Synthesis, spectroscopic, thermal, crystal structure properties and characterization of
new Hofmann-type-like clathrates with 4-aminopyridine and water

Şahin, Onur; KARTAL, Zeki

doi:10.3906/kim-2011-29

Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water

Zeki KARTAL, (Girilmemişş)

Onur ŞAHİN (Sinop Üniversitesi, Sağlık Bilimleri Fakültesi, İş Sağlığı ve Güvenliği Bölümü, Sinop, Türkiye)

Turkish Journal of Chemistry

6 0

Yıl: 2021 Cilt: 45 Sayı: 3 Sayfa Aralığı: 616 - 633 Metin Dili: İngilizce DOI: 10.3906/kim-2011-29 İndeks Tarihi: 28-06-2022

Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water

Öz:

In this study, synthesis of two new heteronuclear tetracyanonickelate(II) clathrates based on 4-aminopyridine (4AP) and guest water $(H_2O)$ molecule and investigation of their structural properties were reported. These clathrates were characterized by using vibration spectroscopy, elemental, thermal analysis and single crystal X-ray diffraction (SC-XRD) techniques. Examining the elemental and spectral data of these clathrates, it was observed that the formulas $[Zn(II)(4AP)_2 Ni(µ-CN)_2 (CN)_2 ]·6H_2 O$ and $[Cu(II)(4AP)_4 Ni(µCN)_2 (CN)_2 ]·H_2O$ were defined their structures. General information about the structural properties of these clathrates in single crystal form has been obtained by considering the changes in the characteristic peaks of the cyanide group and the 4AP that formed them. The thermal behaviors of these clathrates were obtained by examining the temperature-dependent changes of their masses. The magnetic susceptibilities of these clathrates in single crystal form were measured with a Gouy balance. According to the data obtained using SC-XRD technique, the heterometallic $[Zn(II)(4AP)_2 Ni(µ-CN)_2 (CN)_2 ]·6H_2O$ compound has Cmcm and the heterometallic $[Cu(II) (4AP)_4 Ni(µ-CN)_2 (CN)_2 ]·H_2O$ compound has crystal structures in the C2/c space group.

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APA	KARTAL Z, Şahin O (2021). Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water. , 616 - 633. 10.3906/kim-2011-29
Chicago	KARTAL Zeki,Şahin Onur Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water. (2021): 616 - 633. 10.3906/kim-2011-29
MLA	KARTAL Zeki,Şahin Onur Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water. , 2021, ss.616 - 633. 10.3906/kim-2011-29
AMA	KARTAL Z,Şahin O Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water. . 2021; 616 - 633. 10.3906/kim-2011-29
Vancouver	KARTAL Z,Şahin O Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water. . 2021; 616 - 633. 10.3906/kim-2011-29
IEEE	KARTAL Z,Şahin O "Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water." , ss.616 - 633, 2021. 10.3906/kim-2011-29
ISNAD	KARTAL, Zeki - Şahin, Onur. "Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water". (2021), 616-633. https://doi.org/10.3906/kim-2011-29

APA	KARTAL Z, Şahin O (2021). Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water. Turkish Journal of Chemistry, 45(3), 616 - 633. 10.3906/kim-2011-29
Chicago	KARTAL Zeki,Şahin Onur Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water. Turkish Journal of Chemistry 45, no.3 (2021): 616 - 633. 10.3906/kim-2011-29
MLA	KARTAL Zeki,Şahin Onur Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water. Turkish Journal of Chemistry, vol.45, no.3, 2021, ss.616 - 633. 10.3906/kim-2011-29
AMA	KARTAL Z,Şahin O Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water. Turkish Journal of Chemistry. 2021; 45(3): 616 - 633. 10.3906/kim-2011-29
Vancouver	KARTAL Z,Şahin O Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water. Turkish Journal of Chemistry. 2021; 45(3): 616 - 633. 10.3906/kim-2011-29
IEEE	KARTAL Z,Şahin O "Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water." Turkish Journal of Chemistry, 45, ss.616 - 633, 2021. 10.3906/kim-2011-29
ISNAD	KARTAL, Zeki - Şahin, Onur. "Synthesis, spectroscopic, thermal, crystal structure properties and characterization of new Hofmann-type-like clathrates with 4-aminopyridine and water". Turkish Journal of Chemistry 45/3 (2021), 616-633. https://doi.org/10.3906/kim-2011-29