Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması

USTA, Nazım; can, özer; ÖZTÜRK, ERKAN

Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması

Nazım USTA, (Pamukkale Üniversitesi, Mühendislik Fakültesi, Makine Mühendisliği Bölümü, Denizli, Türkiye)

Özer CAN, (Pamukkale Üniversitesi, Teknik Eğitim Fakültesi, Makine Eğitimi Bölümü, Denizli, Türkiye)

Erkan ÖZTÜRK (Pamukkale Üniversitesi, Teknik Eğitim Fakültesi, Makine Eğitimi Bölümü, Denizli, Türkiye)

Mühendislik Bilimleri Dergisi

11 2

Yıl: 2005 Cilt: 11 Sayı: 3 Sayfa Aralığı: 325 - 334 Metin Dili: Türkçe İndeks Tarihi: 29-07-2022

Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması

Öz:

Biyodizel ve etanol, dizel motorlar için yenilenebilir alternatif yakıtlardır ve farklı oranlarda No. 2 dizel yakıta karıştırılarak dizel motorlarda kullanılabilirler. Etanol tek bir kimyasal yapıya ve belli özelliklere sahip yakıt olmasına rağmen, biyodizellerin özellikleri elde edildikleri yağın cinsine ve esterleştirme metodlarına bağlı olarak değişmektedir. Bu çalışmada etanol ve iki farklı biyodizelin özellikleri No. 2 dizel yakıt ile karşılaştırılmış, etanol ve biyodizellerin ön yanma odalı turbo dizel bir motorun performans ve emisyonlarına etkileri incelenmiştir. Kullanılan alternatif yakıtlar CO, is ve $SO_2$ emisyonlarının azalmasını sağlarken, $NO_x$ emisyonunda artışa sebep olmuştur. Etanol ilavesi güçte bir miktar düşmeye sebep olurken, biyodizel ilavesi dizel yakıta göre çok az oranda güç artışı sağlamıştır.

Anahtar Kelime:

Comparsion of biodiesel and ethanol as an alternative diesel engine fuel

Öz:

Biodiesel and ethanol are alternative renewable diesel engine fuels and their mixtures with diesel fuel No. 2 at different proportions can be used in diesel engines. Although ethanol is unique chemical molecule and has certain specifications, specifications of biodiesel may vary depending on type of the oil used in the production and esterification technique. In this study, the specifications of ethanol and two different biodiesels were compared with those of diesel fuel No. 2. Effects of ethanol and the biodiesels on performance and emissions of a turbocharged indirect injection diesel engine were investigated. The alternative fuels used in the experiments caused increase in $NO_x$ emission, while they reduced CO, soot and $SO_2$ emissions. Although ethanol addition caused some power reduction, the biodiesel addition resulted in slightly higher power with respect to the diesel fuel.

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

1.Abu-Qudais M., Haddad, O., Qudaisat M. 2000. The Effect of Alcohol fumigation on Diesel Engine Performance and Emissions. Energy Conversion and Management; 41 (4): 389-99.
2.Agarwal, A. K., Das, L. M. 2001. Biodiesel Development and Characterization For use as Fuel in Compression Ignition Engines, Transactions of the ASME, 123,440-447.
3.Ajav, E. A., Singh, B., Bhattacharya, T. K. 1999. Experimental Study of Some Performance Parameters of Constant Speed Stationary Diesel Engine Using Ethanol-Diesel Blends as Fuel, Biomass and Bioenergy, 17: 357-365.
4.Alcantara, R., Amores J., Canoira L., Fidalgo, E., Franco, M. J., Navarro, A. 2000. Catalytic Production of Biodiesel From Soybean oil, Used Frying oil and Tallow. Biomass Bioenergy, 18 (6):515-27.
5.Altın, R., Çetinkaya, S., Yücesu H. S. 2001. The Potential of Using Vegetable oil Fuels as Fuel for Diesel Engines, Energy Conversion and Management, 42, 529-538.
6.Al-Widyan, M. I., Al-Shyoukh, A.O. 2002. Experimental Evaluation of the Transesterification of Waste Palm oil into Biodiesel, Bioresource Technology, 85, 253-256.
7.Antolin, G., Tinaut, F.V., Briceno, Y., Castano, V., Perez, C., Ramirez, A. I. 2002. Optimisation of Biodiesel Production by Sunflower oil Transesterification, Bioresource Technology, 83, 111-114.
8.Asfar, K. R., Hamed, H. 1998. Combustion of Fuel Blends. Energy Convers Manage, (10): 1081-93.
9.Bang-Quan, H., Shi-Jin, S., Jian-Xin, W., Hong, H. 2003. The Effect of Ethanol Blended Diesel Fuels on Emissions From A Diesel Engine, Atmospheric Environment, 37: 4965-4971.
10.Bari, S., Lim T. H., Yu, C. W. 2002. Effects of Preheating of Crude Palm Oil (CPO) on Injection System, Performance and Emission of a Diesel Engine. Renewable Energy, 27: 339-351.
11.Beatrice, C., Bertoli, C., Giacomo, N. D. 1998. New Findings on Combustion Behavior of Oxygenated Synthetic Diesel Fuels, Combustion Science and Technology, 137: 31-50.
12.Bilgin, A., Durgun, O., Şahin, Z. 2002. The Effects of Diesel-Ethanol Blends on Diesel Engine Performance, Energy Sources, 24: 431-440.
13.Canakci, M., Van Gerpen, J. 2001. Biodiesel Production From oils and Fats With High Free Fatty Acids, Transactions of the ASAE, 44, 6, 1429-1436.
14.Chao, M. R., Lin, T. C, Chao, H. R., Chang, F. H., Chen, C. B. 2001. Effects of Methanol-Containing Additive on Emission Characteristics From a Heavy-Duty Diesel Engine, The Science of the Total Environment, 279: 167-179.
15.Choi, C. Y., Reitz, R. D. 1999. An Experimental Study on The Effects of Oxygenated Fuel Blends and Multiple Injection Strategies on DI Diesel Engine Emissions, Fuel, 78: 1303-1317.
16.Crabbe, E., Nolasco-Hipolito, C., Kobayashi, G., Sonomoto, KIA. 2001. Biodiesel Production From Crude Palm oil and Evaluation of Butanol Extraction and fuel Properties. Process Biochem, 37 (1):65—71.
17.Curran, H. J., Fisher, E. M, Glaude, P. A., Marinov, N. M., Pitz, W. J., Westbrook, C. K., Layton, D. W., Flynn, P. F., Durrett, R. P., zur Loye., A. O., Akinyemi, O. C, Dryer, F. L. 2001. Detailed Chemical Kinetic Modelling of Diesel Combustion With Oxygenated Fuels, SAE, Paper No: 2001-01-0653.
18.Demirbaş, A. 2002. Biodiesel From ve Getable Oils via Transesterification in Supercritical Methanol, Energy Conversion and Management, 43, 2349-2356.
19.Dorado, M.P., Arnal, J. M., Gomez, J., Gil, A. and Lopez, F. J. 2002. The Effect of a Waste Vegetable oil Blend With Diesel Fuel on Engine Performance, Transactions of the ASAE, 45 (3), 519-523.
20.Dorado, M. P., Ballesteros E., Arnal, J. M., Gomez J., Lopez F. J. 2003. Exhaust Emissions From a Diesel Engine Fuelled With Transesterified Waste Olive oil. Fuel, 82(11): 1311-5.
21.Eugene, E. E., Bechtold, R. L., Timbaro, T. J., McCalhim, P. W. 1984. State of Art Report on the Use of Alcohols in Diesel Engines, SAE, Paper No: 840118.
22.Fischer, S. L., Dryer, F. L., and Curran, H. J. 2000. The Reaction Kinetics of Dimethyl Ether: High-Temperature Pyrolysis and Oxidation in Flow Reactors, International Journal of Chemical Kinetics, (32-12): 713-740.
23.Flynn, P. F, Durrett, R. P, Hunter, G. L, Zu Loye, A. O, Akinyemi, O. C, Dec, J. E, Westbrook, C. K. 1999. Diesel Combustion: an Integrated View Combining Laser Diagnostics, Chemical Kinetics and Empirical Validation. Society of Automotive Engineers Paper No. 1999-01-05 09, SAE, Warrendale, PA.
24.Goering, C.E., Crowell, T. J., Griffith, D. R., Jarrett M. W., Savage, L. D. 1992. Compression-ignition, Flexible-fuel Engine. Trans ASAE, 35 (2): 423-8.
25.Gonzalez, Gomez M. E., Howard-Hildige R., Leahy J. J., O'Reilly, T., Supple, B., Malone, M. 2000. 26.Emission and Performance Characteristics of a 2 Litre Toyota Diesel van Operating on Esterified Waste Cooking oil and Mineral Diesel Fuel. Environ Monitor Assessment, 65: 13-20.
27.Graboski, M.S., McCormick R.L., Alleman T. L., Herring, A. M. 2003. The Effect of Biodiesel Composition on Engine Emissions from a DDC Series 60 Diesel Engine, Final Report February 2003, NREL/SR-510-31461, National Renewable Energy Laboratory, Golden, Colorado, USA.
28.Haas, M. J., Bloomer, S, Scott, K. 2000. Simple, High-efficiency Synthesis of Fatty Acid Methyl Esters From Soapstock, JAOCS, 77 (4), 373-379.
29.Haas, M. J., Scott, K. M., Alleman, T. L., McCormick, R. L. 2001. Engine Performance of Biodiesel Fuel Prepared From Soybean Soapstock: A High Quality Renewable Fuel Produced From a Waste Feedstock, Energy and Fuels, 15 (5), 1207-1212.
30.Haas, M. J, Michalski, P. J., Runyon, S., Nunez, A., Scott, K.M. 2003. Production of FAME From Acid oil, a by-product of Vegetable oil Refining, JAOCS, 80 (1), 97-102.
31.Hansen, A.C., Lyne, W.L., Zhang Q. 2001. Ethanol-Diesel Blends: A Step Towards A Bio-Based Fuel for Diesel Engines, ASAE, Paper No: 01-6048.
32.Henham, A.W.E., Johns, R.A., Newnham, S. 1991. Development of a fuel-tolerant Diesel for Alternative Fuels. Int J Vehicle Des, 2(3):296-303.
33.Hofman V., Solseng E., Biodiesel fuel use in an Unmodified Diesel Engine. 2002. An ASAE/CSAE Meeting Presentation, Paper No: MBSK 02-109.
34.Hotta, Y., Nakakika, K., Inayoshi, M., Ogawa, T., Sato, T., Yamada, M. 1997. Combustion Improvement for Reducing Exhaust Emissions in IDI Diesel Engine, JSAE Review, 18:19-31.
35.Kalligeros, S., Zannikos, F., Stournas, S., Lois E., Anastopoulos, G., Teas C. H. and Sakellaropoulos F. 2003. An Investigation of Using Biodiesel/marine Diesel Blends on the Performance of a Stationary Diesel Engine. Biomass and Bioenergy, 24 (2): 141-149.
36.Karaosmanoğlu, F., Kurt G., Özaktaş, T. 2000. Long Term CI Engine test of Sunflower oil, Renewable Energy, (19), 219-221.
37.Kitamura, T., Ito, T., Senda, J., Fujimoto, H. 2001a. Extraction of the Suppression Effects of Oxygenated Fuels on Soot Formation Using a Detailed Chemical Kinetic Model, JSAE Review, 22 (2): 139-145.
38.Kitamura, T., Ito, T., Senda, J. Fujimoto, H. 2001b. Detailed Chemical Kinetic Modeling of Diesel Spray Combustion with Oxygenated Fuels, SAE, Paper No: 2001-01-1262.
39.Knothe, G. 2001. Analytical Methods Used in the Production and fuel Quality Assessment of Biodiesel, Transactions of the ASAE, 44 (2), 193-200.
40.Kocis, D., Song, K., Lee, H. S., and Litzinger, T. 2000. Effects of Dimethoxymethane and Dimethylcarbonate on Soot Production in an Optically-accessible DI Diesel Engine, SAE, Paper No: 2000-01-2795
41.Lin, C.Y., Huang, J. C. 2003. An Oxygenating Additive for Improving the Performance and Emission Characteristics of Marine Diesel Engines, Ocean Engineering, 30: 1699-1715.
42.Ma, F., Hana, M. A. 1999. Biodiesel Production: a Review. Bioresour Technol, 70 : 1-15.
43.McCormick, R. L., Parish, R. 2001. Miles Report: Technical Barriers to the Use of Ethanol in Diesel Fuel, National Renewable Energy Laboratory, NREL/MP 540-32674.
44.Monyem, A, Van Gerpen, J. H. 2001. The Effect of Biodiesel Oxidation On Engine Performance and Emissions. Biomass and Bioenergy, 20: 317-325.
45.Ni, T., Pinson, J. A., Gupta, S., Santoro, R. J. 1994. "Suppression of Soot Formation in Ethene Laminar Flames by Chemical Additives", Proceedings of the 25th International Symposium on Combustion, The Combustion Institute, 585-592.
46.Noguchi, N., Terao, H., Sakata, C. 1996. Performance Improvement by Control of Flow Rates and Diesel Injection Timing on Dual-fuel Engine With Ethanol. Bioresour Technol, 56 (1): 35-9.
47.Nwafor, O. M. I., Rice, G., Ogbonna, A. I. 2000. Effect of Advanced Injection Timing on the Performance of Rapeseed oil in Diesel Engines. Renewable Energy, 21 : 433-444.
49.Ozaktas, T. 2000. Compression Ignition Engine Fuel Properties of a Used Sunflower Oil-Diesel Fuel Blend. Energy Source, 22 (4): 377-82.
50.Pramanik, K. 2003. Properties and use of Jatropha Curcas oil and Diesel Fuel Blends in Compression Ignition Engine, Renewable Energy, 28, 239-248.
51.Rafiqul Islam, M.D., Subrahmanyam, J. P., Gajendra Babu, M.G. 1997. Computer Simulation Studies of an Alcohol-fueled, Low-heat-rejection, Direct-Injection Diesel Engine. SAE International Fall Fuels and Lubricants Meeting and Exposition, SAE Paper No. 972976.
52.Reddy, C. V. R., Krishna, M. V. S. M., Prasad C. M. V. 1999. Studies on Exhaust Emissions in Semi-Adiabatic Compression Ignition Engine With Alternate Fuels. Indian J Eng Mater Sci, 6 (5): 249-55.
53.Satge De Caro, P., Moloungui, Z. 2001. Interest of Combining an Additive with Diesel-Ethanol Blends for Use in Diesel Engines, Fuel, 80: 565-574.
54.Selim, M. Y. E., Radwan, M.S., Elfeky, S. M..S. 2003. Combustion of Jojoba Methyl Ester in an Indirect Injection Diesel Engine, Renewable Energy, 28, 1401-1420.
55.Tomasevic, A. V., Siler-Marinkovic S. S. 2003. Methanolysis of Used Frying Oil, Fuel Processing Technology, 81 (1), 1-6.
56.Williamson, A.M., Badr O. 1998. Assessing the Viability of Using Rape Methyl Ester (RME) as an Alternative to Mineral Diesel Fuel for Powering Road Vehicles in the UK. Applied Energy, 59 (2-3): 187-214.
57.Xiao, Z., Ladommatos, N., Zhao, H. 2000. The Effect of Aromatic Hydrocarbons and Oxygenates on Diesel Engine Emissions. Proceedings of the Institution of Mechanical Engineers. Part D: J Automob Eng, 214 (D3): 307-32.
58.Yu, C. W., Bari, S. and Ameen, A. 2002. A Comparison of Combustion Characteristics of Waste Cooking oil With diesel as fuel in a Direct Inhection Diesel Engine, Proc. Instn. Mech. Engnrs. Part D: J Automobile Engineering, (216), 237-243.
59.Zhang, Y., Dube, M. A., McLean, D.D., Kates, M. 2003. Biodiesel Production From Waste Cooking oil: 1. Process Design and Technological Assessment, Bioresource Technology, 89 (1), 1-16.

APA	USTA N, can ö, ÖZTÜRK E (2005). Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması. , 325 - 334.
Chicago	USTA Nazım,can özer,ÖZTÜRK ERKAN Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması. (2005): 325 - 334.
MLA	USTA Nazım,can özer,ÖZTÜRK ERKAN Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması. , 2005, ss.325 - 334.
AMA	USTA N,can ö,ÖZTÜRK E Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması. . 2005; 325 - 334.
Vancouver	USTA N,can ö,ÖZTÜRK E Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması. . 2005; 325 - 334.
IEEE	USTA N,can ö,ÖZTÜRK E "Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması." , ss.325 - 334, 2005.
ISNAD	USTA, Nazım vd. "Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması". (2005), 325-334.

APA	USTA N, can ö, ÖZTÜRK E (2005). Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması. Mühendislik Bilimleri Dergisi, 11(3), 325 - 334.
Chicago	USTA Nazım,can özer,ÖZTÜRK ERKAN Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması. Mühendislik Bilimleri Dergisi 11, no.3 (2005): 325 - 334.
MLA	USTA Nazım,can özer,ÖZTÜRK ERKAN Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması. Mühendislik Bilimleri Dergisi, vol.11, no.3, 2005, ss.325 - 334.
AMA	USTA N,can ö,ÖZTÜRK E Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması. Mühendislik Bilimleri Dergisi. 2005; 11(3): 325 - 334.
Vancouver	USTA N,can ö,ÖZTÜRK E Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması. Mühendislik Bilimleri Dergisi. 2005; 11(3): 325 - 334.
IEEE	USTA N,can ö,ÖZTÜRK E "Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması." Mühendislik Bilimleri Dergisi, 11, ss.325 - 334, 2005.
ISNAD	USTA, Nazım vd. "Alternatif dizel motor yakıtı olarak biyodizel ve etanolün karşılaştırılması". Mühendislik Bilimleri Dergisi 11/3 (2005), 325-334.