Yıl: 2021 Cilt: 7 Sayı: 3 Sayfa Aralığı: 331 - 346 Metin Dili: İngilizce DOI: 10.17515/resm2021.261na0219 İndeks Tarihi: 21-01-2022

Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes

Öz:
In this study, the influence of the oxidizers on the synthesis of carbon nanotubes by C2H4 decomposition over Fe catalyst has been investigated. CO2, O2, and H2O have been used as oxidizers, and to control catalyst particle formation and their sizes in the pretreatment stage. The same oxidizers have also been used in the growth stage to maintain the catalyst particle size, remove amorphous carbon formation to keep catalyst particle active. The results of scanning electron microscopy indicated that the average diameters of nanotubes decreased from 13.4±1.2 nm to 6.2±0.5 nm and extremely dense nanotubes were obtained when we added a small amount of CO2. Adding O2 extremely decreased the areal carbon nanotube density while widens the diameter distribution. H2O addition resulted in larger average diameters and made the growth strongly pretreatment dependent. Within the parameters tried for catalyst pretreatment and CNT growth processes, CO2 seemed the best choice for a weak oxidizing assistant. The strong dependency of the average diameter on pretreatment conditions indicated that pretreatment is a very important step in deciding the final diameters and their distribution. ©
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  • [1] Endo M, Kim Y, Hayashi T, Muramatsu H, Terrones M, Saito R, Villalpando Paez F, Chou S, Dresselhaus M. Nanotube Coalescence Inducing Mode: A Novel Vibrational Mode in Carbon Systems. Small, 2006; 2:1031-1036. https://doi.org/10.1002/smll.200600087
  • [2] Avouris P. Carbon nanotube electronics and photonics. Physics Today, 2009; 62:34-40. https://doi.org/10.1063/1.3074261
  • [3] Odom T, Huang J, Kim P, Lieber C. Atomic structure and electronic properties of single- walled carbon nanotubes. Nature, 1998; 391:62-64. https://doi.org/10.1038/34145
  • [4] Yuan Z, Huang H, Dang H, Cao J, Hu B, Fan S. Field emission property of highly ordered monodispersed carbon nanotube arrays. Applied Physics Letters, 2001; 78: 3127. https://doi.org/10.1063/1.1372205
  • [5] Alvi M, Al-Ghamdi A, Husain M. Field emission studies of CNTs/ZnO nanostructured thin films for display devices. Physica B: Condensed Matter, 2017; 521:312-316. https://doi.org/10.1016/j.physb.2017.07.015
  • [6] Dai H, Hafner J, Rinzler A, Colbert D, Smalley R. Nanotubes as nanoprobes in scanning probe microscopy, 1996. https://doi.org/10.1038/384147a0
  • [7] Hafner J, Cheung C, Oosterkamp T, Lieber C. High-yield assembly of individual single- walled carbon nanotube tips for scanning probe microscopies. J. Phys. Chem. B, 2001; 105:743-746. https://doi.org/10.1021/jp003948o
  • [8] Tachizaki T, Nakata T, Zhang K, Yamakawa I, Taniguchi S.-i. Nanometer-precise optical length measurement using near-field scanning optical microscopy with sharpened single carbon nanotube probe. Ultramicroscopy, 2018; 186:18-22. https://doi.org/10.1016/j.ultramic.2017.12.006
  • [9] Kong J, Franklin N, Zhou C, Chapline M, Peng S, Cho K, Dai H. Nanotube molecular wires as chemical sensors. Science, 2000; 287: 622. https://doi.org/10.1126/science.287.5453.622
  • [10] Kauffman DR, Star A. Carbon nanotube gas and vapor sensors. Angewandte Chemie International Edition, 2008; 47:6550-6570. https://doi.org/10.1002/anie.200704488
  • [11] Chen L, Pang X, Yu Z. Study on polycarbonate/multi-walled carbon nanotubes composite produced by melt processing. Materials Science and Engineering: A, 2007; 457:287-291. https://doi.org/10.1016/j.msea.2007.01.107
  • [12] Dalton A, Collins S, Razal J, Munoz E, Ebron V, Kim B, Coleman J, Ferraris J, Baughman R. Continuous carbon nanotube composite fibers: properties, potential applications, and problems. Journal of Materials Chemistry, 2004; 14:1-3. https://doi.org/10.1039/b312092a
  • [13] Futaba D, Hata K, Yamada T, Hiraoka T, Hayamizu Y, Kakudate Y, Tanaike O, Hatori H, Yumura M, Iijima S. Shape-engineerable and highly densely packed single-walled carbon nanotubes and their application as super-capacitor electrodes. Nature Materials, 2006; 5:987-994. https://doi.org/10.1038/nmat1782
  • [14] Yang L, Zheng W, Zhang P, Chen J, Tian W, Zhang Y, Sun Z. MXene/CNTs films prepared by electrophoretic deposition for supercapacitor electrodes. Journal of Electroanalytical Chemistry, 2018; 830:1-6. https://doi.org/10.1016/j.jelechem.2018.10.024
  • [15] Jung, M, Yong Eun K, Lee J, Baik Y, Lee K, Wan Park J. Growth of carbon nanotubes by chemical vapor deposition. Diamond and Related Materials, 2001; 10:1235-1240. https://doi.org/10.1016/S0925-9635(00)00446-5
  • [16] Zhang G, Mann D, Zhang L, Javey A, Li Y, Yenilmez E, Wang Q, McVittie J, Nishi Y, Gibbons J. Ultra-high-yield growth of vertical single-walled carbon nanotubes: Hidden roles of hydrogen and oxygen. Proceedings of the National Academy of Sciences of the United States of America, 2005; 102:16141. https://doi.org/10.1073/pnas.0507064102
  • [17] Qu J, Zhao Z, Wang Z, Wang X, Qiu J. Carbon dioxide-assisted fabrication of self- organized tubular carbon micropatterns on silicon substrates. Carbon, 2010; 48:1465- 1472. https://doi.org/10.1016/j.carbon.2009.12.041
  • [18] Amama P, Pint C, McJilton L, Kim S, Stach E, Murray P, Hauge R, Maruyama B. Role of water in super growth of single-walled carbon nanotube carpets. Nano letters, 2008; 9:44-49. https://doi.org/10.1021/nl801876h
  • [19] Rao F, Li T, Wang Y. Effect of hydrogen on the growth of single-walled carbon nanotubes by thermal chemical vapor deposition. Physica E: Low-dimensional Systems and Nanostructures, 2008; 40:779-784. https://doi.org/10.1016/j.physe.2007.09.185
  • [20] Kuo D, Su M. The effects of hydrogen and temperature on the growth and microstructure of carbon nanotubes obtained by the Fe (CO) 5 gas-phase-catalytic chemical vapor deposition. Surface and Coatings Technology, 2007; 201:9172-9178. https://doi.org/10.1016/j.surfcoat.2007.04.083
  • [21] Ince Yardimci A, Yılmaz S, Selamet Y. The effects of catalyst pretreatment, growth atmosphere and temperature on carbon nanotube synthesis using Co-Mo/MgO catalyst. Diamond and Related Materials, 2015; 60:81-86. https://doi.org/10.1016/j.diamond.2015.10.025
  • [22] Yamada T, Maigne A, Yudasaka M, Mizuno K, Futaba D, Yumura M, Iijima S, Hata K. Revealing the Secret of Water-Assisted Carbon Nanotube Synthesis by Microscopic Observation of the Interaction of Water on the Catalysts. Nano Letters, 2008; 8:4288- 4292. https://doi.org/10.1021/nl801981m
  • [23] Zhu L, Xiu Y, Hess D, Wong C. Aligned carbon nanotube stacks by water-assisted selective etching. Nano Lett, 2005; 5:2641-2645. https://doi.org/10.1021/nl051906b
  • [24] Terrado E, Muñoz E, Maser W, Benito A, Martínez M. Important parameters for the catalytic nanoparticles formation towards the growth of carbon nanotube aligned arrays. Diamond and Related Materials, 2007; 16:1082-1086. https://doi.org/10.1016/j.diamond.2006.11.004
  • [25] Nessim G, Hart A, Kim J, Acquaviva D, Oh J, Morgan C, Seita M, Leib J, Thompson C. Tuning of vertically-aligned carbon nanotube diameter and areal density through catalyst pre-treatment. Nano letters, 2008; 8:3587-3593. https://doi.org/10.1021/nl801437c
  • [26] Nam TH, Goto K, Yamaguchi Y, Premalal E, Shimamura Y, Inoue Y, Naito K, Ogihara S. Effects of CNT diameter on mechanical properties of aligned CNT sheets and composites. Composites Part A: Applied Science and Manufacturing, 2015; 76:289-298. https://doi.org/10.1016/j.compositesa.2015.06.009
  • [27] Huang J, Zhang Q, Zhao M, Wei F. Process intensification by CO<sub>2</sub> for high quality carbon nanotube forest growth: Double- walled carbon nanotube convexity or single-walled carbon nanotube bowls? Nano Research, 2009; 2:872-881. https://doi.org/10.1007/s12274-009-9088-6
  • [28] Futaba D, Goto J, Yasuda S, Yamada T, Yumura M, Hata K. General Rules Governing the Highly Efficient Growth of Carbon Nanotubes. Advanced Materials, 2009; 21:4811- 4815. https://doi.org/10.1002/adma.200901257
  • [29] Li X, Zhang X, Ci L, Shah R, Wolfe C, Kar S, Talapatra S, Ajayan P. Air-assisted growth of ultra-long carbon nanotube bundles. Nanotechnology, 2008; 19:455609. https://doi.org/10.1088/0957-4484/19/45/455609
  • [30] Hata K. Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes. Science, 2004; 306:1362-1364. https://doi.org/10.1126/science.1104962
  • [31] Hata K, Futaba D, Mizuno K, Namai T, Yumura M, Iijima S. Water-assisted highly efficient synthesis of impurity-free single-walled carbon nanotubes. Science, 2004; 3060:1362. https://doi.org/10.1126/science.1104962
  • [32] Nikolaev P, Bronikowski M, Bradley R, Rohmund F, Colbert D, Smith K, Smalley R. Gas- phase catalytic growth of single-walled carbon nanotubes from carbon monoxide.Chemical Physics Letters, 1999; 313:91-97. https://doi.org/10.1016/S0009- 2614(99)01029-5
  • [33] Talla J, Zhang D, Kandadai M, Avadhanula A, Curran S. A resonance Raman study of carboxyl induced defects in single-walled carbon nanotubes. Physica B: Condensed
  • Matter, 2010; 405:4570-4573. https://doi.org/10.1016/j.physb.2010.08.041 [34] Dresselhaus MS, Dresselhaus G, Saito R, Jorio A. Raman spectroscopy of carbon nanotubes. Physics reports, 2005; 409:47-99. https://doi.org/10.1016/j.physrep.2004.10.006
APA ince yardimci a, OGÜTLÜ A, Öğütlü D (2021). Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes. , 331 - 346. 10.17515/resm2021.261na0219
Chicago ince yardimci atike,OGÜTLÜ AHMET SABRI,Öğütlü Deniz Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes. (2021): 331 - 346. 10.17515/resm2021.261na0219
MLA ince yardimci atike,OGÜTLÜ AHMET SABRI,Öğütlü Deniz Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes. , 2021, ss.331 - 346. 10.17515/resm2021.261na0219
AMA ince yardimci a,OGÜTLÜ A,Öğütlü D Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes. . 2021; 331 - 346. 10.17515/resm2021.261na0219
Vancouver ince yardimci a,OGÜTLÜ A,Öğütlü D Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes. . 2021; 331 - 346. 10.17515/resm2021.261na0219
IEEE ince yardimci a,OGÜTLÜ A,Öğütlü D "Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes." , ss.331 - 346, 2021. 10.17515/resm2021.261na0219
ISNAD ince yardimci, atike vd. "Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes". (2021), 331-346. https://doi.org/10.17515/resm2021.261na0219
APA ince yardimci a, OGÜTLÜ A, Öğütlü D (2021). Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes. Research on Engineering Structures and Materials, 7(3), 331 - 346. 10.17515/resm2021.261na0219
Chicago ince yardimci atike,OGÜTLÜ AHMET SABRI,Öğütlü Deniz Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes. Research on Engineering Structures and Materials 7, no.3 (2021): 331 - 346. 10.17515/resm2021.261na0219
MLA ince yardimci atike,OGÜTLÜ AHMET SABRI,Öğütlü Deniz Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes. Research on Engineering Structures and Materials, vol.7, no.3, 2021, ss.331 - 346. 10.17515/resm2021.261na0219
AMA ince yardimci a,OGÜTLÜ A,Öğütlü D Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes. Research on Engineering Structures and Materials. 2021; 7(3): 331 - 346. 10.17515/resm2021.261na0219
Vancouver ince yardimci a,OGÜTLÜ A,Öğütlü D Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes. Research on Engineering Structures and Materials. 2021; 7(3): 331 - 346. 10.17515/resm2021.261na0219
IEEE ince yardimci a,OGÜTLÜ A,Öğütlü D "Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes." Research on Engineering Structures and Materials, 7, ss.331 - 346, 2021. 10.17515/resm2021.261na0219
ISNAD ince yardimci, atike vd. "Oxidizer gases effects on the diameter-controlled synthesis of carbon nanotubes". Research on Engineering Structures and Materials 7/3 (2021), 331-346. https://doi.org/10.17515/resm2021.261na0219