Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis

Inger, Erk; ARİ, Betul; SAHİNER, Nurettin; DEMİRCİ, Sahin; SENGEL, Sultan B.

doi:10.51354/mjen.980286

Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis

Sahin Demirci, (Çanakkale Onsekiz Mart Üniversitesi, Çanakkale, Türkiye)

Betul Ari, (Çanakkale Onsekiz Mart Üniversitesi, Çanakkale, Türkiye)

Sultan B. Sengel, (Çanakkale Onsekiz Mart Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Çanakkale, Türkiye)

Erk Inger, (Atılım Üniversitesi, Gövde ve Santral Bakım Bölümü, Ankara, Türkiye)

Nurettin Sahiner (Department of Chemical & Biomedical Engineering, and Materials Science and Engineering Program, University of South Florida, Tampa, FL 33620, USA)

Manas Journal of Engineering

12 1

Yıl: 2021 Cilt: 9 Sayı: 2 Sayfa Aralığı: 142 - 152 Metin Dili: İngilizce DOI: 10.51354/mjen.980286 İndeks Tarihi: 09-02-2022

Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis

Öz:

Here, boric acid (H3BO3) and its dewatered form, boron trioxide (B2O3) were tested as catalysts for hydrogen (H2) evolution in the methanolysis of sodium borohydride (NaBH4) in methanol. Parameters such as catalyst types and their amounts, NaBH4 concentration, and the reaction temperature affecting the hydrogen generation rate (HGR) were studied. It has been found that H3BO3 and B2O3 catalyzed methanolysis reaction of NaBH4 follow up first-order kinetics relative to the concentration of NaBH4. Furthermore, the conversion and activity of these catalysts were examined to determine their performance in ten consecutive use. Interestingly, H3BO3 and B2O3 have demonstrated superior catalytic performances in methanolysis of NaBH4 comparing to the studies published in literature with the activation energy of respectively 22.08 kJ.mol-1, and 23.30 kJ.mol-1 in H2 production. The HGR was calculated as 6481 mL.min-1.g-1 and 5163 mL.min-1.g-1 for H3BO3 and B2O3 catalyst, respectively for 50 mg catalyst at 298 K. These results are comparably better than most metal nanoparticle catalysts used for H2 production in addition to the naturally occurring boron-based environmentally friendliness of these materials.

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	DEMİRCİ S, ARİ B, SENGEL S, Inger E, SAHİNER N (2021). Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis. , 142 - 152. 10.51354/mjen.980286
Chicago	DEMİRCİ Sahin,ARİ Betul,SENGEL Sultan B.,Inger Erk,SAHİNER Nurettin Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis. (2021): 142 - 152. 10.51354/mjen.980286
MLA	DEMİRCİ Sahin,ARİ Betul,SENGEL Sultan B.,Inger Erk,SAHİNER Nurettin Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis. , 2021, ss.142 - 152. 10.51354/mjen.980286
AMA	DEMİRCİ S,ARİ B,SENGEL S,Inger E,SAHİNER N Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis. . 2021; 142 - 152. 10.51354/mjen.980286
Vancouver	DEMİRCİ S,ARİ B,SENGEL S,Inger E,SAHİNER N Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis. . 2021; 142 - 152. 10.51354/mjen.980286
IEEE	DEMİRCİ S,ARİ B,SENGEL S,Inger E,SAHİNER N "Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis." , ss.142 - 152, 2021. 10.51354/mjen.980286
ISNAD	DEMİRCİ, Sahin vd. "Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis". (2021), 142-152. https://doi.org/10.51354/mjen.980286

APA	DEMİRCİ S, ARİ B, SENGEL S, Inger E, SAHİNER N (2021). Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis. Manas Journal of Engineering, 9(2), 142 - 152. 10.51354/mjen.980286
Chicago	DEMİRCİ Sahin,ARİ Betul,SENGEL Sultan B.,Inger Erk,SAHİNER Nurettin Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis. Manas Journal of Engineering 9, no.2 (2021): 142 - 152. 10.51354/mjen.980286
MLA	DEMİRCİ Sahin,ARİ Betul,SENGEL Sultan B.,Inger Erk,SAHİNER Nurettin Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis. Manas Journal of Engineering, vol.9, no.2, 2021, ss.142 - 152. 10.51354/mjen.980286
AMA	DEMİRCİ S,ARİ B,SENGEL S,Inger E,SAHİNER N Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis. Manas Journal of Engineering. 2021; 9(2): 142 - 152. 10.51354/mjen.980286
Vancouver	DEMİRCİ S,ARİ B,SENGEL S,Inger E,SAHİNER N Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis. Manas Journal of Engineering. 2021; 9(2): 142 - 152. 10.51354/mjen.980286
IEEE	DEMİRCİ S,ARİ B,SENGEL S,Inger E,SAHİNER N "Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis." Manas Journal of Engineering, 9, ss.142 - 152, 2021. 10.51354/mjen.980286
ISNAD	DEMİRCİ, Sahin vd. "Boric acid versus boron trioxide as catalysts for green energy source H2 production from sodium borohydride methanolysis". Manas Journal of Engineering 9/2 (2021), 142-152. https://doi.org/10.51354/mjen.980286