Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the
effect of bismuth promotion and optimization via response surface methodology

er, ömer faruk; Demir Kivrak, Hilal; Ulas, Berdan

doi:10.3906/kim-2102-16

Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology

Ömer Faruk ER, (Van Yüzüncü Yıl Üniversitesi, Mühendislik Fakültesi, Kimya Mühendisliği Bölümü, Van, Türkiye)

Berdan ULAŞ, (Van Yüzüncü Yıl Üniversitesi, Mühendislik Fakültesi, Maden Mühendisliği Bölümü, Van, Türkiye)

Hilal KIVRAK (Eskişehir Osmangazi Üniversitesi, Mühendislik ve Mimarlık Bilimleri Fakültesi, Kimya Mühendisliği Bölümü, Eskişehir, Türkiye)

Turkish Journal of Chemistry

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Yıl: 2021 Cilt: 45 Sayı: 4 Sayfa Aralığı: 1173 - 1188 Metin Dili: İngilizce DOI: 10.3906/kim-2102-16 İndeks Tarihi: 29-06-2022

Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology

Öz:

In this study, the carbon nanotube supported gold, bismuth, and gold-bismuth (Au/MWCNT, Bi/MWCNT, and Au-Bi/ MWCNT) nanocatalysts were prepared with NaBH4 reduction method at varying molar atomic ratio for glucose electrooxidation (GAEO). The synthesized nanocatalysts at different Au: Bi atomic ratios are characterized via x-ray diffraction (XRD), transmission electron microscopy (TEM), and $N_2$ adsorption-desorption. For the performance of AuBi/MWCNT for GAEO, electrochemical measurements are performed by using different electrochemical techniques namely cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS). Monometallic Au/MWCNT exhibits higher activity than Bi/MWCNT with 256.57 mA/mg (0.936 mA/cm2 ) current density. According to CV results, Au80Bi20/MWCNT nanocatalyst has the highest GAEO activity with the mass activity of 320.15 mA/mg (1.133 mA/cm2 ). For $Au_{80}Bi_{20}/MWCNT$, central composite design (CCD) is utilized for optimum conditions of the electrode preparation. $Au_{80}Bi_{20}/MWCNT$ nanocatalysts are promising anode nanocatalysts for direct glucose fuel cells (DGFCs).

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	er ö, Ulas B, Demir Kivrak H (2021). Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology. , 1173 - 1188. 10.3906/kim-2102-16
Chicago	er ömer faruk,Ulas Berdan,Demir Kivrak Hilal Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology. (2021): 1173 - 1188. 10.3906/kim-2102-16
MLA	er ömer faruk,Ulas Berdan,Demir Kivrak Hilal Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology. , 2021, ss.1173 - 1188. 10.3906/kim-2102-16
AMA	er ö,Ulas B,Demir Kivrak H Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology. . 2021; 1173 - 1188. 10.3906/kim-2102-16
Vancouver	er ö,Ulas B,Demir Kivrak H Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology. . 2021; 1173 - 1188. 10.3906/kim-2102-16
IEEE	er ö,Ulas B,Demir Kivrak H "Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology." , ss.1173 - 1188, 2021. 10.3906/kim-2102-16
ISNAD	er, ömer faruk vd. "Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology". (2021), 1173-1188. https://doi.org/10.3906/kim-2102-16

APA	er ö, Ulas B, Demir Kivrak H (2021). Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology. Turkish Journal of Chemistry, 45(4), 1173 - 1188. 10.3906/kim-2102-16
Chicago	er ömer faruk,Ulas Berdan,Demir Kivrak Hilal Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology. Turkish Journal of Chemistry 45, no.4 (2021): 1173 - 1188. 10.3906/kim-2102-16
MLA	er ömer faruk,Ulas Berdan,Demir Kivrak Hilal Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology. Turkish Journal of Chemistry, vol.45, no.4, 2021, ss.1173 - 1188. 10.3906/kim-2102-16
AMA	er ö,Ulas B,Demir Kivrak H Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology. Turkish Journal of Chemistry. 2021; 45(4): 1173 - 1188. 10.3906/kim-2102-16
Vancouver	er ö,Ulas B,Demir Kivrak H Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology. Turkish Journal of Chemistry. 2021; 45(4): 1173 - 1188. 10.3906/kim-2102-16
IEEE	er ö,Ulas B,Demir Kivrak H "Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology." Turkish Journal of Chemistry, 45, ss.1173 - 1188, 2021. 10.3906/kim-2102-16
ISNAD	er, ömer faruk vd. "Remarkable bismuth-gold alloy decorated on MWCNT for glucose electrooxidation: the effect of bismuth promotion and optimization via response surface methodology". Turkish Journal of Chemistry 45/4 (2021), 1173-1188. https://doi.org/10.3906/kim-2102-16