Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu

ERDOĞDULAR, Ali; Apar, Dilek

doi:10.17341/gazimmfd.615654

Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu

Ali Osman Erdoğdular, (Yıldız Teknik Üniversitesi, Kimya-Metalurji Fakültesi, Kimya Mühendisliği Bölümü, İstanbul, Türkiye)

Dilek Kılıç Apar (Yıldız Teknik Üniversitesi, Kimya-Metalurji Fakültesi, Kimya Mühendisliği Bölümü, İstanbul, Türkiye)

Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi

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Yıl: 2021 Cilt: 36 Sayı: 2 Sayfa Aralığı: 1055 - 1074 Metin Dili: Türkçe DOI: 10.17341/gazimmfd.615654 İndeks Tarihi: 29-07-2022

Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu

Öz:

Bu çalışmada, canlı formda kefir biyokütleleri ile sulu çözeltilerden Remazol Ultra Kırmızı RGB boyar maddesinin biyosorpsiyon yöntemi ile giderimi incelenmiştir. Biyosorpsiyon prosesini optimize etmek ve modellemek amacı ile deneyler kesikli olarak, farklı pH (2-2,5-3-3,5-4-5-6-7-8), sıcaklık (18- 25-32-39℃), çalkalama hızı (0-140-300 rpm) ve başlangıç boyar madde derişimlerinde (50-75-100-200-400 mg/L) gerçekleştirilmiştir. pH 2’de, 25℃ sıcaklıkta, 100 mg/L başlangıç boyar madde derişiminde, 2,4 g/L kefir biyokütlesi kullanılarak gerçekleştirilen 180 dakikalık biyosorpsiyon işlemi sonunda %93 oranında boyar madde giderimi elde edilmiştir. Kefir biyokütlesi için maksimum biyosorpsiyon kapasitesi değeri 400 mg/L başlangıç boyar madde derişiminde 118 mg/g olarak elde edilmiştir. Ardışık olarak gerçekleştirilen biyosorpsiyon deneyleri kefir biyokütlelerinin tekrar kullanılabilir olduğunu göstermiştir. Gerçekleştirilen modelleme çalışmaları sonucunda, kefir biyokütleleri ile boyar madde biyosorpsiyon kinetiğinin yalancı birinci derece kinetik modeliyle, biyosorpsiyon dengesinin ise Temkin izoterm modeliyle ifade edilebileceği belirlenmiştir.

Anahtar Kelime: Remazol Kırmızı RGB kefir biyokütlesi biyosorpsiyon izoterm kinetik

Biosorption of reactive dye Remazol Ultra Red RGB by metabolically active kefir biomass

Öz:

In the present study biosorptive removal of Remazol Ultra Red RGB textile dye from aqueous solutions with living kefir biomass was investigated. The experiments were carried out at batch operation mode under different process conditions such as initial pH (2-2.5-3-3.5-4 -5- 6-7-8), temperature (18-25-32-39℃), shaking rate (0-140-300 rpm) and initial dye concentration (50-75-100-200-400 mg/L) to optimize and model the biosorption process. 93% dye removal was attained in 180 min processing time by using 2.4 g/L kefir biomass for 100 mg/L initial dye concentration at pH 2 and 25℃. The maximum adsorption capacity for kefir biomass was obtained as 118 mg/g at 400 mg/L dye concentration. Successively performed biosorption experiments showed that the kefir biomass is reusable. As a result of the modelling studies performed the biosorption kinetics and the equilibrium by kefir biomass were best described respectively with the Pseudo first order and the Temkin models.

Anahtar Kelime: kinetics

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	ERDOĞDULAR A, Apar D (2021). Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu. , 1055 - 1074. 10.17341/gazimmfd.615654
Chicago	ERDOĞDULAR Ali,Apar Dilek Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu. (2021): 1055 - 1074. 10.17341/gazimmfd.615654
MLA	ERDOĞDULAR Ali,Apar Dilek Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu. , 2021, ss.1055 - 1074. 10.17341/gazimmfd.615654
AMA	ERDOĞDULAR A,Apar D Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu. . 2021; 1055 - 1074. 10.17341/gazimmfd.615654
Vancouver	ERDOĞDULAR A,Apar D Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu. . 2021; 1055 - 1074. 10.17341/gazimmfd.615654
IEEE	ERDOĞDULAR A,Apar D "Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu." , ss.1055 - 1074, 2021. 10.17341/gazimmfd.615654
ISNAD	ERDOĞDULAR, Ali - Apar, Dilek. "Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu". (2021), 1055-1074. https://doi.org/10.17341/gazimmfd.615654

APA	ERDOĞDULAR A, Apar D (2021). Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 36(2), 1055 - 1074. 10.17341/gazimmfd.615654
Chicago	ERDOĞDULAR Ali,Apar Dilek Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 36, no.2 (2021): 1055 - 1074. 10.17341/gazimmfd.615654
MLA	ERDOĞDULAR Ali,Apar Dilek Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, vol.36, no.2, 2021, ss.1055 - 1074. 10.17341/gazimmfd.615654
AMA	ERDOĞDULAR A,Apar D Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 2021; 36(2): 1055 - 1074. 10.17341/gazimmfd.615654
Vancouver	ERDOĞDULAR A,Apar D Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 2021; 36(2): 1055 - 1074. 10.17341/gazimmfd.615654
IEEE	ERDOĞDULAR A,Apar D "Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu." Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 36, ss.1055 - 1074, 2021. 10.17341/gazimmfd.615654
ISNAD	ERDOĞDULAR, Ali - Apar, Dilek. "Remazol Ultra Kırmızı RGB reaktif boyar maddesinin metabolik olarak aktif kefir biyokütlesi ile biyosorpsiyonu". Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 36/2 (2021), 1055-1074. https://doi.org/10.17341/gazimmfd.615654