Yıl: 2021 Cilt: 10 Sayı: 4 Sayfa Aralığı: 1535 - 1551 Metin Dili: Türkçe DOI: 10.17798/bitlisfen.982620 İndeks Tarihi: 29-07-2022

Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması

Öz:
Uçucu organik bir bileşik (UOB) olan benzen, kimyasal ve petrokimyasal gibi faaliyetlerle sanayiden ve endüstriden atmosfere salınmaktadır. Benzen, canlı sağlığı ve çevre için ağır kirliliklerden biri olup, kanserojen, mutajenik ve oldukça toksik polar olmayan bir kirleticidir. İnsan sağlığı ve ekolojik çevre için bir potansiyel tehlikedir. Bu sebeple benzenin bir kirletici olarak atmosferden uzaklaştırılması büyük önem taşımaktadır. Bu çevresel iyileştirme çalışmasında, Derik Halhalı zeytininin çekirdeği bir doğal selüloz (DS) kaynağı olarak manyetit ($Fe_3O_4$) modifikasyonunda kullanıldı. Başarıyla üretilen $Fe_3O_4$/DS nano-adsorbentin benzen giderimine karşı adsorpsiyon özellikleri incelendi. Birlikte çökeltme yöntemiyle elde edilen Fe3O4/DS nano-adsorbenti SEMEDS, FTIR ve BET analizleri ile karakterize edildi. Benzen giderim prosesinde, benzen başlangıç konsantrasyonu, adsorbent miktarı, adsorpsiyon süresi ve adsorpsiyon sıcaklığı gibi farklı parametrelerin etkileri değerlendirildi. Optimum değerler olarak belirlenen 90 dakika adsorpsiyon süresi, 15 ppm benzen başlangıç konsantrasyonu, 100 mg adsorbent miktarı ve 25°C adsorpsiyon sıcaklığı gibi koşullar altında benzen adsorpsiyon kapasitesi 298.15 mg/g olarak bulundu. Bu sonuç, başarıyla üretilen $Fe_3O_4$/DS nano-adsorbentin UOB kirleticilerin giderimindeki uygulama potansiyelini ortaya koymaktadır. Öte yandan, Quasi-birinci-dereceden kinetik modeli takip eden gaz halindeki benzenin $Fe_3O_4$/DS nano-adsorbenti üzerine adsorpsiyon prosesi fiziksel adsorpsiyon mekanizmasını işaret etmektedir. Ayrıca, 1.74 kJ/mol olarak hesaplanan E değeri (Dubinin-Radushkevich model sabiti) adsorpsiyon prosesinin fiziksel etkileşim mekanizması üzerinden gerçekleştiğini desteklemektedir. Son olarak, beş döngüden sonra, $Fe_3O_4$/DS nano-adsorbentin %90.61'lik bir yeniden kullanım verimini koruduğu bulundu, bu da nano-adsorbentin pratik uygulamalarda büyük bir potansiyele sahip olduğu anlamına geliyor.
Anahtar Kelime: Benzen giderimi Derik Halhalı zeytini Adsorpsiyon Nano-adsorbent Fe3O4/DS

Production of Eco-Friendly Cellulosic Magnetic Nano-Adsorbent from Derik Halhali Olive Seed and Its Use in Benzene Removal

Öz:
Benzene, a volatile organic compound (VOC), is released into the atmosphere from industry and industry through chemical and petrochemical activities. Benzene is one of the heavy pollutants for living health and the environment, and it is a carcinogenic, mutagenic and highly toxic non-polar pollutant. It is a potential hazard to human health and the ecological environment. For this reason, it is of great importance to remove benzene from the atmosphere as a pollutant. In this environmental improvement study, Derik Halhali olive seed was used as a natural cellulose (NC) source in the modification of magnetite ($Fe_3O_4$). The adsorption properties of the successfully produced $Fe_3O_4$/NC nano-adsorbent against benzene removal were investigated. $Fe_3O_4$/NC nanoadsorbent obtained by co-precipitation method was characterized by SEM-EDS, FTIR and BET analyses. In the benzene removal process, the effects of different parameters such as benzene initial concentration, adsorbent amount, adsorption time and adsorption temperature were evaluated. Benzene adsorption capacity was found to be 298.15 mg/g under the optimum values such as 90 min adsorption time, 15 ppm initial concentration of benzene, 100 mg adsorbent amount and 25°C adsorption temperature. This result reveals the application potential of the successfully produced $Fe_3O_4$/NC nano-adsorbent in the removal of VOC pollutants. On the other hand, the adsorption process of gaseous benzene on $Fe_3O_4$/NC nano-adsorbent following the Quasi-first-order kinetic model indicates the physical adsorption mechanism. In addition, the E value (Dubinin-Radushkevich model constant) calculated as 1.74 kJ/mol supports that the adsorption process takes place through the physical interaction mechanism. Finally, after five cycles, the $Fe_3O_4$/NC nano-adsorbent was found to maintain a reuse efficiency of 90.61%, meaning that the nano-adsorbent has great potential in practical applications.
Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
  • [1] Chavadej S., Kiatubolpaiboon W., Rangsunvigit P., Sreethawong T. 2007. A combined multistage corona discharge and catalytic system for gaseous benzene removal. Journal of Molecular Catalysis A: Chemical, 263 (1-2): 128-136.
  • [2] Batur E., Baytar O., Kutluay S., Horoz S., Şahin Ö. 2021. A comprehensive new study on the removal of pb (ii) from aqueous solution by Şırnak coal-derived char. Environmental Technology, 42 (3): 505-520.
  • [3] Baytar. O, Şahin Ö., Horoz S., Kutluay S. 2020. High-performance gas-phase adsorption of benzene and toluene on activated carbon: response surface optimization, reusability, equilibrium, kinetic, and competitive adsorption studies. Environmental Science and Pollution Research, 27 (21): 26191-26210.
  • [4] Kutluay S., Baytar O., Şahin Ö., Arran A. 2020. Optimization of Process conditions for adsorption of methylene blue on formaldehyde-modified peanut shells using box-behnken experimental design and response surface methodology. European Journal of Technique, 10 (1): 131-142.
  • [5] Ozkaya M., Cakir E., Gokbayrak Z., Ercan H., Taskin N.. 2006. Morphological and molecular characterization of derik halhali olive (olea europaea l.) accessions grown in Derik–Mardin province of Turkey. Scientia Horticulturae, 108 (2): 205-209.
  • [6] Shendi E.G., Özay D.S., Özkaya M.T., Üstünel N.F. 2019. Chemical characterization and storage stability of extra virgin olive oil extracted from Derik Halhalı cultivar. Croatian Journal of Food Science and Technology, 11 (1): 52-58.
  • [7] Hokkanen S., Bhatnagar A., Sillanpää M. 2016. A Review on modification methods to cellulosebased adsorbents to improve adsorption capacity. Water Research, 91: 156-173.
  • [8] Maleki A., Kamalzare M. 2014. Fe3O4@Cellulose composite nanocatalyst: preparation, characterization and application in the synthesis of benzodiazepines. Catalysis Communications, 53: 67-71.
  • [9] Alslaibi T.M., Abustan I., Ahmad M.A., Foul A.A. 2014. Kinetics and equilibrium adsorption of iron (ii), lead (ii), and copper (ii) onto activated carbon prepared from olive stone waste. Desalination and Water Treatment, 52 (40-42): 7887-7897.
  • [10] Alu’datt M.H., Alli I., Ereifej K., Alhamad M.N., Alsaad A., Rababeh T. 2011. Optimisation and characterisation of various extraction conditions of phenolic compounds and antioxidant activity in olive seeds. Natural Product Research, 25 (9): 876-889.
  • [11] Cao L., Cheng Z., Yan M., Chen Y. 2019. Anisotropic rubber nanocomposites via magneticinduced alignment of Fe3O4/Cellulose nanocrystals hybrids obtained by templated assembly. Chemical Engineering Journal, 363: 203-212.
  • [12] De las Nieves Piña M., Rodríguez P., Gutiérrez M.S., Quiñonero D., Morey J., Frontera A. 2018. Adsorption and quantification of volatile organic compounds (VOCs) by using hybrid magnetic nanoparticles. Chemistry–A European Journal, 24 (49): 12820-12826.
  • [13] Ece M.Ş. 2021. Synthesis and characterization of activated carbon supported magnetic nanoparticles (Fe3O4/AC@SiO2@Sulfanilamide) and its application in removal of toluene and benzene. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 617: 126231.
  • [14] Ece M.Ş., Kutluay S., Şahin Ö., Horoz S. 2020. Development of novel Fe3O4/AC@SiO2@1,4- DAAQ magnetic nanoparticles with outstanding VOC removal capacity: characterization, optimization, reusability, kinetics, and equilibrium studies. Industrial & Engineering Chemistry Research, 59 (48): 21106-21123.
  • [15] Kutluay S. 2021. Excellent Adsorptive performance of novel magnetic nano-adsorbent functionalized with 8-Hydroxyquinoline-5-Sulfonic acid for the removal of volatile organic compounds (BTX) vapors. Fuel, 287: 119691.
  • [16] Low L.E., Tey B.T., Ong B.H., Tang S.Y. 2018. A facile and rapid sonochemical synthesis of monodispersed Fe3O4@Cellulose nanocrystal nanocomposites without inert gas protection. Asia‐Pacific Journal of Chemical Engineering, 13 (4): e2209.
  • [17] Kutluay S., Baytar O., Şahin Ö. 2019. Equilibrium, kinetic and thermodynamic studies for dynamic adsorption of benzene in gas phase onto activated carbon produced from elaeagnus angustifolia seeds. Journal of Environmental Chemical Engineering, 7 (2): 102947.
  • [18] Zhao Z., Wang S., Yang Y., Li X., Li J., Li Z. 2015. Competitive adsorption and selectivity of benzene and water vapor on the microporous metal organic frameworks (HKUST-1). Chemical Engineering Journal, 259: 79-89.
  • [19] Khan N.A., Khan S.U., Ahmed S., Farooqi I.H., Dhingra A., Hussain A., Changani F. 2019. Applications of nanotechnology in water and wastewater treatment: A review. Asian Journal of Water, Environment and Pollution, 16 (4): 81-86.
  • [20] Azizi A. 2020. Green synthesis of Fe3O4 nanoparticles and its application in preparation of Fe3O4/Cellulose magnetic nanocomposite: a suitable proposal for drug delivery systems. Journal of Inorganic and Organometallic Polymers and Materials, 30: 3552–3561.
  • [21] De Luna M.D.G., Flores E.D., Genuino D.A.D., Futalan C.M., Wan M.W. 2013. Adsorption of Eriochrome Black T (EBT) dye using activated carbon prepared from waste rice hulls— optimization, isotherm and kinetic studies. Journal of the Taiwan Institute of Chemical Engineers, 44 (4): 646-653.
  • [22] Kutluay S., Ece M.Ş., Şahin Ö. 2020. Synthesis of magnetic Fe3O4/AC nanoparticles and its application for the removal of gas-phase toluene by adsorption process. International Journal of Chemistry and Technology, 4 (2): 146-155.
  • [23] Şahin Ö., Kutluay S., Horoz S., Ece M.Ş. 2021. Fabrication and characterization of 3,4- diaminobenzophenone-functionalized magnetic nanoadsorbent with enhanced VOC adsorption and desorption capacity. Environmental Science and Pollution Research, 28 (5): 5231-5253.
  • [24] Dou B., Hu Q., Li J., Qiao S., Hao Z. 2011. Adsorption performance of VOCs in ordered mesoporous silicas with different pore structures and surface chemistry. Journal of Hazardous Materials, 186 (2-3): 1615-1624.
  • [25] Tsai J.H., Chiang H.M., Huang G.Y., Chiang H.L. 2008. Adsorption characteristics of acetone, chloroform and acetonitrile on sludge-derived adsorbent, commercial granular activated carbon and activated carbon fibers. Journal of Hazardous Materials, 154 (1-3): 1183-1191.
  • [26] Qian Q., Gong C., Zhang Z., Yuan G. 2015. Removal of VOCs by activated carbon microspheres derived from polymer: a comparative study. Adsorption, 21 (4): 333-341.
  • [27] Mao H., Huang R., Hashisho Z., Wang S., Chen H., Wang H., Zhou D. 2016. Adsorption of toluene and acetone vapors on microwave-prepared activated carbon from agricultural residues: isotherms, kinetics, and thermodynamics studies. Research on Chemical Intermediates, 42 (4): 3359-3371.
  • [28] Ramirez D., Sullivan P.D., Rood M.J., Hay K.J. 2004. Equilibrium adsorption of phenol-, tire-, and coal-derived activated carbons for organic vapors. Journal of Environmental Engineering, 130 (3): 231-241.
  • [29] Ece M.Ş., Kutluay S., Şahin Ö. 2021. Silica-coated magnetic Fe3O4 nanoparticles as efficient nano-adsorbents for the improvement of the vapor-phase adsorption of benzene. International Journal of Chemistry and Technology, 5 (1): 33 - 41.
  • [30] Kutluay S. 2019. Benzen uçucu organik bileşiğinin badem kabuğundan üretilen char üzerine gaz fazı adsorpsiyonu: kinetik, denge ve termodinamik. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, 8 (4): 1432-1445.
  • [31] Freundlich H. 1906. Over the adsorption in solution. The Journal of Physical Chemistry, 57: 385- 471.
  • [32] Sari A., Tuzen M., Citak D., Soylak M. 2007. Equilibrium, kinetic and thermodynamic studies of adsorption of Pb (II) from aqueous solution onto Turkish kaolinite clay. Journal of Hazardous Materials, 149 (2): 283-291.
  • [33] Aziz A., Kim M., Kim S., Kim K.S. 2017. Adsorption and kinetic studies of volatile organic compounds (VOCs) on seed assisted template free ZSM-5 zeolite in air. Journal of Nanotechnology & Advanced Materials, 5: 1-9.
  • [34] Song G., Zhu X., Chen R., Liao Q., Ding Y.D., Chen L. 2016. An investigation of CO2 adsorption kinetics on porous magnesium oxide. Chemical Engineering Journal, 283: 175-183.
  • [35] Wang Y., Tao H., Yu D., Chang C. 2018. Performance assessment of ordered porous electrospun honeycomb fibers for the removal of atmospheric polar volatile organic compounds. Nanomaterials, 8 (5): 350.
  • [36] Foo K.Y., Hameed B.H. 2010. Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal, 156 (1): 2-10.
  • [37] Sadeghalvad B., Azadmehr A., Hezarkhani A. 2016. Enhancing adsorptive removal of sulfate by metal layered double hydroxide functionalized quartz-albitophire iron ore waste: preparation, characterization and properties. RSC Advances, 6 (72): 67630-67642.
  • [38] Wang C., Zhong H., Wu W., Pan C., Wei X., Zhou G., Yang F. 2019. Fe3O4@C core–shell carbon hybrid materials as magnetically separable adsorbents for the removal of dibenzothiophene in fuels. ACS Omega, 4 (1): 1652-1661.
  • [39] Zou W., Gao B., Ok Y.S., Dong L. 2019. Integrated adsorption and photocatalytic degradation of volatile organic compounds (VOCs) using carbon-based nanocomposites: a critical review. Chemosphere, 218: 845-859.
  • [40] Gan F., Cheng B., Jin Z., Dai Z., Wang B., Yang L., Jiang X. 2021. Hierarchical porous biochar from plant-based biomass through selectively removing lignin carbon from biochar for enhanced removal of toluene. Chemosphere, 279: 130514.
  • [41] Kutluay S., Temel F. 2021. Silica gel based new adsorbent having enhanced VOC dynamic adsorption/desorption performance. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 609: 125848.
  • [42] Temel F., Kutluay S. 2020. Investigation of high-performance adsorption for benzene and toluene vapors by calix[4]arene based organosilica (CBOS). New Journal of Chemistry, 44 (30): 12949- 12961.
APA KUTLUAY S, ECE M, ŞAHİN Ö, Kahraman Z, Önal F, Atku F (2021). Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması. , 1535 - 1551. 10.17798/bitlisfen.982620
Chicago KUTLUAY SİNAN,ECE MEHMET SAKIR,ŞAHİN Ömer,Kahraman Zafer,Önal Ferat,Atku Fesih Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması. (2021): 1535 - 1551. 10.17798/bitlisfen.982620
MLA KUTLUAY SİNAN,ECE MEHMET SAKIR,ŞAHİN Ömer,Kahraman Zafer,Önal Ferat,Atku Fesih Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması. , 2021, ss.1535 - 1551. 10.17798/bitlisfen.982620
AMA KUTLUAY S,ECE M,ŞAHİN Ö,Kahraman Z,Önal F,Atku F Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması. . 2021; 1535 - 1551. 10.17798/bitlisfen.982620
Vancouver KUTLUAY S,ECE M,ŞAHİN Ö,Kahraman Z,Önal F,Atku F Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması. . 2021; 1535 - 1551. 10.17798/bitlisfen.982620
IEEE KUTLUAY S,ECE M,ŞAHİN Ö,Kahraman Z,Önal F,Atku F "Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması." , ss.1535 - 1551, 2021. 10.17798/bitlisfen.982620
ISNAD KUTLUAY, SİNAN vd. "Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması". (2021), 1535-1551. https://doi.org/10.17798/bitlisfen.982620
APA KUTLUAY S, ECE M, ŞAHİN Ö, Kahraman Z, Önal F, Atku F (2021). Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, 10(4), 1535 - 1551. 10.17798/bitlisfen.982620
Chicago KUTLUAY SİNAN,ECE MEHMET SAKIR,ŞAHİN Ömer,Kahraman Zafer,Önal Ferat,Atku Fesih Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 10, no.4 (2021): 1535 - 1551. 10.17798/bitlisfen.982620
MLA KUTLUAY SİNAN,ECE MEHMET SAKIR,ŞAHİN Ömer,Kahraman Zafer,Önal Ferat,Atku Fesih Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol.10, no.4, 2021, ss.1535 - 1551. 10.17798/bitlisfen.982620
AMA KUTLUAY S,ECE M,ŞAHİN Ö,Kahraman Z,Önal F,Atku F Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2021; 10(4): 1535 - 1551. 10.17798/bitlisfen.982620
Vancouver KUTLUAY S,ECE M,ŞAHİN Ö,Kahraman Z,Önal F,Atku F Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi. 2021; 10(4): 1535 - 1551. 10.17798/bitlisfen.982620
IEEE KUTLUAY S,ECE M,ŞAHİN Ö,Kahraman Z,Önal F,Atku F "Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması." Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, 10, ss.1535 - 1551, 2021. 10.17798/bitlisfen.982620
ISNAD KUTLUAY, SİNAN vd. "Derik Halhalı Zeytin Çekirdeğinden Çevre Dostu Selülozik Manyetik Nano-Adsorbent Üretimi ve Benzen Gideriminde Kullanılması". Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 10/4 (2021), 1535-1551. https://doi.org/10.17798/bitlisfen.982620