Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its
use in structural isomer separation

Cakar, fatih; IŞIK, BİROL; Cankurtaran, Hüsnü; Cankurtaran, Özlem

doi:10.3906/kim-2101-13

Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation

Birol IŞIK, (Yıldız Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Fatih ÇAKAR, (Yıldız Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Hüsnü CANKURTARAN, (Yıldız Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Özlem CANKURTARAN (Yıldız Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Turkish Journal of Chemistry

1 0

Yıl: 2021 Cilt: 45 Sayı: 3 Sayfa Aralığı: 845 - 857 Metin Dili: İngilizce DOI: 10.3906/kim-2101-13 İndeks Tarihi: 29-06-2022

Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation

Öz:

The selectivity of 4-(Decyloxy) benzoic acid (DBA) liquid crystal in surface adsorption region (303.2–328.2 K) and thermodynamic region (423.2 – 433.2 K) was investigated by inverse gas chromatography at infinite dilution (IGC-ID). The selectivity parameters of the structural isomer series named butyl acetate, butyl alcohol, and amyl alcohol series were calculated for the DBA using IGC-ID technique. Additionally, the surface properties including dispersive surface energy $(gamma_S ^{D}),$ free energy (DGA S ), enthalpy $(DeltaH_A ^{S}),$, and acidity-basicity constants were calculated with net retention volumes obtained from IGC-ID experiment results. When the DHA S and $(DeltaG_A ^{S}),$ are constants, DBA surface was found to be an acidic character $(K_D/K_A cong 0.89).$

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	IŞIK B, Cakar f, Cankurtaran H, Cankurtaran Ö (2021). Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation. , 845 - 857. 10.3906/kim-2101-13
Chicago	IŞIK BİROL,Cakar fatih,Cankurtaran Hüsnü,Cankurtaran Özlem Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation. (2021): 845 - 857. 10.3906/kim-2101-13
MLA	IŞIK BİROL,Cakar fatih,Cankurtaran Hüsnü,Cankurtaran Özlem Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation. , 2021, ss.845 - 857. 10.3906/kim-2101-13
AMA	IŞIK B,Cakar f,Cankurtaran H,Cankurtaran Ö Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation. . 2021; 845 - 857. 10.3906/kim-2101-13
Vancouver	IŞIK B,Cakar f,Cankurtaran H,Cankurtaran Ö Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation. . 2021; 845 - 857. 10.3906/kim-2101-13
IEEE	IŞIK B,Cakar f,Cankurtaran H,Cankurtaran Ö "Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation." , ss.845 - 857, 2021. 10.3906/kim-2101-13
ISNAD	IŞIK, BİROL vd. "Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation". (2021), 845-857. https://doi.org/10.3906/kim-2101-13

APA	IŞIK B, Cakar f, Cankurtaran H, Cankurtaran Ö (2021). Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation. Turkish Journal of Chemistry, 45(3), 845 - 857. 10.3906/kim-2101-13
Chicago	IŞIK BİROL,Cakar fatih,Cankurtaran Hüsnü,Cankurtaran Özlem Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation. Turkish Journal of Chemistry 45, no.3 (2021): 845 - 857. 10.3906/kim-2101-13
MLA	IŞIK BİROL,Cakar fatih,Cankurtaran Hüsnü,Cankurtaran Özlem Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation. Turkish Journal of Chemistry, vol.45, no.3, 2021, ss.845 - 857. 10.3906/kim-2101-13
AMA	IŞIK B,Cakar f,Cankurtaran H,Cankurtaran Ö Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation. Turkish Journal of Chemistry. 2021; 45(3): 845 - 857. 10.3906/kim-2101-13
Vancouver	IŞIK B,Cakar f,Cankurtaran H,Cankurtaran Ö Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation. Turkish Journal of Chemistry. 2021; 45(3): 845 - 857. 10.3906/kim-2101-13
IEEE	IŞIK B,Cakar f,Cankurtaran H,Cankurtaran Ö "Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation." Turkish Journal of Chemistry, 45, ss.845 - 857, 2021. 10.3906/kim-2101-13
ISNAD	IŞIK, BİROL vd. "Evaluation of the surface properties of 4-(Decyloxy) benzoic acid liquid crystal and its use in structural isomer separation". Turkish Journal of Chemistry 45/3 (2021), 845-857. https://doi.org/10.3906/kim-2101-13