Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide
redox probes on screen printed carbon electrode through cyclic voltammetry and
electrochemical impedance spectroscopy

Koç, Yücel; Avci, Huseyin; moralı, ugur; Erol, Salim

doi:10.3906/kim-2105-55

Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy

Yücel KOÇ, (Eskişehir Osmangazi Üniversitesi, Mühendislik Mimarlık Fakültesi, Kimya Mühendisliği Bölümü, Eskişehir, Türkiye)

Uğur MORALI, (Eskişehir Osmangazi Üniversitesi, Mühendislik Mimarlık Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümü, Eşkişehir, Türkiye)

Salim EROL, (Eskişehir Osmangazi Üniversitesi, Hücresel Tedavi ve Kök Hücre Araştırma Merkezi, Eşkişehir, Türkiye)

Hüseyin AVCI (Eskişehir Osmangazi Üniversitesi, Mühendislik Mimarlık Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümü, Eskişehir, Türkiye)

Turkish Journal of Chemistry

44 0

Yıl: 2021 Cilt: 45 Sayı: 6 Sayfa Aralığı: 1895 - 1915 Metin Dili: İngilizce DOI: 10.3906/kim-2105-55 İndeks Tarihi: 01-07-2022

Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy

Öz:

Potassium ferricyanide, potassium ferrocyanide, and their combination system are widely used redox probes for electrochemical impedance spectroscopy (EIS) characterization. In this work, electrochemical behavior of $K_3 Fe(CN)_6 , K_4 Fe(CN)_6 , and K_3 Fe(CN)_6 / K_4 Fe(CN)_6$ redox probes at five different concentrations using a screen printed carbon electrode (SPCE) by cyclic voltammetry (CV) and EIS methods was analyzed. Redox potentials were observed as a result of anodic and cathodic peak with CV analysis with determination 10 mM appropriate concentration through 0.01 mM, 0.1 mM, 1 mM, and 100 mM. In addition, with EIS analysis, each redox probe was simulated according to two different Randles circuit models and fitting equivalent model with varying concentration was determined and examined in detail. The results also demonstrated that selected high and low concentrations of redox probes can be categorized in two different models, although 1 mM behaved as a critical transition concentration. This study may contribute to the determination of relevant redox probe and its concentration in electrochemical investigations by selecting $K_3 Fe(CN)_6 /K_4 Fe(CN)_6$ to decrease any risk of inaccuracy.

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	Koç Y, moralı u, Erol S, Avci H (2021). Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy. , 1895 - 1915. 10.3906/kim-2105-55
Chicago	Koç Yücel,moralı ugur,Erol Salim,Avci Huseyin Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy. (2021): 1895 - 1915. 10.3906/kim-2105-55
MLA	Koç Yücel,moralı ugur,Erol Salim,Avci Huseyin Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy. , 2021, ss.1895 - 1915. 10.3906/kim-2105-55
AMA	Koç Y,moralı u,Erol S,Avci H Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy. . 2021; 1895 - 1915. 10.3906/kim-2105-55
Vancouver	Koç Y,moralı u,Erol S,Avci H Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy. . 2021; 1895 - 1915. 10.3906/kim-2105-55
IEEE	Koç Y,moralı u,Erol S,Avci H "Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy." , ss.1895 - 1915, 2021. 10.3906/kim-2105-55
ISNAD	Koç, Yücel vd. "Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy". (2021), 1895-1915. https://doi.org/10.3906/kim-2105-55

APA	Koç Y, moralı u, Erol S, Avci H (2021). Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy. Turkish Journal of Chemistry, 45(6), 1895 - 1915. 10.3906/kim-2105-55
Chicago	Koç Yücel,moralı ugur,Erol Salim,Avci Huseyin Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy. Turkish Journal of Chemistry 45, no.6 (2021): 1895 - 1915. 10.3906/kim-2105-55
MLA	Koç Yücel,moralı ugur,Erol Salim,Avci Huseyin Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy. Turkish Journal of Chemistry, vol.45, no.6, 2021, ss.1895 - 1915. 10.3906/kim-2105-55
AMA	Koç Y,moralı u,Erol S,Avci H Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy. Turkish Journal of Chemistry. 2021; 45(6): 1895 - 1915. 10.3906/kim-2105-55
Vancouver	Koç Y,moralı u,Erol S,Avci H Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy. Turkish Journal of Chemistry. 2021; 45(6): 1895 - 1915. 10.3906/kim-2105-55
IEEE	Koç Y,moralı u,Erol S,Avci H "Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy." Turkish Journal of Chemistry, 45, ss.1895 - 1915, 2021. 10.3906/kim-2105-55
ISNAD	Koç, Yücel vd. "Investigation of electrochemical behavior of potassium ferricyanide/ferrocyanide redox probes on screen printed carbon electrode through cyclic voltammetry and electrochemical impedance spectroscopy". Turkish Journal of Chemistry 45/6 (2021), 1895-1915. https://doi.org/10.3906/kim-2105-55