Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi

Eda Ceylan, (Gebze Teknik Üniversitesi, Mühendislik Fakültesi, Çevre Mühendisliği Bölümü, Kocaeli, Türkiye)
Gizem BAŞARAN, (Gebze Teknik Üniversitesi, Mühendislik Fakültesi, Çevre Mühendisliği Bölümü, Kocaeli, Türkiye)
Nihal Bektaş, (Gebze Teknik Üniversitesi, Mühendislik Fakültesi, Çevre Mühendisliği Bölümü, Kocaeli, Türkiye)
HÜSEYİN CENGİZ YATMAZ (Gebze Teknik Üniversitesi, Mühendislik Fakültesi, Çevre Mühendisliği Bölümü, Kocaeli, Türkiye)
Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi
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Yıl: 2022 Cilt: 37 Sayı: 3 Sayfa Aralığı: 1427 - 1440 Metin Dili: Türkçe DOI: 10.17341/gazimmfd.931836 İndeks Tarihi: 29-07-2022

Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi

Öz:
Boyar maddelerin yoğun kullanıldığı tekstil endüstrisi atıksuları, genellikle biyolojik olarak kendiliğinden parçalanamayan büyük moleküllü toksik organik yapıları barındırdığından, konvansiyonel arıtım metotlarının yenilikçi adımlarla desteklenmesi önem arz etmektedir. Bu çalışmada, demir metali ile modifiye edilmiş kitosan (CS) adsorbent maddesi geliştirilmiş ve Reactive Orange (RO16) boyar maddesinin giderimi üzerine etkisi incelenmiştir. Bu amaçla, kitosan üzerine yüklenebilen maksimum demir miktarının belirlenmesi için 250, 500 ve 750 mg/L [Fe+2] konsantrasyonu olan FeSO4 çözeltisi ve kitosan 25oC sıcaklıkta 2 h reaksiyona tabi tutulmuştur. Demir ile modifiye edilmiş adsorbent maddeler sırasıyla CSFe-1, CSFe-2 ve CSFe-3 olarak tanımlanmış ve birim Fe+2 adsorpsiyon değerleri 79mg/g, 112mg/g ve 110mg/g olarak hesaplanmıştır. RO16 boyar maddesinin giderimi üzerine etkisi incelemek için CSFe-1 ve CSFe-2 adsorbent maddeleri seçilmiştir. 50 mg/L RO16 sulu çözeltisi ortamında 0,5g/L adsorbent madde kullanarak yürütülen adsorpsiyon çalışmalarının sonunda saf kitosan ile renk giderim verimi %25 iken, CSFe-1 ve CSFe-2 ile renk giderim verimi %90’a ulaşmış ve RO16 boyar maddesi için adsorbentlerin maksimum adsorpsiyon kapasiteleri sırasıyla 27, 91 ve 88 mg/g olarak hesaplanmıştır.
Anahtar Kelime: boyar madde giderimi adsorpsiyon adsorbent kitosan demir modifikasyonu

The effect of iron-loaded chitosan on the removal of Reactive Orange 16 dye

Öz:
In this study, iron modified chitosan (CS) adsorbent material was developed, and Reactive Orange 16 (RO16) dye removal was investigated. To determine the maximum iron content, chitosan was agitated at 25℃ for 2h with FeSO4 solution containing 250, 500 and 750 mg/L [Fe+2]. The adsorbents were identified as CSFe1, CSFe-2 and CSFe-3. Fe+2 adsorption values were calculated as 79, 112 and 110 mg/g. CSFe-1 and CSFe2 adsorbents were selected, and adsorption studies were carried out in 50 mg/L RO16 solutions at 0.5 g/L adsorbent amount. The color removal efficiencies were calculated as 27, 91 and 88 mg/g for pure chitosan, CSFe-1 and CSFe-2, respectively and found as 25% with pure chitosan, 90% for both CSFe-1 and CSFe-2. The best yield was obtained for the CSFe-1 adsorbent. To determine the optimum adsorption conditions, adsorbent amount (0.25, 0.5, 1 g CSFe-1/L), agitation speed (250, 350 rpm), dye solution concentration (25, 50, 100 mg/L) and temperature (25, 50℃) effects were investigated. The 0.5 g CSFe-1/L loading, 250 rpm, 25℃ and 50 mg/L dye solution concentration was determined, and 92% color removal efficiency was obtained. Color removal efficiencies of CSFe-1 in three consecutive runs were calculated as 92, 90 and 87%, respectively.
Anahtar Kelime: chitosan adsorption

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA Ceylan E, Başaran Dindaş G, Bektaş N, Yatmaz H (2022). Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi. , 1427 - 1440. 10.17341/gazimmfd.931836
Chicago Ceylan Eda,Başaran Dindaş Gizem,Bektaş Nihal,Yatmaz H Cengiz Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi. (2022): 1427 - 1440. 10.17341/gazimmfd.931836
MLA Ceylan Eda,Başaran Dindaş Gizem,Bektaş Nihal,Yatmaz H Cengiz Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi. , 2022, ss.1427 - 1440. 10.17341/gazimmfd.931836
AMA Ceylan E,Başaran Dindaş G,Bektaş N,Yatmaz H Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi. . 2022; 1427 - 1440. 10.17341/gazimmfd.931836
Vancouver Ceylan E,Başaran Dindaş G,Bektaş N,Yatmaz H Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi. . 2022; 1427 - 1440. 10.17341/gazimmfd.931836
IEEE Ceylan E,Başaran Dindaş G,Bektaş N,Yatmaz H "Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi." , ss.1427 - 1440, 2022. 10.17341/gazimmfd.931836
ISNAD Ceylan, Eda vd. "Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi". (2022), 1427-1440. https://doi.org/10.17341/gazimmfd.931836
APA Ceylan E, Başaran Dindaş G, Bektaş N, Yatmaz H (2022). Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 37(3), 1427 - 1440. 10.17341/gazimmfd.931836
Chicago Ceylan Eda,Başaran Dindaş Gizem,Bektaş Nihal,Yatmaz H Cengiz Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 37, no.3 (2022): 1427 - 1440. 10.17341/gazimmfd.931836
MLA Ceylan Eda,Başaran Dindaş Gizem,Bektaş Nihal,Yatmaz H Cengiz Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, vol.37, no.3, 2022, ss.1427 - 1440. 10.17341/gazimmfd.931836
AMA Ceylan E,Başaran Dindaş G,Bektaş N,Yatmaz H Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 2022; 37(3): 1427 - 1440. 10.17341/gazimmfd.931836
Vancouver Ceylan E,Başaran Dindaş G,Bektaş N,Yatmaz H Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 2022; 37(3): 1427 - 1440. 10.17341/gazimmfd.931836
IEEE Ceylan E,Başaran Dindaş G,Bektaş N,Yatmaz H "Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi." Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 37, ss.1427 - 1440, 2022. 10.17341/gazimmfd.931836
ISNAD Ceylan, Eda vd. "Demir yüklenmiş kitosanın Reaktif Turuncu 16 boyar maddesinin giderimine etkisi". Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 37/3 (2022), 1427-1440. https://doi.org/10.17341/gazimmfd.931836
Sayfa Oluşturulma Tarihi
23-04-2024 22:29

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