37094/adyujsci.706982 |
