Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine

KARTAL, Zeki; Şahin, Onur

doi:10.3906/kim-2101-32

Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine

Zeki KARTAL, (Girilmemişş)

Onur ŞAHİN (Sinop Üniversitesi, Sağlık Bilimleri Fakültesi, İş Sağlığı ve Güvenliği Bölümü, Sinop, Türkiye)

Turkish Journal of Chemistry

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Yıl: 2021 Cilt: 45 Sayı: 3 Sayfa Aralığı: 942 - 955 Metin Dili: İngilizce DOI: 10.3906/kim-2101-32 İndeks Tarihi: 29-06-2022

Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine

Öz:

In this study, synthesis of two new tetracyanocadmate(II) and tetracyanozincate(II) complexes based on 3-aminopyridine (3AP) and investigation of their structural properties were reported. These complexes were characterized by using vibration spectroscopy, elemental, thermal analysis and single crystal X-ray diffraction (SC-XRD) techniques. Investigation of the elemental, spectral and single crystal data of these complexes showed that the formulas $[Cd(3AP2 Zn(μ4 -CN4 n$ (1) and $[Cd(3AP)_2 Cd(μ_4 -CN)_4 ]_n$ (2) fully explained their crystal structure. General information about the structural and chemical properties of these complexes obtained in single crystal form was obtained by observing the changes in the characteristic peaks of the 3AP with the $[Zn(μ_4 -CN)_4 ]^{2-} and [Cd(μ_4 -CN)_4 ]^{2-}$ structures that make up these complexes. The behaviors of these complexes against changes in temperature were obtained by examining the temperature-dependent changes of their mass. The asymmetric unit of the heterometallic complexes 1 and 2 consist of half Cd(II) ion, half M ion [M = Zn1 in 1 and Cd2 in 2], two cyanide ligands and one 3AP

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	KARTAL Z, Şahin O (2021). Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine . , 942 - 955. 10.3906/kim-2101-32
Chicago	KARTAL Zeki,Şahin Onur Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine . (2021): 942 - 955. 10.3906/kim-2101-32
MLA	KARTAL Zeki,Şahin Onur Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine . , 2021, ss.942 - 955. 10.3906/kim-2101-32
AMA	KARTAL Z,Şahin O Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine . . 2021; 942 - 955. 10.3906/kim-2101-32
Vancouver	KARTAL Z,Şahin O Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine . . 2021; 942 - 955. 10.3906/kim-2101-32
IEEE	KARTAL Z,Şahin O "Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine ." , ss.942 - 955, 2021. 10.3906/kim-2101-32
ISNAD	KARTAL, Zeki - Şahin, Onur. "Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine ". (2021), 942-955. https://doi.org/10.3906/kim-2101-32

APA	KARTAL Z, Şahin O (2021). Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine . Turkish Journal of Chemistry, 45(3), 942 - 955. 10.3906/kim-2101-32
Chicago	KARTAL Zeki,Şahin Onur Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine . Turkish Journal of Chemistry 45, no.3 (2021): 942 - 955. 10.3906/kim-2101-32
MLA	KARTAL Zeki,Şahin Onur Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine . Turkish Journal of Chemistry, vol.45, no.3, 2021, ss.942 - 955. 10.3906/kim-2101-32
AMA	KARTAL Z,Şahin O Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine . Turkish Journal of Chemistry. 2021; 45(3): 942 - 955. 10.3906/kim-2101-32
Vancouver	KARTAL Z,Şahin O Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine . Turkish Journal of Chemistry. 2021; 45(3): 942 - 955. 10.3906/kim-2101-32
IEEE	KARTAL Z,Şahin O "Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine ." Turkish Journal of Chemistry, 45, ss.942 - 955, 2021. 10.3906/kim-2101-32
ISNAD	KARTAL, Zeki - Şahin, Onur. "Synthesis, spectroscopic, thermal, crystal structure properties, and characterization ofnew Hofmann-$T_d$-type complexes with 3-aminopyridine ". Turkish Journal of Chemistry 45/3 (2021), 942-955. https://doi.org/10.3906/kim-2101-32