Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors
Yıl: 2021 Cilt: 14 Sayı: 2 Sayfa Aralığı: 664 - 676 Metin Dili: İngilizce DOI: 10.18185/erzifbed.951061 İndeks Tarihi: 02-03-2022
Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors
Öz: In this study, all-solid-state chromium (III) selective potentiometric poly(vinylchloride) (PVC) membrane sensors were constructed by using the newly synthesized ionophores called (E)-4-((4–nitrophenylimino) methyl) phenyl acrylate (A1), (E)-4-((4-chlorophenylimino) methyl) phenyl acrylate (A2) and (E)-4-(4- hydroxybenzylideneimino) benzoic acid acrylate (A3). The most suitable membrane composition, which has the best potentiometric characteristics, was examined by using membrane cocktail coated electrodes containing the ionophores, o-nitrophenyloctyl ether (o-NPOE), bis(2-ethylhexyl) sebacate (DOS), dibutyl phthalate (DBP), dioctyl phthalate (DOP) and PVC. In addition, the effect of potassium tetrakis(4-chlorophenyl) borate (KTpClPB) and sodium tetraphenylborate (NaTPB) as ionic additives was investigated to determine optimum membrane composition. The optimum membrane composition was determined as 1.0 % (w/w) A2, 67.0 % (w/w) o-NPOE, and 32.0 % (w/w) PVC. On the condition of pH 3.50 the prepared electrode exhibited a linear response over the concentration range of 1.3×10-7−1.0×10-1 M chromium (III) ion solutions (R2=0.9938) with a sensitivity of 27.1 ± 0.8 mV/ decade, detection limit of 6.3×10-8 M and short response time of ≤10 s. The influences of some widely used cation species over electrode responses were studied. In order to investigate whether the proposed electrode could be used analytically, potentiometric determination of chromium (III) ion was carried out in real samples. The results were statistically compared with the Inductively Coupled PlasmaMass Spectrometry (ICP-MS) method.
Anahtar Kelime: Akriloil Grup İçeren Schiff Bazlarının Potansiyometrik İyon-Seçici Sensörlerde İyonofor Olarak Kullanımının Araştırılması
Öz: Bu çalışmada, yeni sentezlenen iyonoforlar kullanılarak tümüyle katı-hal krom (III)-seçici potansiyometrik polivinil klorür (PVC) membran sensör geliştirildi. Bu amaçla yeni sentezlenen akriloil grup içeren (E)-4-(4- Nitro fenilimino) metil fenil akrilat (A1), (E)-4-(4-kloro fenilimino) metil fenil akrilat (A2) ve (E)-4-(4- hidroksibenzil dimino) benzoik asit akrilat (A3) schiff bazları iyonofor olarak kullanıldı. En uygun potansiyometrik özelliklere sahip membran bileşimi farklı oranlarda iyonoforlar (A1, A2 ve A3), plastikleştiriciler (o-nitrofeniloktil eter (o-NPOE)), bis (2-etilheksil) sebekat (DOS), dibutil ftalat (DBP), dioktil ftalat (DOP) ve PVC kullanılarak belirlendi. Ayrıca, optimum membran kompozisyonunu belirlemek için iyonik katkı maddesi olarak potasyum tetrakis(4-klorofenil) borat (KTpClPB) ve sodyum tetrafenilboratın (NaTPB) etkisi araştırıldı. Geliştirilen krom (III)-seçici sensör için % 1,0 A2 bileşiği, % 67,0 (a/a) o-NPOE ve % 32,0 (a/a) PVC oranları en uygun membran bileşimi olarak belirlendi. Geliştirilen krom (III)-seçici sensör pH 3,50’de 1,3×10-7−1,0×10-1 M konsantrasyon aralığında standart krom (III) iyon çözeltisine karşı doğrusal cevap sergiledi (R2= 0,9938). Sensör ile doğrusal çalışma aralığındaki her onkat’lık Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors 665 standart krom (III) konsantrasyon değişiminin ortalaması 27,1 ± 0,8 mV’luk eğim değeri, tekrarlanabilir potansiyeller elde edildi. Geliştirilen tümüyle katı-hal krom (III)-seçici potansiyometrik PVC membran sensörün tayin limiti 6,3×10-8 M ve cevap süresi ≤10 s olarak belirlendi. Yaygın bazı katyon türlerinin geliştirilen sensör üzerindeki girişim etkileri incelendi. Önerilen sensörün analitik olarak kullanılıp kullanılamayacağını araştırmak için, gerçek numunelerde krom (III) iyonunun potansiyometrik tayini gerçekleştirildi. Elde edilen sonuçlar İndüktif Eşleşmiş Plazma-Kütle Spektrometrisi (ICP-MS) metodu ile elde edilen verilerle istatiksel olarak karşılaştırıldı.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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| APA | Cubuk O, KIRANLIOĞLU G, ÇOLDUR F, Özkınalı S (2021). Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors. , 664 - 676. 10.18185/erzifbed.951061 |
| Chicago | Cubuk Osman,KIRANLIOĞLU Gülüzar,ÇOLDUR Fatih,Özkınalı Sevil Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors. (2021): 664 - 676. 10.18185/erzifbed.951061 |
| MLA | Cubuk Osman,KIRANLIOĞLU Gülüzar,ÇOLDUR Fatih,Özkınalı Sevil Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors. , 2021, ss.664 - 676. 10.18185/erzifbed.951061 |
| AMA | Cubuk O,KIRANLIOĞLU G,ÇOLDUR F,Özkınalı S Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors. . 2021; 664 - 676. 10.18185/erzifbed.951061 |
| Vancouver | Cubuk O,KIRANLIOĞLU G,ÇOLDUR F,Özkınalı S Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors. . 2021; 664 - 676. 10.18185/erzifbed.951061 |
| IEEE | Cubuk O,KIRANLIOĞLU G,ÇOLDUR F,Özkınalı S "Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors." , ss.664 - 676, 2021. 10.18185/erzifbed.951061 |
| ISNAD | Cubuk, Osman vd. "Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors". (2021), 664-676. https://doi.org/10.18185/erzifbed.951061 |
| APA | Cubuk O, KIRANLIOĞLU G, ÇOLDUR F, Özkınalı S (2021). Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 14(2), 664 - 676. 10.18185/erzifbed.951061 |
| Chicago | Cubuk Osman,KIRANLIOĞLU Gülüzar,ÇOLDUR Fatih,Özkınalı Sevil Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi 14, no.2 (2021): 664 - 676. 10.18185/erzifbed.951061 |
| MLA | Cubuk Osman,KIRANLIOĞLU Gülüzar,ÇOLDUR Fatih,Özkınalı Sevil Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol.14, no.2, 2021, ss.664 - 676. 10.18185/erzifbed.951061 |
| AMA | Cubuk O,KIRANLIOĞLU G,ÇOLDUR F,Özkınalı S Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2021; 14(2): 664 - 676. 10.18185/erzifbed.951061 |
| Vancouver | Cubuk O,KIRANLIOĞLU G,ÇOLDUR F,Özkınalı S Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors. Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi. 2021; 14(2): 664 - 676. 10.18185/erzifbed.951061 |
| IEEE | Cubuk O,KIRANLIOĞLU G,ÇOLDUR F,Özkınalı S "Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors." Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 14, ss.664 - 676, 2021. 10.18185/erzifbed.951061 |
| ISNAD | Cubuk, Osman vd. "Investigation of Schiff Bases Containing Acryloyl Moiety as Ionophore in Potentiometric Ion-Selective Sensors". Erzincan Üniversitesi Fen Bilimleri Enstitüsü Dergisi 14/2 (2021), 664-676. https://doi.org/10.18185/erzifbed.951061 |
