Application of inverse gas chromatography in the surface characterization of diethanol
amine modified polystyrene based polymer

SENKAL, B.FILIZ; Korkmaz, Burak; Cankurtaran, Özlem; Cakar, fatih; adıgüzel, ayşegül çiğdem

doi:10.3906/kim-2105-45

Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer

Ayşegül Çiğdem ADIGÜZEL, (Bursa Teknik Üniversitesi, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Bölümü, Bursa, Türkiye)

Burak KORKMAZ, (İstanbul Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Fatih ÇAKAR, (Yıldız Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Bahire Filiz ŞENKAL, (İstanbul Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Özlem CANKURTARAN (Yıldız Teknik Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Turkish Journal of Chemistry

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Yıl: 2021 Cilt: 45 Sayı: 5 Sayfa Aralığı: 1533 - 1542 Metin Dili: İngilizce DOI: 10.3906/kim-2105-45 İndeks Tarihi: 30-06-2022

Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer

Öz:

In the present work, diethanol amine modified polystyrene based polymer (PVBC-Diethanol amine) was synthesized and characterized, then surface properties of the polymer were examined by inverse gas chromatography method at infinite dilution. The retention diagrams obtained based on the interaction of polar and nonpolar probes with the polymer were drawn over a temperature range from 30 to 55 °C. Through the diagrams, the dispersive component of the surface free energy, $gamma_S ^{D}$ of the polymer surface, and the specific enthalpy of adsorption, $DeltaH_A ^{S}$ , of probes on the polymer were also calculated. Lewis acid, $K_A$, and Lewis base, $K_D$ , parameters of PVBC-Diethanol amine surface were determined. The values of $K_A and K_D$ indicated that PVBC-Diethanol amine surface exhibited a basic behavior.

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	adıgüzel a, Korkmaz B, Cakar f, SENKAL B, Cankurtaran Ö (2021). Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer. , 1533 - 1542. 10.3906/kim-2105-45
Chicago	adıgüzel ayşegül çiğdem,Korkmaz Burak,Cakar fatih,SENKAL B.FILIZ,Cankurtaran Özlem Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer. (2021): 1533 - 1542. 10.3906/kim-2105-45
MLA	adıgüzel ayşegül çiğdem,Korkmaz Burak,Cakar fatih,SENKAL B.FILIZ,Cankurtaran Özlem Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer. , 2021, ss.1533 - 1542. 10.3906/kim-2105-45
AMA	adıgüzel a,Korkmaz B,Cakar f,SENKAL B,Cankurtaran Ö Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer. . 2021; 1533 - 1542. 10.3906/kim-2105-45
Vancouver	adıgüzel a,Korkmaz B,Cakar f,SENKAL B,Cankurtaran Ö Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer. . 2021; 1533 - 1542. 10.3906/kim-2105-45
IEEE	adıgüzel a,Korkmaz B,Cakar f,SENKAL B,Cankurtaran Ö "Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer." , ss.1533 - 1542, 2021. 10.3906/kim-2105-45
ISNAD	adıgüzel, ayşegül çiğdem vd. "Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer". (2021), 1533-1542. https://doi.org/10.3906/kim-2105-45

APA	adıgüzel a, Korkmaz B, Cakar f, SENKAL B, Cankurtaran Ö (2021). Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer. Turkish Journal of Chemistry, 45(5), 1533 - 1542. 10.3906/kim-2105-45
Chicago	adıgüzel ayşegül çiğdem,Korkmaz Burak,Cakar fatih,SENKAL B.FILIZ,Cankurtaran Özlem Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer. Turkish Journal of Chemistry 45, no.5 (2021): 1533 - 1542. 10.3906/kim-2105-45
MLA	adıgüzel ayşegül çiğdem,Korkmaz Burak,Cakar fatih,SENKAL B.FILIZ,Cankurtaran Özlem Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer. Turkish Journal of Chemistry, vol.45, no.5, 2021, ss.1533 - 1542. 10.3906/kim-2105-45
AMA	adıgüzel a,Korkmaz B,Cakar f,SENKAL B,Cankurtaran Ö Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer. Turkish Journal of Chemistry. 2021; 45(5): 1533 - 1542. 10.3906/kim-2105-45
Vancouver	adıgüzel a,Korkmaz B,Cakar f,SENKAL B,Cankurtaran Ö Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer. Turkish Journal of Chemistry. 2021; 45(5): 1533 - 1542. 10.3906/kim-2105-45
IEEE	adıgüzel a,Korkmaz B,Cakar f,SENKAL B,Cankurtaran Ö "Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer." Turkish Journal of Chemistry, 45, ss.1533 - 1542, 2021. 10.3906/kim-2105-45
ISNAD	adıgüzel, ayşegül çiğdem vd. "Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer". Turkish Journal of Chemistry 45/5 (2021), 1533-1542. https://doi.org/10.3906/kim-2105-45