Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template

Kocak, Gökhan; Butun, Vural

doi:10.3906/kim-2106-18

Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template

Gökhan KOÇAK, (Adıyaman Üniversitesi, Meslek Yüksekokulu, Kimya ve Kimyasal Proses Teknolojileri Bölümü, Adıyaman, Türkiye)

Vural BÜTÜN (Eskişehir Osmangazi Üniversitesi, Fen Edebiyat Fakültesi, Kimya Bölümü, Eskişehir, Türkiye)

Turkish Journal of Chemistry

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Yıl: 2022 Cilt: 46 Sayı: 1 Sayfa Aralığı: 1 - 13 Metin Dili: İngilizce DOI: 10.3906/kim-2106-18 İndeks Tarihi: 04-07-2022

Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template

Öz:

The aim of this study is to highlight the use of polystyrene (PS) latexes stabilized with block copolymers as a hard template in the production of metal oxide hollow spheres. PS latexes produced by dispersion polymerization by stabilizing with tertiary amine methacrylate-based diblock copolymer were used as a hard template in the preparation of nickel manganese oxide $(NiMn_2 O_4 )$ hollow spheres and cobalt iron oxide $(CoFe_2 O_4 )$ bowl-like structures. Thanks to the diblock copolymer stabilizer with tertiary amine functional groups on the PS surface, precursor salts of $CoFe_2 O_4 and NiMn_2 O_4$ were first homogeneously deposited on the surface of PS latexes with a controlled precipitation technique. Then, metal oxide hollow spheres and bowl-like structures were produced by calcination. XRD results showed that $CoFe_2 O_4 and NiMn_2 O_4$ structures were successfully obtained after calcination. The thermogravimetric analysis results showed that the $CoFe_2 O_4 and NiMn_2 O_4$ contents of the hybrid PS spheres were in the range of 26.0–28.6 wt%. SEM images showed that the inorganic-polymer spheres fused with each other after calcination to form larger magnetic $CoFe_2 O_4$ bowl-like structures. SEM images also indicated successful production of highly rough $NiMn_2 O_4$ hollow spheres with nanosheets on the surface.

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	Kocak G, Butun V (2022). Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template. , 1 - 13. 10.3906/kim-2106-18
Chicago	Kocak Gökhan,Butun Vural Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template. (2022): 1 - 13. 10.3906/kim-2106-18
MLA	Kocak Gökhan,Butun Vural Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template. , 2022, ss.1 - 13. 10.3906/kim-2106-18
AMA	Kocak G,Butun V Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template. . 2022; 1 - 13. 10.3906/kim-2106-18
Vancouver	Kocak G,Butun V Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template. . 2022; 1 - 13. 10.3906/kim-2106-18
IEEE	Kocak G,Butun V "Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template." , ss.1 - 13, 2022. 10.3906/kim-2106-18
ISNAD	Kocak, Gökhan - Butun, Vural. "Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template". (2022), 1-13. https://doi.org/10.3906/kim-2106-18

APA	Kocak G, Butun V (2022). Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template. Turkish Journal of Chemistry, 46(1), 1 - 13. 10.3906/kim-2106-18
Chicago	Kocak Gökhan,Butun Vural Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template. Turkish Journal of Chemistry 46, no.1 (2022): 1 - 13. 10.3906/kim-2106-18
MLA	Kocak Gökhan,Butun Vural Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template. Turkish Journal of Chemistry, vol.46, no.1, 2022, ss.1 - 13. 10.3906/kim-2106-18
AMA	Kocak G,Butun V Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template. Turkish Journal of Chemistry. 2022; 46(1): 1 - 13. 10.3906/kim-2106-18
Vancouver	Kocak G,Butun V Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template. Turkish Journal of Chemistry. 2022; 46(1): 1 - 13. 10.3906/kim-2106-18
IEEE	Kocak G,Butun V "Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template." Turkish Journal of Chemistry, 46, ss.1 - 13, 2022. 10.3906/kim-2106-18
ISNAD	Kocak, Gökhan - Butun, Vural. "Production of NiMn2O4 hollow spheres and $CoFe_2O_4$bowl-like structures by using block copolymer stabilized polystyrene spheres as a hard template". Turkish Journal of Chemistry 46/1 (2022), 1-13. https://doi.org/10.3906/kim-2106-18